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In situ fabrication of flaky-like NiMn-layered double hydroxides as efficient catalyst for Li-O2 battery

  • Xiaofei WangEmail author
  • Xuedan Hou
  • Qian Wang
  • Wanyin Ge
  • Shouwu Guo
Original Paper
  • 26 Downloads

Abstract

Layered double hydroxide (LDH)-based catalysts have emerged as one of the most promising catalysts due to their unique layered structure, compositional flexibility, low cost, and easy synthesis. Herein, NiMn-LDH was in situ incorporated with carbon black (CB) via a facile hydrothermal method, and the morphology of the LDHs tended to be small-sized flaky-like from large bulk flower-like with the increasing amount of CB. The fabricated 50CB/NiMn-LDH cathode tended to induce the poorly crystalline film–like Li2O2 to form, indicating the significant effect of NiMn-LDH flake on the surface redox reaction. The lithium-oxygen (Li-O2) battery with 50CB/NiMn-LDH cathode exhibited improved capacity output (5684 vs 2682 mAh g−1), low overpotential (1.49 vs 1.62 V), and stable cyclability (35th vs 15th). The present synthetic strategy is very simple and low cost and can be easily extended to other LDH-based materials with significant effect.

Keywords

Li-O2 battery Electrochemical performance Catalyst Layered double hydroxides 

Notes

Funding information

This study is supported by the National Natural Science Foundation of China (No. 51608412), the Natural Science Basic Research Plan in Shaanxi Province of China (No. 2016JQ2034), the Scientific Research Fund of Shaanxi University of Science and Technology (No. 2016BJ-48), the Special Fund Project of Education Department in Shaanxi Province of China (No. 17JK0086), and the Science and Technology Department Foundation of Shaanxi Province (No. 2016GY-199).

