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A novel method for the modification of LiNi0.8Co0.15Al0.05O2 with high cycle stability and low pH

  • Chunhui Cao
  • Jian ZhangEmail author
  • Xiaohua Xie
  • Baojia Xia
Original Paper
  • 32 Downloads

Abstract

Ni-rich cathode materials have high specific capacity and low cost, but they also have several drawbacks, such as high pH and poor cycle stability. In this paper, a simple dry-coat method using MnCO3 was adopted to improve the performance of LiNi0.8Co0.15Al0.05O2 (NCA), which is the first report of its kind. The modified NCA showed a capacity of 193 mAh g− 1 and capacity retention of 98.9% at 1 °C rate after 100 cycles, compared to the corresponding values (195 mAh g− 1 and 94.0%) for the pristine NCA. The pH was reduced from 12.19 to 11.69. Moreover, the storage performance in air and thermal stability in the delithiated state were also improved.

Keywords

MnCO3 LiNi0.8Co0.15Al0.05O2 Dry-coat Cycle stability pH 

Notes

Funding information

This work was financially supported by the National Key R&D program of China (2016YFB0100500).

References

  1. 1.
    Sasaki T, Nonaka T, Oka H, Okuda C, Itou Y, Kondo Y, Takeuchi Y, Ukyo Y, Tatsumi K, Muto S (2009) Capacity-fading mechanisms of LiNiO2-based lithium-ion batteries. J Electrochem Soc 156:A289–A293CrossRefGoogle Scholar
  2. 2.
    Kojima Y, Muto S, Tatsumi K, Kondo H, Oka H, Horibuchi K, Ukyo Y (2011) Degradation analysis of a Ni-based layered positive-electrode active material cycled at elevated temperatures studied by scanning transmission electron microscopy and electron energy-loss spectroscopy. J Power Sources 196:7721–7727CrossRefGoogle Scholar
  3. 3.
    Watanabe S, Kinoshita M, Hosokawa T, Morigaki K, Nakura K (2014) Capacity fading of LiAlyNi1−x−yCoxO2 cathode for lithium-ion batteries during accelerated calendar and cycle life tests (effect of depth of discharge in charge-discharge cycling on the suppression of the micro-crack generation of LiAlyNi1−x−yCoxO2 particle). J Power Sources 260:50–56CrossRefGoogle Scholar
  4. 4.
    Kleiner K, Melke J, Merz M, Jakes P, Nagel P (2015) Unraveling the degradation process of LiNi0.8Co0.15Al0.05O2 electrodes in commercial lithium ion batteries by electronic structure investigations. Acs Appl Mater Inter 7:19589–19600CrossRefGoogle Scholar
  5. 5.
    Shizuka K, Kiyohara C, Shima K, Takeda Y (2007) Effect of CO2 on layered Li1+zNi1−x−yCox M yO2 (M = Al, Mn) cathode materials for lithium ion batteries. J Power Sources 166:233–238CrossRefGoogle Scholar
  6. 6.
    Eom J, Kim MG, Cho J (2008) Storage characteristics of LiNi0.8 Co0.1+xMn0.1−xO2 (x = 0, 0.03, and 0.06) cathode materials for lithium batteries. J Electrochem Soc 155:A239–A245CrossRefGoogle Scholar
  7. 7.
    Matsumoto K, Kuzuo R, Takeya K, Yamanaka A (1999) Effects of CO2 in air on Li deintercalation from LiNi1−x−yCoxAlyO2. J Power Sources 81:558–561CrossRefGoogle Scholar
  8. 8.
    Zhang XY, Jiang WJ, Zhu XP, Mauger A, Qilu JCM (2011) Aging of LiNi1/3Mn1/3Co1/3O2 cathode material upon exposure to H2O. J Power Sources 196:5102–5108CrossRefGoogle Scholar
  9. 9.
    Liu HS, Zhang ZR, Gong ZL, Yang Y (2004) Origin of deterioration for LiNiO2 cathode material during storage in air. Electrochem Solid State Lett 7:A190–A193CrossRefGoogle Scholar
  10. 10.
    Liu HS, Yang Y, Zhang JJ (2006) Investigation and improvement on the storage property of LiNi0.8Co0.2O2 as a cathode material for lithium-ion batteries. J Power Sources 162:644–650CrossRefGoogle Scholar
  11. 11.
    Moshtev R, Zlatilova P, Vasilev S, Bakalova I, Kozawa A (1999) Synthesis, XRD characterization and electrochemical performance of overlithiated LiNiO2. J Power Sources 81:434– 441CrossRefGoogle Scholar
  12. 12.
    Park JH, Park JK, Lee JW (2016) Stability of LiNi0.6Mn0.2 Co0.2O2 as a cathode material for lithium-ion batteries against air and moisture. B Korean Chem Soc 37:344–348CrossRefGoogle Scholar
