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Improving lithium–sulfur battery performances by using conjugative porous polymer as the sulfur support: the case of N-containing porous aromatic framework 41

  • Qian Wang
  • Haiyan Gao
  • Qi Cui
  • Keke Wu
  • Feiyan Hao
  • Jianguo Yu
  • Yongnan Zhao
  • Young-Uk Kwon
Original Paper

Abstract

N-containing porous aromatic framework 41 (PAF-41) with hierarchical porous structure has been readily synthesized through AlCl3 catalyzed Scholl reaction by using triphenylamine as the monomer. The extended skeleton of PAF-41 is constructed by N-bridged biphenyl groups to generate a consecutive conjugative electronic structure. The hierarchical porous skeleton and the presence of N atoms effectively confine the electroactive species by synergistic physisorption and chemisorption to alleviate the shuttle effect that is induced by the soluble polysulfides. These features render the sulfur impregnated PAF-41 (SPAF-41) improved lithium–sulfur battery performances, especially the cycling stability. SPAF-41 composite cathode with high sulfur loading of 72 wt% exhibits enhanced rate capability and excellent cycling performance. The cell delivers a high capacity of 725.8 mAh g−1 at 0.5 °C in the first cycle and sustains a reversible capacity of 491.4 mAh g−1 after 500 charge–discharge cycles. A low decay rate of 0.06% per cycle is achieved. The well conductive PAF-41 support bestows the cell high Coulombic efficiency of 97.36%.

Keywords

N-containing Porous aromatic frameworks Lithium–sulfur batteries Cycling stability 

Notes

Funding information

This research is financially supported by Natural Science Foundations of China (No. 21271138 and 21703152) and Natural Science Foundations of Tianjin (No. 17JCQNJC06100 and 17JCTPJC47300).

Supplementary material

10008_2018_4166_MOESM1_ESM.docx (234 kb)
ESM 1 (DOCX 234 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Qian Wang
    • 1
  • Haiyan Gao
    • 1
  • Qi Cui
    • 1
  • Keke Wu
    • 1
  • Feiyan Hao
    • 1
  • Jianguo Yu
    • 1
  • Yongnan Zhao
    • 1
  • Young-Uk Kwon
    • 1
    • 2
  1. 1.Tianjin Key Laboratory of Advanced Fibers and Energy Storage Technology, School of Material Science and EngineeringTianjin Polytechnic UniversityTianjinChina
  2. 2.Department of ChemistrySungkyunkwan UniversitySuwonKorea

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