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Electrochemical deposition of cabbage-like lead microstructures on fluorine-doped tin oxide for oxygen sensor application

  • Dharini Bhagat
  • Manmohansingh Waldiya
  • Indrajit Mukhopadhyay
Original Paper
  • 17 Downloads

Abstract

Metallic lead (Pb) has been electrodeposited on FTO substrate at room temperature from aqueous nitrate solution under constant applied potential in the range of − 0.46 to − 0.8 V vs. SCE. Cyclic voltammetry shows that 3D nucleation and growth are the main feature at higher electrolyte concentration when the profile is recorded at 20 mVs−1. While a single step potential facilitates the deposition of faceted crystals of Pb, distinguished lead having cabbage-like morphology can be deposited by applying sequential two step potentials. The I-t response shows that the deposition is initiated through instantaneous 2D nucleation and growth at the shorter time domain followed by 3D nucleation and growth in 0.4 M Pb(NO3)2. Theoretical simulation of the closely matched experimental I-t profile for simple step potential provides a 2D rate constant of 2.00 ± 0.04 × 10−7 mol cm−2 s−1 while for 3D, the vertical and plane growth rate constant of 3.27 ± 0.05 × 10−5 mol cm−2 s−1 and 2.00 ± 0.04 × 10−7 mol cm−2 s−1, respectively. The formation of the cabbage morphology has been discussed on the basis of time evaluation of FE-SEM. The high surface area of unique lead deposits with cabbage morphology shows better life time and oxygen sensitivity in a typical oxygen sensor application.

Graphical abstract

Keywords

Lead metal Electrodeposition Nucleation and growth Oxygen sensor Pre-nucleated surface Cabbage-like morphology 

Notes

Acknowledgements

The authors would like to acknowledge Solar Research & Development Centre (SRDC), Pandit Deendayal Petroleum University (PDPU), for providing the technical and financial assistance.

Funding information

Financial support from the Department of Science and Technology (DST), Government of India, (Project number SR/S1/PC-44/2011), is deeply acknowledged to carry out this whole investigation.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest

