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Dispersion of Titanium(IV) Oxide Nanoparticles in Mixed Matrix Membrane Using Octaisobutyl Polyhedral Oligomeric Silsesquioxane for Enhanced CO2/CH4 Separation Performance

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Abstract

Titanium(IV) oxide (TiO2) nanoparticles have been incorporated into mixed matrix membranes (MMMs) to improve gas separation performance. However, TiO2 nanoparticles tend to agglomerate due to high surface energy and van der Waals forces. This leads to precipitation which causes the formation of non-homogeneous MMM morphology. In this study, the effect of octaisobutyl polyhedral oligomeric silsesquioxane (POSS) addition on TiO2/polysulfone MMM was investigated. The aims are to enhance gas separation performance whilst preventing agglomeration of TiO2 nanoparticles. The results demonstrated that inclusion of POSS as dispersant increases MMMs’ CO2/CH4 selectivity and permeance, possibly due to less void formation and more evenly distributed pore structure. For example, synergistic addition of 5 wt% TiO2 and 5 wt% POSS increased the CO2/CH4 selectivity up to 390% compared to MMM without POSS. This is supported by elemental mapping of titanium which revealed that POSS successfully dispersed TiO2 nanoparticles and prevented aggregation. TiO2-POSS/PSf MMMs also retained their favorable thermal stability.

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Acknowledgements

The authors are thankful to CO2 Research Centre (CO2RES) under Institute of Contaminant Management, Universiti Teknologi PETRONAS (UTP) for the experimental and technical support. In addition, we would like to express our gratitude for the financial support received from YUTP-FRG (No. 015 3AA-E08) and FRGS (Ref. No. FRGS/1/2018/TK02/UTP/02/3, Cost Center 015MA0-003).

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Authors and Affiliations

  1. CO2 Research Centre (CO2RES), Institute of Contaminant Management, Chemical Engineering Department, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak, Malaysia

    Grace Ying En Tan, Pei Ching Oh & Kok Keong Lau

  2. School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300, Nibong Tebal, Penang, Malaysia

    Siew Chun Low

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  1. Grace Ying En Tan
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  2. Pei Ching Oh
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Correspondence to Pei Ching Oh.

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Tan, G.Y.E., Oh, P.C., Lau, K.K. et al. Dispersion of Titanium(IV) Oxide Nanoparticles in Mixed Matrix Membrane Using Octaisobutyl Polyhedral Oligomeric Silsesquioxane for Enhanced CO2/CH4 Separation Performance. Chin J Polym Sci 37, 654–663 (2019). https://doi.org/10.1007/s10118-019-2246-8

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  • DOI: https://doi.org/10.1007/s10118-019-2246-8

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