Clean Technologies and Environmental Policy

, Volume 16, Issue 2, pp 395–403 | Cite as

Investigation of sorbents synthesised by mechanical–chemical reaction for sorption of As(III) and As(V) from aqueous medium

  • I. AndjelkovicEmail author
  • J. Nesic
  • D. Stankovic
  • D. Manojlovic
  • M. B. Pavlovic
  • C. Jovalekic
  • G. Roglic
Original Paper


Efficiency of Fe2O3 and mixture of Fe2O3 and MnO2 nanoparticles synthesised by mechanical–chemical reaction for inorganic As(III) and As(V) sorption was examined. Sorbents (Fe2O3 and mixture Fe2O3:MnO2 = 3:1) synthesised by mechanical–chemical treatment in planetary ball mile with different milling times were tested by batch experiments. Experimental data were fitted both to Freundlich and Langmuir adsorption models. Efficiency of sorption was in good correlation with the time of milling in case of pure oxide. There were small differences in sorption between As(III) and As(V). In the case of mixture of oxides results were different. The best results were obtained by 30 min of milling. With prolonged milling, the sorption decreased to 3 h and after that increased again. These results were explained by phase transition. Sorption kinetics, influence of pH and the presence of other anions were examined for mixture of oxides with highest sorption capacity. The bioavailability of sorbed arsen was tested using modified Tessier procedure.


