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Chinese Journal of Polymer Science

, Volume 30, Issue 1, pp 56–62 | Cite as

Ring opening polymerization of tetrahydrofuran catalysed by maghnite-H+

  • Khadidja Benkenfoud
  • Amine HarraneEmail author
  • Mohammed Belbachir
Article

Abstract

The cationic ring-opening polymerization of tetrahydrofuran using maghnite-H+ is reported. Maghnite-H+, is a non-toxic solid catalyst issued from proton exchanged montmorillonite clay. Polytetrahydrofuran, also called “poly(butandiol) ether”, with acetate and hydroxyl end groups was successfully synthesized. Effects of reaction temperature, weight ratio of initiator/monomer and reaction time on the conversion of monomer and on the molecular weight are investigated. A cationic mechanism of the reaction was proposed. This chemistry can be considered as a suitable route for preparing poly(THF) as a soft segment for thermoplastic elastomers.

Keywords

Montmorillonite Maghnite Ring opening polymerization THF 

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Copyright information

© Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  • Khadidja Benkenfoud
    • 1
  • Amine Harrane
    • 1
    Email author
  • Mohammed Belbachir
    • 1
  1. 1.Laboratoire de Chimie des Polymères, Département de Chimie, Faculté des SciencesUniversité d’Oran Es-SeniaOranAlgeria

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