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Theoretical predictions and experimental studies of self-organized C60 nanoparticles in water solution and on the support

  • Yu.I. Prilutski
  • S.S. Durov
  • V.N. Yashchuk
  • T.Yu. Ogul’chansky
  • V.E. Pogorelov
  • Yu.A. Astashkin
  • E.V. Buzaneva
  • Yu.D. Kirghisov
  • G.V. Andrievsky
  • P. Scharff
Regular paper

Abstract.

The formation in water of highly stable hydrated clusters (Ih symmetry group) and microcrystals (Th symmetry group) from C60 fullerenes is theoretically predicted using a molecular dynamics calculation. The proposed models are confirmed by the experiments on the Raman and absorption spectra of the fullerene aqueous solution. The additional study of the structure of C60 fullerene aggregates in the dry layer on the support (dielectric/semiconductor) is also performed.

PACS: 02.70.Ns Molecular dynamics and particle methods – 61.46.+w Clusters, nanoparticles, and nanocrystalline materials – 78.20.-e Optical properties of bulk materials and thin films 

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Copyright information

© EDP Sciences, Springer-Verlag, Società Italiana di Fisica 1999

Authors and Affiliations

  • Yu.I. Prilutski
    • 1
  • S.S. Durov
    • 1
  • V.N. Yashchuk
    • 1
  • T.Yu. Ogul’chansky
    • 1
  • V.E. Pogorelov
    • 1
  • Yu.A. Astashkin
    • 1
  • E.V. Buzaneva
    • 2
  • Yu.D. Kirghisov
    • 2
  • G.V. Andrievsky
    • 3
  • P. Scharff
    • 4
  1. 1.Department of Physics, Kiev Shevchenko University, Vladimirskaya Str., 64, 252033 Kiev, UkraineUA
  2. 2.Department of Radiophysics, Kiev Shevchenko University, Vladimirskaya Str., 64, 252033 Kiev, UkraineUA
  3. 3.Institute for Therapy of the Academy of Medical Sciences of Ukraine, Postysheva Str. 2a, 310116 Kharkov, UkraineUA
  4. 4.Institut für Anorganische und Analytische Chemie, TU Clausthal, Paul-Ernst-Strasse 4, D-38670 Clausthal-Zellerfeld, GermanyDE

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