Arsenic removal Adsorption Kinetics Isotherms 


  1. Altundogan HS, Altundogan S, Tumen F, Bildik M (2000) Arsenic removal from aqueous solutions by adsorption on red mud. Waste Manage (Oxf) 20:761–767CrossRefGoogle Scholar
  2. Amin MN, Kitagawa T, Begum A, Katsumata H, Suzuki T, Ohta K (2006) Removal of arsenic in aqueous solutions by adsorption onto waste rice husk. Ind Eng Chem Res (ACS) 45:8105–8110CrossRefGoogle Scholar
  3. Bang S, Patel M, Lippincott L, Meng X (2005) Removal of arsenic from groundwater by granular titanium dioxide adsorbent. Chemosphere 60:389–397CrossRefGoogle Scholar
  4. Biswas KB, Inoue J, Inoue K, Ghimire NK, Harada H, Ohto K, Kawakita H (2008) Adsorptive removal of As(V) and As(III) from water by a Zr(IV)-loaded orange waste gel. J Hazard Mater 154:1066–1074CrossRefGoogle Scholar
  5. Chakraborty S, Wolthers M, Chatterjee D, Charlet L (2007) Adsorption of arsenite and arsenate onto muscovite and biotite mica. J Colloid Interface Sci 309:392–401CrossRefGoogle Scholar
  6. Chutia P, Kato S, Kojima T, Satokawa S (2008) Arsenic adsorption from aqueous solution on synthetic zeolites. J Hazard Mater 162:440–447CrossRefGoogle Scholar
  7. Di Natale F, Erto A, Lancia A, Musmarra D (2008) Experimental and modeling analysis of As(V) ions adsorption on granular activated carbon. Water Res 42:2007–2016CrossRefGoogle Scholar
  8. Dong L, Zinin VP, Cowen PJ, Ming L (2009) Iron coated pottery granules for arsenic removal from drinking water. J Hazard Mater 168:626–632CrossRefGoogle Scholar
  9. Edwards MA (1994) Chemistry of arsenic removal during coagulation and Fe–Mn oxidation. J Am Water Works Assoc 86:64–77Google Scholar
  10. Ferguson FJ, Gavis J (1972) A review of the arsenic cycle in natural waters. Water Res 6:1259–1274CrossRefGoogle Scholar
  11. Ghimire KN, Inoue K, Makino K, Miyajima T (2002) Adsorption removal of arsenic using orange juice residue. Sep Sci Technol 37:2785–2799CrossRefGoogle Scholar
  12. Hering JG, Chen P, Wilkie JA, Elimelech M, Liang S (1996) Arsenic removal by ferric chloride. J Am Water Works Assoc 88:155–167Google Scholar
  13. Jing C, Meng X, Calvache E, Jiang G (2009) Remediation of organic and inorganic arsenic contaminated groundwater using a nanocrystalline TiO2-based adsorbent. Environ Pollut 157:2514–2519CrossRefGoogle Scholar
  14. Jovanovic D, Jakovljevic B, Rasic-Milutinovic Z, Paunovic K, Pekovic G, Knezevic T (2011) Arsenic occurrence in drinking water supply systems in ten municipalities in Vojvodina Region, Serbia. Environ Res 111:315–318CrossRefGoogle Scholar
  15. Lien HL, Wilkin RT (2005) High-level arsenite removal from groundwater by zero-valent iron. Chemosphere 59:377–386CrossRefGoogle Scholar
  16. Maiti A, DasGupta S, Basu KJ, De S (2007) Adsorption of arsenite using natural laterite as adsorbent. Sep Purif Technol 55:350–359CrossRefGoogle Scholar
  17. Manna B, Ghosh CU (2007) Adsorption of arsenic from aqueous solution on synthetic hydrous stannic oxide. J Hazard Mater 144:522–531CrossRefGoogle Scholar
  18. McKay G, Ho YS (1999) Pseudo-second-order model for sorption processes. Process Biochem 34:451–465CrossRefGoogle Scholar
  19. Mohan D, Pittman CU Jr (2007) Arsenic removal from water/wastewater using adsorbents—a critical review. J Hazard Mater 142:1–53CrossRefGoogle Scholar
  20. NRC, National Research Council (1999) Arsenic in drinking water. National Academy Press, Washington, DCGoogle Scholar
  21. Singh TS, Pant KK (2004) Equilibrium, kinetics and thermodynamic studies for adsorption of As(III) on activated alumina. Sep Purif Technol 36:139–147CrossRefGoogle Scholar
  22. Sun H, Wang L, Zhang R, Sui J, Xu G (2006) Treatment of groundwater polluted by arsenic compounds by zero valent iron. J Hazard Mater 129:297–303CrossRefGoogle Scholar
  23. Suryanarayana C (2001) Mechanical alloying and milling. Prog Mater Sci 46:1–184CrossRefGoogle Scholar
  24. Tessier A, Campbell PGC, Bisson M (1979) Sequential extraction procedure for the speciation of particulate trace metal. Anal Chem 51:844–851CrossRefGoogle Scholar
  25. Tripathy SS, Raichur MA (2008) Enhanced adsorption capacity of activated alumina by impregnation with alum for removal of As(V) from water. Chem Eng J 138:179–186CrossRefGoogle Scholar
  26. Zhang W, Singh P, Paling P, Delides S (2004) Arsenic removal from contaminated water by natural iron ores. Miner Eng 17:517–524CrossRefGoogle Scholar
  27. Zhang G, Qu J, Liu H, Liu R, Wu R (2007) Preparation and evaluation of a novel Fe–Mn binary oxide adsorbent for effective arsenite removal. Water Res 41:1921–1928CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2013

Authors and Affiliations

  • I. Andjelkovic
    • 1
    Email author
  • J. Nesic
    • 1
  • D. Stankovic
    • 1
  • D. Manojlovic
    • 2
  • M. B. Pavlovic
    • 3
  • C. Jovalekic
    • 4
  • G. Roglic
    • 2
  1. 1.Innovation Center of the Faculty of ChemistryUniversity of BelgradeBelgradeSerbia
  2. 2.Faculty of ChemistryUniversity of BelgradeBelgradeSerbia
  3. 3.Faculty of Electrical EngineeringUniversity of BelgradeBelgradeSerbia
  4. 4.Institute for Multidisciplinary ResearchUniversity of BelgradeBelgradeSerbia

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