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Solid-state electrochemical analysis of Inka pottery from Qotakalli archeological site in the Cusco (Perú) area

  • Lyda La-Torre-RiverosEmail author
  • Antonio Doménech-CarbóEmail author
  • Carlos R. Cabrera
  • María Teresa Doménech-Carbó
  • Wilber Huahuasoncco-Condori
  • Dino Quispe Guzmán
  • María del Carmen Gutiérrez-Castillo
  • Katia Carmona-Ochoa
  • Amelia Pérez-Trujillo
Original Paper
  • 18 Downloads

Abstract

A series of sherds from the archeological site of Qotakalli in the area of Cusco (Perú), corresponding to four different Inka periods, were studied by means of square wave voltammetry of immobilized particles (VIMP) and electrochemical impedance spectroscopy (EIS). Ceramic microparticles were placed on a graphite working electrode and were characterized by VIMP and EIS in contact with 0.10 M H2SO4 aqueous electrolyte. Voltammetric features of the sherds, corresponding to the reduction of Fe(III) and Mn(IV) minerals and the oxidation of Fe(II), provided characteristic voltammetric features able to differentiate between different types of ceramic production and Inka periods. A consistent grouping was obtained from VIMP and EIS measurements, mainly responsive to porosity and microstructure variations of the ceramic samples, being also consistent with attenuated total reflectance—Fourier transformed infrared (ATR-FTIR) measurements, scanning electron microscopy (SEM), and optical and structural observations. Grouping of ceramic samples is important to support the archeological proposal of a diverse origin and production of pottery in Qotakalli.

Keywords

Inka pottery Cusco Voltammetry Impedance spectroscopy SEM 

Notes

Funding information

This study was financially supported by the Convenio de Cofinanciamiento 018-2016-FONDECYT, the MINECO Project CTQ2017-85317-C2-1-P supported by MINECO, ERDF, and AEI funds.

Supplementary material

10008_2019_4243_MOESM1_ESM.doc (426 kb)
ESM 1 (DOC 426 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Lyda La-Torre-Riveros
    • 1
    Email author
  • Antonio Doménech-Carbó
    • 2
    Email author
  • Carlos R. Cabrera
    • 3
  • María Teresa Doménech-Carbó
    • 4
  • Wilber Huahuasoncco-Condori
    • 1
  • Dino Quispe Guzmán
    • 1
  • María del Carmen Gutiérrez-Castillo
    • 5
  • Katia Carmona-Ochoa
    • 5
  • Amelia Pérez-Trujillo
    • 5
  1. 1.Departamento Académico de QuímicaUniversidad Nacional de San Antonio Abad de CuscoCuscoPerú
  2. 2.Departamento de Química AnalíticaUniversitat de ValènciaBurjassotSpain
  3. 3.Department of ChemistryUniversity of Puerto RicoSan JuanPuerto Rico
  4. 4.Institut de Restauració del PatrimoniUniversitat Politècnica de ValènciaValenciaSpain
  5. 5.Ministerio de CulturaDirección Desconcentrada CuscoCuscoPerú

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