  13. 13.
    Xunhui X, Zhixing W, Peng Y, Huajun G, Fengxiang W, Jiexi W, Xinhai L (2013) Washing effects on electrochemical performance and storage characteristics of LiNi0.8Co0.1Mn0.1O2 as cathode material for lithium-ion batteries. J Power Sources 222:318– 325CrossRefGoogle Scholar
  14. 14.
    Kim J, Hong YS, Ryu KS, Kim MG, Cho J (2006) Washing effect of a LiNi0.83Co0.15Al0.02O2 cathode in water. Electrochem Solid State Lett 9:A19–A23CrossRefGoogle Scholar
  15. 15.
    Naushad (ed) (2012) Life cycle assessment of wastewater treatment. Massachusetts Institute of Technology, BostonGoogle Scholar
  16. 16.
    Sulz CH (1888) A treatise on beverages or the complete practical bottler. Dick & Fitzgerald Publishers, New YorkGoogle Scholar
  17. 17.
    Kim H, Lee K, Kim S, Kim Y (2016) Fluorination of free lithium residues on the surface of lithium nickel cobalt aluminum oxide cathode materials for lithium ion batteries. Mater Design 100:175–179CrossRefGoogle Scholar
  18. 18.
    Ring RJ, Royston D (1973) A review of fluorine cells and fluorine production facilities. Australian Atomic Energy CommissionGoogle Scholar
  19. 19.
    Manthiram A, Knight JC, Myung ST, Oh SM, Sun YK (2016) Nickel-rich and lithium-rich layered oxide cathodes: progress and perspectives. Adv Energy Mater 6:1501010CrossRefGoogle Scholar
  20. 20.
    Cho Y, Oh P, Cho J (2013) A new type of protective surface layer for high-capacity Ni-based cathode materials: nanoscaled surface pillaring layer. Nano Lett 13:1145–1152CrossRefGoogle Scholar
  21. 21.
    Huang B, Li XH, Wang ZX, Guo HJ, Shen L, Wang J (2014) A comprehensive study on electrochemical performance of Mn-surface-modified LiNi0.8Co0.15Al0.05O2 synthesized by an in situ oxidizing-coating method. J Power Sources 252:200– 207CrossRefGoogle Scholar
  22. 22.
    Yang J, Xia YY (2016) Suppressing the phase transition of the layered Ni-rich oxide cathode during high-voltage cycling by introducing low-content Li2MnO3. Acs Appl Mater Inter 8:1297–1308CrossRefGoogle Scholar
  23. 23.
    Zhang HL, Li B, Wang J, Wu BH, Fu T, Zhao JB (2016) Effects of Li2MnO3 coating on the high-voltage electrochemical performance and stability of Ni-rich layer cathode materials for lithium-ion batteries. Rsc Adv 6:22625–22632CrossRefGoogle Scholar
  24. 24.
    Cao CH, Zhang J, Xie XH, Xia BJ (2017) Composition, structure, and performance of Ni-based cathodes in lithium ion batteries. Ionics 23:1337–1356CrossRefGoogle Scholar
  25. 25.
    Jo JH, Jo CH, Yashiro H, Kim SJ, Myung ST (2016) Re-heating effect of Ni-rich cathode material on structure and electrochemical properties. J Power Sources 313:1–8CrossRefGoogle Scholar
  26. 26.
    Jung SK, Gwon H, Hong J, Park KY, Seo DH, Kim H, Hyun J, Yang W, Kang K (2013) Understanding the degradation mechanisms of LiNi0.5Co0.2Mn0.3O2 cathode material in lithium ion batteries. Adv Energy Mater 1300787Google Scholar
  27. 27.
    Ohzuku T, Ueda A, Nagayama M (1993) Electrochemistry and structural chemistry of LiNiO2 (R-3m) for 4 volt secondary lithium cells. J Electrochem Soc 140:1862–1870CrossRefGoogle Scholar
  28. 28.
    Guilmard M, Croguennec L, Delmas C (2003) Thermal stability of lithium nickel oxide derivatives. Part II: LixNi0.70Co0.15Al0.15O2 and LixNi0.90Mn0.10O2 (x = 0.50 and 0.30). Comparison with LixNi1.02O2 and LixNi0.89Al0.16O2. Chem Mater 15:4484–4493CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Chunhui Cao
    • 1
    • 2
  • Jian Zhang
    • 1
    Email author
  • Xiaohua Xie
    • 1
  • Baojia Xia
    • 1
  1. 1.Research Center for New Energy TechnologyShanghai Institute of Microsystem and Information TechnologyShanghaiChina
  2. 2.University of Chinese Academy of SciencesBeijingChina

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