Redox reactivity at silver microparticle—glassy carbon contacts under a coating of polymer of intrinsic microporosity (PIM)
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Silver microparticles (ca. 1 μm average size clustered into cage-like aggregates of 10–20 μm diameter) are shown to adhere to a glassy carbon electrode surface to give voltammetric current responses, which are considerably enhanced/stabilised when applying a coating with a molecularly rigid polymer of intrinsic microporosity (PIM-EA-TB). In preliminary voltammetric experiments characteristic Ag(0/I) surface oxidation and back-reduction processes are observed in aqueous phosphate buffer (associated with silver phosphate layer formation on the silver surface). In contrast to the oxidation, which is dominated by a nucleation process causing a sharp well-defined current signal, for the back-reduction stochastic current responses are observed possibly associated with density fluctuations in the surrounding liquid phase (“Brownian activation”) as an essential part of the mechanism of conversion of surface-oxidised silver back to silver metal.
KeywordsMicroparticle Polymer membrane Brownian motion Stochastic Catalysis
Voltammetric analysis of microparticles  has been developed as analytical tool in the study of redox-active materials which are “mechanically attached”  or adhered  or simply deposited from solution onto suitable electrode surfaces. For silver-based materials, voltammetric microparticle analysis has been applied to silver tarnish products and silver alloys . In recent work on silver nanoparticle electrochemistry in solution, the “impact” of these nanoparticles  and the resulting redox conversion  were employed to obtain nanoparticle size, shape , and reactivity  information. Due to the small size of these nanoparticles (and the appropriate choice of reaction conditions) complete/quantitative conversion of silver to soluble or insoluble species is usually possible . In contrast, for macroscopic silver samples, for example a silver wire or silver-coated textiles, in contact to a glassy carbon electrode surface , more complex behaviour has been reported with incomplete conversion and formation of an electrically insulating layer between silver metal and electrode surface. The electrical contact of metallic silver to the underlying glassy carbon electrode has been shown to be broken during oxidation when an insulating film is produced. As a result, only a small amount of the available silver was oxidised . The back-reduction to metallic silver was suggested to be associated with nucleation of silver metal on glassy carbon and a “re-connection” from glassy carbon to the metallic silver-coated textile. Very similar processes are observed here for silver microparticles immobilised at a glassy carbon electrode surface and immersed in aqueous electrolyte media.
The application of a polymer of intrinsic microporosity (PIM) as new class of molecularly rigid and microporous ion-conducting materials in electrochemistry has been suggested recently . It has been demonstrated that metal nanoparticle catalysts can be PIM-coated and thereby protected against poisoning  and against detrimental loss and corrosion processes . Here, we employ an intrinsically microporous polymer (PIM) material based on an ethano-anthracene (EA) building block that was synthesised employing a Tröger base (TB) method (PIM-EA-TB , see molecular structure in Fig. 1b). This polymer material exhibits 70 kDa average molecular weight and N2-adsorption surface area of typically 1027 m2 g−1 . The inherent microporosity of PIM-EA-TB allows ion and small molecule transport without inhibiting the electrode reaction . The rigid molecular structure ensures a stable attachment of the microparticles to the electrode surface as well as sufficient access of electrolyte through the microporous film.
In this study, silver microparticles are investigated at glassy carbon electrode surfaces and when immersed into aqueous phosphate buffer solution. During oxidation, silver microparticles are shown to only react partially (similar to silver wire in contact to glassy carbon ) due to surface coating with an insulating silver phosphate film. The process is chemically reversible, and after back reduction, the silver microparticles remain at the electrode surface (protected by a PIM-EA-TB film). Stochastic events during the reduction are suggested to be associated with activation by interfacial momentum transfer from Brownian motion in the liquid phase.
Chloroform, isopropanol, sodium hydroxide, and phosphoric acid (85%) were purchased from Aldrich and used without further purification. PIM-EA-TB was prepared following a literature recipe . Solutions were prepared with filtered and deionised water of resistivity 18.2 MΩ cm from a Thermo Scientific water purification system (ELGA).
A μAutolab III system (Ecochemie, NL) was employed for electrochemical measurements in a conventional three-electrode cell with a platinum wire counter electrode and a KCl-saturated calomel (SCE) reference (Radiometer, Kopenhagen). All experiments were performed with a 3-mm-diameter glassy carbon electrode (Bioanalytical Systems, IN, USA). Morphology of the silver sample was analysed with a JEOL FESEM6301F scanning electron microscope (SEM).
Silver microparticles synthesis
The synthesis of Ag microparticles is based on the non-hydrolytic sol-gel method [18, 19] that has been recently applied for the synthesis of Ag antimicrobial coatings [20, 21]. Briefly, 642 mg of silver acetate (99%, Aldrich) along with 20 cm3 of benzylamine (99%, Aldrich) were used for the synthesis of the particles. The result mixture was transferred into a stainless steel autoclave and heated at 200 °C for 48 h. The resulting suspension was centrifuged and the silver microparticles separated as precipitate, thoroughly washed with ethanol, and subsequently dried in air at 70 °C.
Procedures for electrode preparation
Electrodes were prepared by drop casting. A weight of 4 mg of Ag microparticles was dispersed in 1 mL of isopropanol. After sonication for 15 min, the prepared suspension was loaded onto a glassy carbon (GC) disk electrode with a diameter of 3 mm. The silver layer was allowed to dry under ambient conditions before electrochemical measurements. The PIM-Ag samples were prepared by coatings with PIM-EA-TB on Ag. A solution of 1 mg mL−1 PIM-EA-TB in chloroform was applied directly onto the Ag microparticle layer followed by drying under ambient conditions.
