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Chinese Journal of Polymer Science

, Volume 28, Issue 3, pp 405–415 | Cite as

Biodegradable aliphatic/aromatic copolyesters based on terephthalic acid and poly(L-lactic acid): Synthesis, characterization and hydrolytic degradation

  • Bing-tao Wang
  • Yan Zhang
  • Ping-an Song
  • Zheng-hong Guo
  • Jie Cheng
  • Zheng-ping Fang (方征平)Email author
Article

Abstract

Biodegradable aliphatic/aromatic copolyesters, poly(butylene terephthalate-co-lactate) (PBTL) were prepared via direct melt polycondensation of terephthalic acid (TPA), 1,4-butanediol (BDO) and poly(L-lactic acid) oligomer (OLLA). The effects of polymerization time and temperature, as well as aliphatic/aromatic moiety ratio on the physical and thermal properties were investigated. The largest molecular weight of the copolyesters was up to 64100 with molecular weight distribution index of 2.09 when the polycondensation was carried out at 230°C for 6 h. DSC, XRD, DMA and TGA analysis clearly indicated that the degree of crystallinity, glass-transition temperature, melting point, decomposition temperature, tensile strength, elongation and Young’s modulus were influenced by the ratio between TPA and OLLA in the final copolyesters. Hydrolytic degradation results demonstrated that the incorporation of biodegradable lactate moieties into the aromatic polyester could efficiently improve hydrolytic degradability of the copolymer even though it still had many aromatic units in the main chains.

Keywords

Aliphatic/aromatic copolyesters Direct melt polycondensation Biodegradable 

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Copyright information

© Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  • Bing-tao Wang
    • 1
    • 2
  • Yan Zhang
    • 2
  • Ping-an Song
    • 1
    • 2
  • Zheng-hong Guo
    • 2
  • Jie Cheng
    • 2
  • Zheng-ping Fang (方征平)
    • 1
    • 2
    Email author
  1. 1.Institute of Polymer CompositesZhejiang University, Key Laboratory of Macromolecular Synthesis and Functionalization, Ministry of EducationHangzhouChina
  2. 2.Lab of Polymer Materials and Engineering, Ningbo Institute of TechnologyZhejiang UniversityNingboChina

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