References

  1. 1.
    Han H, Jeon Y, Liu Z, Song T (2018) Highly graphitic carbon nanofibers web as a cathode material for lithium-oxygen batteries. Appl Sci 8:1–9Google Scholar
  2. 2.
    Zhang P, Zhao Y, Zhang X (2018) Functional and stability orientation synthesis of materials and structures in aprotic Li-O2 batteries. Chem Soc Rev 47(8):2921–3004CrossRefGoogle Scholar
  3. 3.
    Chang ZW, Meng FL, Zhong HX, Zhang XB (2018) Anchoring iron-EDTA complex on graphene toward the synthesis of highly efficient Fe-N-C oxygen reduction electrocatalyst for fuel cells. Chin J Chem 36(4):287–292CrossRefGoogle Scholar
  4. 4.
    Li F, Chen Y, Tang D-M, Jian Z, Liu C, Golberg D, Yamada A, Zhou H (2014) Performance-improved Li-O2 battery with Ru nanoparticles supported on binder-free multi-walled carbon nanotube paper as cathode. Energy Environ Sci 7(5):1648–1652CrossRefGoogle Scholar
  5. 5.
    Yang ZD, Chang ZW, Zhang Q, Huang K, Zhang XB (2018) Decorating carbon nanofibers with Mo2C nanoparticles towards hierarchically porous and highly catalytic cathode for high-performance Li-O2 batteries. Sci Bull 63:433–440CrossRefGoogle Scholar
  6. 6.
    Xu JJ, Chang ZW, Yin YB, Zhang XB (2017) Nanoengineered ultralight and robust all-metal cathode for high-capacity, stable lithium–oxygen batteries. ACS Cent Sci 3(6):598–604CrossRefGoogle Scholar
  7. 7.
    Liu QC, Jiang YS, Xu JJ, Xu D, Chang ZW, Yin YB, Liu WQ, Zhang AB (2015) Hierarchical Co3O4 porous nanowires as an efficient bifunctional cathode catalyst for long life Li-O2 batteries. Nano Res 8(2):576–583CrossRefGoogle Scholar
  8. 8.
    Kim J, Jo H, Wu M, Yoon DH, Kang Y, Jung HK (2017) Mesoporous amorphous binary Ru-Ti oxides as bifunctional catalysts for non-aqueous Li-O2 batteries. Nanotechnology 28:1–7Google Scholar
  9. 9.
    Lee YJ, Park SH, Kim SH, Ko Y, Kang K, Lee YJ (2018) High-rate and high-areal-capacity air cathodes with enhanced cycle life based on RuO2/MnO2 bifunctional electrocatalysts supported on CNT for pragmatic Li-O2 batteries. ACS Catal 8(4):2923–2934CrossRefGoogle Scholar
  10. 10.
    Wang G, Zhang L, Zhang J (2012) A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev 41(2):797–828CrossRefGoogle Scholar
  11. 11.
    Xu C, Gallant BM, Wunderlich PU, Lohmann T, Greer JR (2015) Three-dimensional Au microlattices as positive electrodes for Li-O2 batteries. ACS Nano 9(6):5876–5883CrossRefGoogle Scholar
  12. 12.
    Lu YC, Xu Z, Gasteiger HA, Chen S, Hamad-Schifferli K, Yang SH (2010) Platinum-gold nanoparticles: a highly active bifunctional electrocatalyst for rechargeable lithium-air batteries. J Am Chem Soc 132(35):12170–12171CrossRefGoogle Scholar
  13. 13.
    Yang Y, Liu W, Wang YM, Wang XC, Xiao L, Lu JT, Zhuang L (2014) A PtRu catalyzed rechargeable oxygen electrode for Li-O2 batteries: performance improvement through Li2O2 morphology control. Phys Chem Chem Phys 16(38):20618–20623CrossRefGoogle Scholar
  14. 14.
    He S, An Z, Wei M, Evans DG, Duan X (2013) Layered double hydroxide-based catalysts: nanostructure design and catalytic performance. Chem Commun 49(53):5912–5920CrossRefGoogle Scholar
  15. 15.
    Zhao Y, Li B, Wang Q, Gao W, Wang CJ, Wei M, Evans DG, Duan X, O’Hare D (2014) Ni-Ti layered double hydroxides nanosheets as efficient photocatalysts for oxygen evolution from water using visible light. Chem Sci 5(3):951–958CrossRefGoogle Scholar
  16. 16.
    Ma R, Liu Z, Li L, Iyi N, Sasaki T (2006) Exfoliating layered double hydroxides in formamide: a method to obtain positively charged nanosheets. J Mater Chem 16(39):3809–3813CrossRefGoogle Scholar
  17. 17.
    Li M, Cheng JP, Wang J, Liu F, Zhang XB (2016) The growth of nickel-manganese and cobalt-manganese layered double hydroxides on reduced graphene oxide for supercapacitor. Electrochim Acta 206:108–115CrossRefGoogle Scholar
  18. 18.
    Guo Y, Zhu Z, Qiu Y, Zhao J (2013) Enhanced adsorption of acid brown 14 dye on calcined Mg/Fe layered double hydroxide with memory effect. Chem Eng J 219:69–77CrossRefGoogle Scholar
  19. 19.
    Ainara GG, Diana I, Veronica G, Mohamed M, Asiri AM, Basahel SN, Al-Thabaiti SA, Alyoubi AO, Chadwick D, Shaffer MS (2012) Graphene oxide as support for layered double hydroxides: enhancing the CO2 adsorption capacity. Chem Mater 24:4531–4539CrossRefGoogle Scholar
  20. 20.
    Huang S, Zhu GN, Zhang C, Tjiu WW, Xia YY, Liu T (2012) Immobilization of Co-Al layered double hydroxides on graphene oxide nanosheets: growth mechanism and supercapacitor studies. ACS Appl Mater Interfaces 4(4):2242–2249CrossRefGoogle Scholar
  21. 21.