References

  1. 1.
    Delayen J, Dick G, Mercereau J (1981) Test of a ß≃ 0.1 superconducting split ring resonator. IEEE Trans Magn 17(1):939–942CrossRefGoogle Scholar
  2. 2.
    Pavlov D (1993) Premature capacity loss (PCL) of the positive lead/acid battery plate: a new concept to describe the phenomenon. J Power Sources 42(3):345–363CrossRefGoogle Scholar
  3. 3.
    Avellaneda CO, Napolitano MA, Kaibara EK, Bulhões LOS (2005) Electrodeposition of lead on ITO electrode: influence of copper as an additive. Electrochim Acta 50(6):1317–1321CrossRefGoogle Scholar
  4. 4.
    Rashkova B, Guel B, Pötzschke RT, Staikov G, Lorenz WJ (1998) Electrodeposition of Pb on n-Si (111). Electrochim Acta 43(19-20):3021–3028CrossRefGoogle Scholar
  5. 5.
    Mukhopadhyay I, Raghavan MSS, Sharon M, Minoura H, Veluchamy P (1994) Photoelectrochemical studies of photoactive lead oxide prepared by the “potential pulse coupled potentiodynamic anodization technique” in alkaline medium. J Electroanal Chem 379(1-2):531–534CrossRefGoogle Scholar
  6. 6.
    Patel DB, Mukhopadhyay I (2015) Schottky junction solar cells based on non-stoichiometric PbO x films. J Phys D Appl Phys 48(2):025102CrossRefGoogle Scholar
  7. 7.
    Willett M (2014) Oxygen sensing for industrial safety - evolution and new approaches. Sensors 14(4):6084–6103CrossRefGoogle Scholar
  8. 8.
    Winand R (1994) Electrodeposition of metals and alloys—new results and perspectives. Electrochim Acta 39(8-9):1091–1105CrossRefGoogle Scholar
  9. 9.
    Ghali E, Girgis M (1985) Electrodeposition of lead from aqueous acetate and chloride solutions. Metall Trans B 16(3):489–496CrossRefGoogle Scholar
  10. 10.
    Mostany J, Parra J, Scharifker BR (1986) The nucleation of lead from halide-containing solutions. J Appl Electrochem 16(3):333–338CrossRefGoogle Scholar
  11. 11.
    Mostany J, Mozota J, Scharifker BR (1984) Three-dimensional nucleation with diffusion controlled growth: Part II. The nucleation of lead on vitreous carbon. J Electroanal Chem Interfacial Electrochem 177(1-2):25–37CrossRefGoogle Scholar
  12. 12.
    Popov KI, Stojilković ER, Radmilović V, Pavlović MG (1997) Morphology of lead dendrites electrodeposited by square-wave pulsating overpotential. Powder Technol 93(1):55–61CrossRefGoogle Scholar
  13. 13.
    Danilov FI, Protsenko VS, Vasil’eva EA, Kabat OS (2011) Antifriction coatings of Pb–Sn–Cu alloy electro-deposited from methanesulphonate bath. Trans IMF 89(3):151–115CrossRefGoogle Scholar
  14. 14.
    Wong SM, Abrantes LM (2005) Lead electrodeposition from very alkaline media. Electrochim Acta 51(4):619–626CrossRefGoogle Scholar
  15. 15.
    Carlos IA, Siqueira JLP, Finazzi GA, De Almeida MRH (2003) Voltammetric study of lead electrodeposition in the presence of sorbitol and morphological characterization. J Power Sources 117(1-2):179–186CrossRefGoogle Scholar
  16. 16.
    Carlos IA, Matsuo TT, Siqueira JLP, De Almeida MRH (2004) Voltammetric and morphological study of lead electrodeposition on copper substrate for application of a lead–acid batteries. J Power Sources 132(1-2):261–265CrossRefGoogle Scholar
  17. 17.
    Gu Y-Y, Zhou Q-H, Yang T-Z, Wei LIU, Zhang D-C (2011) Lead electrodeposition from alkaline solutions containing xylitol. Trans Nonferrous Met Soc China 21(6):1407–1413CrossRefGoogle Scholar
  18. 18.
    Bhatt AI, Bond AM, Zhang J (2007) Electrodeposition of lead on glassy carbon and mercury film electrodes from a distillable room temperature ionic liquid, DIMCARB. J of Solid State Electrochem 11(12):1593–1603CrossRefGoogle Scholar
  19. 19.
    Katayama Y, Fukui R, Miura T (2013) Electrodeposition of Lead from 1-butyl-1-methylpyrrolidinium Bis (trifluoromethylsulfonyl) amide Ionic Liquid. J Electrochem Soc 160(6):D251–D255CrossRefGoogle Scholar
  20. 20.
    Nikolić ND, Branković G, Lačnjevac UČ (2011) Formation of two-dimensional (2D) lead dendrites by application of different regimes of electrolysis. J Solid State Electrochem 16:2121–2126CrossRefGoogle Scholar
  21. 21.
    Nikolić ND, Ivanović ER, Branković G, Lačnjevac UČ, Stevanović SI, Stevanović JS, Pavlović MG (2015) Electrochemical and crystallographic aspects of lead granular growth. Metall Mater Trans B Process Metall Mater Process Sci 46(4):1760–1774CrossRefGoogle Scholar
  22. 22.
    Fletcher S (1983) Some new formulae applicable to electrochemical nucleation/growth/collision. Electrochim Acta 28(7):917–923CrossRefGoogle Scholar
  23. 23.
    O’M Bockris AKNR J, Aldeco MG (2000) Modern electrochemistry, vol 2. Kluwer Academic Publishers, New YorkGoogle Scholar
  24. 24.
    Jaya S, Prabhakarrao G, Prasadarao T (1986) Bull Electrochem 2(1):65–68Google Scholar
  25. 25.
    Hills GJ, Schiffrin DJ, Thompson J (1974) Electrochemical nucleation from molten salts—I. Diffusion controlled electrodeposition of silver from alkali molten nitrates. Electrochim Acta 19(11):657–670CrossRefGoogle Scholar
  26. 26.
    Bewick A, Fleischmann M, Thirsk HR (1962) Kinetics of the electrocrystallization of thin films of calomel. Trans Faraday Soc 58:2200–2216CrossRefGoogle Scholar
  27. 27.
    Armstrong RD, Fleischmann M, Thirsk HR (1966) The anodic bbhaviour of mercury in hydroxide ion solutions. J Electroanal Chem 11(3):208–223Google Scholar
  28. 28.
    Cobianu C, Serban B, Avramescu V, Hobbs B, Pratt K, Willett M (2012) Lifetime considerations for lead-free oxygen galvanic sensors. Ann Acad Romanian Sci 5:7–8Google Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Solar Research and Development Centre, Department of Solar EnergyPandit Deendayal Petroleum UniversityGandhinagarIndia

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