Optical trapping assembling of clusters and nanoparticles in solution by CW and femtosecond lasers
Laser trapping of molecular systems in solution is classified into three cases: JUST TRAPPING, EXTENDED TRAPPING, and NUCLEATION and GROWTH. The nucleation in amino acid solutions depends on where the 1064-nm CW trapping laser is focused, and crystallization and liquid–liquid phase separation are induced by laser trapping at the solution/air surface and the solution/glass interface, respectively. Laser trapping crystallization is achieved even in unsaturated solution, on which unique controls of crystallization are made possible. Crystal size is arbitrarily controlled by tuning laser power for a plate-like anhydrous crystal of l-phenylalanine. The α- or γ-crystal polymorph of glycine is selectively prepared by changing laser power and polarization. Further efficient trapping of nanoparticles and their following ejection induced by femtosecond laser pulses are introduced as unique trapping phenomena and finally future perspective is presented.
KeywordsLaser trapping Femtosecond trapping Nucleation Crystal growth Polymorph control Crystal size
- 2.H. Masuhara, F.C. De Schryver, N. Kitamura, N. Tamai, Microchemistry: Spectroscopy and Chemistry in Small Domains (Elsevier, Amsterdam, 1994)Google Scholar