    Zhang L, Wang J, Zhu J, Zhang X, Hui KS, Hui KN (2013) 3D porous layered double hydroxides grown on graphene as advanced electrochemical pseudocapacitor materials. J Mater Chem A 1(32):9046–9053CrossRefGoogle Scholar
  22. 22.
    Chitravathi S, Kumar S, Munichandraiah N (2016) NiFe-layered double hydroxides: a bifunctional O2 electrode catalyst for non-aqueous Li-O2 batteries. RSC Adv 6(105):103106–103115CrossRefGoogle Scholar
  23. 23.
    Liu Y, Liu Y, Shi H, Wang M, Cheng SH-S, Bian H, Kamruzzaman M, Cao L, Chung CY, Lu Z (2016) Cobalt-copper layered double hydroxide nanosheets as high-performance bifunctional catalysts for rechargeable lithium-air batteries. J Alloys Compd 688:380–387CrossRefGoogle Scholar
  24. 24.
    Sumboja A, Chen J, Zong Y, Lee PS, Liu Z (2016) NiMn layered double hydroxides as efficient electrocatalysts for the oxygen evolution reaction and their application in rechargeable Zn-air batteries. Nanoscale 9:774–780CrossRefGoogle Scholar
  25. 25.
    Dastan D, Banpurkar A (2017) Solution processable sol–gel derived titania gate dielectric for organic field effect transistors. J Mater Sci Mater Electron 28(4):3851–3859CrossRefGoogle Scholar
  26. 26.
    Akhundi A, García-López EI, Marcì G, Habibi-Yangjeh A, Palmisano L (2017) Comparison between preparative methodologies of nanostructured carbon nitride and their use as selective photocatalysts in water suspension. Res Chem Intermed 43(9):5153–5168CrossRefGoogle Scholar
  27. 27.
    Dastan D, Chaure N, Kartha M (2017) Surfactants assisted solvothermal derived titania nanoparticles: synthesis and simulation. J Mater Sci Mater Electron 28(11):7784–7796CrossRefGoogle Scholar
  28. 28.
    Dastan D, Leila Panahi S, Yengntiwar AP, Banpurkar AG (2016) Morphological and electrical studies of titania powder and films grown by aqueous solution method. Adv Sci Lett 22(4):950–953CrossRefGoogle Scholar
  29. 29.
    Chen H, Chang X, Chen D, Liu J, Liu P, Xue Y, Lin H, Han S (2016) Graphene-karst cave flower-like Ni-Mn layered double oxides nanoarrays with energy storage electrode. Electrochim Acta 220:36–46CrossRefGoogle Scholar
  30. 30.
    Dastan D, Londhe PU, Chaure NB (2014) Characterization of TiO2 nanoparticles prepared using different surfactants by sol-gel method. J Mater Sci Mater Electron 25(8):3473–3479CrossRefGoogle Scholar
  31. 31.
    Dastan D, Panahi SL, Chaure NB (2016) Characterization of titania thin films grown by dip-coating technique. J Mater Sci Mater Electron 27(12):12291–12296CrossRefGoogle Scholar
  32. 32.
    Dastan D, Chaure NB (2014) Influence of surfactants on TiO2 nanoparticles grown by sol-gel technique. J Mater Mech Manufact 2:21–24Google Scholar
  33. 33.
    Lv L, Xu K, Wang C, Wan H, Ruan Y, Liu J, Zhou R, Miao L, Ostrikov K, Lan Y, Jiang J (2016) Intercalation of glucose in NiMn-layered double hydroxide nanosheets: an effective pathway towards battery-type electrodes with enhanced performance. Electrochim Acta 216:35–43CrossRefGoogle Scholar
  34. 34.
    Wang X, Wang Q, Hou X, Liu Y, Zheng P, Huo J, Yin L, Guo S (2018) Facile fabrication of two-dimensional reduced graphene oxide/CoAl-layered double hydroxides nanocomposites for lithium-oxygen battery with improved electrochemical performance. J Alloys Compd 744:196–203CrossRefGoogle Scholar
  35. 35.
    Dastan D (2017) Effect of preparation methods on the properties of titania nanoparticles: solvothermal versus sol-gel. Appl Phys A 123:1–13CrossRefGoogle Scholar
  36. 36.
    Kovanda F, Grygar T, Dornik V (2003) Thermal behaviour of Ni-Mn layered double hydroxide and characterization of formed oxides. Solid State Sci 5(7):1019–1026CrossRefGoogle Scholar
  37. 37.
    Meini S, Piana M, Tsiouvaras N, Garsuch A, Gasteiger HA (2012) The effect of water on the discharge capacity of a non-catalyzed carbon cathode for Li-O2 batteries. Electrochem Solid-State Lett 15(4):A45–A48CrossRefGoogle Scholar
  38. 38.
    Radin MD, Siegel DJ (2013) Charge transport in lithium peroxide: relevance for rechargeable metal-air batteries. Energy Environ Sci 6(8):2370–2379CrossRefGoogle Scholar
  39. 39.
    Wang X, Cai S, Zhu D, Chen YG (2015) Enhanced electrochemical performance of Li-O2 battery based on modifying the solid-state air cathode with Pd catalyst. RSC Adv 107:88485–88491CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.School of Materials Science and EngineeringShaanxi University of Science and TechnologyXi’anChina
  2. 2.School of Materials Science and Chemical EngineeringXi’an Technological UniversityXi’anChina
  3. 3.Department of Electronic Engineering, School of Electronic Information and Electrical EngineeringShanghai Jiao Tong UniversityShanghaiChina

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