Journal of Solid State Electrochemistry

, Volume 23, Issue 2, pp 497–502 | Cite as

Analysis of discrete spectra of electrochemical noise of lithium power sources

  • A. L. Klyuev
  • B. M. GrafovEmail author
  • A. D. Davydov
  • V. P. Lukovtsev
  • E. M. Petrenko
Original Paper


The Fourier, Daubechies, and Chebyshev transforms are used to analyze discrete spectra of electrochemical noise of lithium power sources under the open-circuit conditions. In the absence of trend of open-circuit voltage, all three approaches lead to similar estimates of intensity of discrete spectra of electrochemical noise of lithium power sources. A trend of open-circuit voltage has different effects on the Fourier, Daubechies, and Chebyshev spectra. The Fourier spectrum is most sensitive to a trend of open-circuit voltage; the Chebyshev spectrum is most resistant to the trend. The Daubechies spectrum occupies an intermediate position between the Fourier spectrum and the Chebyshev spectrum in the resistance to the trend of open-circuit voltage.


Lithium power sources Electrochemical noise Trend of open-circuit voltage Fourier discrete noise spectra Daubechies discrete noise spectra Chebyshev discrete noise spectra 


Funding information

This work was partially supported by the Russian Foundation for Basic Research, project no. 16-29-09375.


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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • A. L. Klyuev
    • 1
  • B. M. Grafov
    • 1
    Email author
  • A. D. Davydov
    • 1
  • V. P. Lukovtsev
    • 1
  • E. M. Petrenko
    • 1
  1. 1.Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussia

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