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Clustering-triggered Emission of Cellulose and Its Derivatives

  • Lin-Lin Du
  • Bing-Li Jiang
  • Xiao-Hong Chen
  • Yun-Zhong Wang
  • Lin-Min Zou
  • Yuan-Li Liu
  • Yong-Yang GongEmail author
  • Chun Wei
  • Wang-Zhang YuanEmail author
Article
  • 12 Downloads

Abstract

In recent years, nonconventional luminogens free of aromatic groups have attracted extensive attention due to their academic importance and promising wide applications. Whilst previous studies generally focused on fluorescence from aliphatic amine or carbonylcontaining systems, less attention has been paid to room temperature phosphorescence (RTP) and the systems with predominant oxygen functionalities. In this work, photophysical properties of the polyhydroxy polymers, including microcrystalline cellulose (MCC), 2-hydroxyethyl cellulose (HEC), hydroxypropyl cellulose (HPC), and cellulose acetate (CA), were studied and compared. While MCC, HEC, and HPC solids showed bright emission alongside distinct RTP, CA demonstrated relatively low intensity of solid emission without noticeable RTP. Their emissions were explained in terms of the clustering-triggered emission (CTE) mechanism and conformation rigidification. Additionally, on account of its intrinsic emission, concentrated HEC aqueous solution could be used as the probe for the detection of 2,4,6-trinitrophenol (TNP).

Keywords

Cellulose Nonconventional luminogens Room temperature phosphorescent Clustering-triggered emission 

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Notes

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Nos. 51603050 and 51863006), the Natural Science Foundation of Guangxi (Nos. 2016GXNSFBA-380196, 2016GXNSFBA380064), Guangxi University Young and Middle-aged Teachers Basic Ability Promotion Project (No. KY2016YB316), and The Open Project Foundation of Guangxi Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials (15-KF-10).

Supplementary material

10118_2019_2215_MOESM1_ESM.pdf (1.3 mb)
Clustering-triggered Emission of Cellulose and Its Derivatives

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Copyright information

© Chinese Chemical Society, Institute of Chemistry (CAS) and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Lin-Lin Du
    • 1
  • Bing-Li Jiang
    • 2
  • Xiao-Hong Chen
    • 3
  • Yun-Zhong Wang
    • 3
  • Lin-Min Zou
    • 1
  • Yuan-Li Liu
    • 1
  • Yong-Yang Gong
    • 1
    Email author
  • Chun Wei
    • 1
  • Wang-Zhang Yuan
    • 3
    Email author
  1. 1.Key Laboratory of New Processing Technology for Non-ferrous Metals and Materials, Ministry of Education, College of Materials Science and EngineeringGuilin University of TechnologyGuilinChina
  2. 2.College of PharmacyGuilin Medical UniversityGuilinChina
  3. 3.School of Chemistry and Chemical EngineeringShanghai Jiao Tong UniversityShanghaiChina

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