Results and discussion
The area under the oxidation peak suggests approximately 5 μC charge has passed, which corresponds to only 0.2% of the silver present. When applying a film of 4 μg PIM-EA-TB from a chloroform solution over the silver microparticles on the glassy carbon surface, the oxidation signal in the voltammogram can be improved by one order of magnitude in terms of charge (see Fig. 3a). The PIM-EA-TB polymer is proposed to act here as a porous matrix that allows oxidation and reduction to occur whilst stopping losses due to dislodged silver microparticles. As a result, voltammetric responses for the silver microparticles are more stable and repeatable. Within the potential range studied here PIM-EA-TB has no direct electrochemical activity [13, 14] and it can be considered both cation and anion conducting . Generally, with the PIM-EA-TB coating applied features such as the position of oxidation and back-reduction voltammetric responses are maintained and also the complex peak shape observed during the reduction is retained. Figure 3b shows how the amount of PIM-EA-TB deposited over the electrode surface affects the voltammetric responses. With approximately 4 μg polymer, a relatively stable/repeatable signal is obtained. Excess PIM-EA-TB leads to lowering of current responses. Therefore, in the following experiments, this amount of 4 μg polymer coating is kept constant.
The limiting current for the catalytic nitrate reduction is approximately linear to the nitrate concentration in the 1 to 100 mM concentration range indicative of a process that is not impeded by the PIM-EA-TB film coating. This behaviour confirms that the silver microparticles are active when immobilised on the glassy carbon electrode surface.
For all concentrations of phosphate buffer, significant randomness in the reduction signal is observed. This is most clearly seen for experiments in 0.01 M NaOH. Figure 5b shows a multi-cycle voltammetric experiment performed in pH 12 NaOH solution showing the stochastic nature of the reduction current peaks, which occur around 0.0 V vs. SCE and with an average charge complementary to that observed for the oxidation peak, however, in short “bursts” which may be linked to individual particles or regions on the electrode surface “re-connecting” to the silver microparticles. The trigger responsible for these processes could be associated at least in part with a density fluctuation in the liquid phase adjacent to the electrode surface or “Brownian activation”.
This type of phenomenon is closely linked to Brownian motion and the associated diffusional transport in the liquid phase. Brownian motion  as proposed by Einstein and by von Smoluchowski  is induced by natural fluctuations in the density of the liquid, which are comparable to the more collective fluctuations caused by lattice phonons in solid materials. Artificial Brownian motors  are of interest in nanoscale systems that exploit these density fluctuations. Brownian motion of objects at liquid/solid interfaces can affect the rate of physical processes such as electron transfer, but these effects require micron-sized particles to become apparent. The idea of “Brownian activation” has been postulated previously for example for the inter-nanoparticle electron transfer within hybrid films of redox active TiO2 nanoparticles . Related effects of Brownian motion at liquid/solid interfaces may also play a role in the voltammetry of “impact” processes [30, 31] where stochastic effects are assigned to bulk transport (motion) rather than to surface processes (activation).
For cyclic voltammograms shown in Fig. 5a, nucleation processes are believed to be responsible for the sharp oxidation peak observed during the oxidation of silver microparticles in the presence of phosphate buffer. In contrast, the reduction is governed by a stochastic process with multiple events that occur of a period of time. When scanning the potential of the electrode more quickly, these current responses distribute to more negative potentials indicative either (i) of irreversible electron transfer (microscopic) and/or (ii) irreversible activation of microparticles (macroscopic). The stochastic nature of “Brownian activation” is suggested to be associated with these processes but further investigation of the mechanism will be necessary.
Summary and conclusion
an improved voltammetric response for silver microparticles was observed when deposits at the electrode surface are mechanically stabilised against loss and dislodgment with the PIM-EA-TB coating and
the voltammetric characteristics (apart from the magnitude of the current) for the silver microparticles immersed in aqueous electrolyte media at pH 12 are not affected by the PIM-EA-TB polymer coating for the oxidation of silver, the back reduction to silver metal, and for the catalytic reduction of nitrate to nitrite; the PIM-EA-TB film is sufficiently permeable for both cations and anions under these conditions;
for the Ag(I/0) reduction, the stochastic nature of voltammetric current responses suggests that natural density fluctuations at the glassy carbon | silver microparticle interface (Brownian activation) could be the trigger to voltammetric responses.
These are preliminary findings and further work and optimisation of processes and peak appearances will be possible adjusting parameters such as ionic strength, pH, and phosphate concentration. Potential applications of the stochastic voltammetric response may be in electroanalysis (e.g. when traces of chemical species could trigger or suppress the current spikes). The beneficial application of PIM-EA-TB as an intrinsically microporous coating in microparticle voltammetry could be of interest in a wider range of electroanalytical applications and in particular in electrocatalysis with immobilised microparticle catalysts.
D.H. thanks the Royal Society for a Newton Fellowship. F.M. and N.B.M. thank the Leverhulme Foundation for the financial support (RPG-2014-308). E.R. thanks the Estonian Research Council (Grant PUT431) and the European Regional Development Fund project TK134 (TAR16019) for the financial support.
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