Journal of Solid State Electrochemistry

, Volume 20, Issue 11, pp 3071–3081 | Cite as

Glassy carbon electrode modified with hemin and new melamine compounds for H2O2 amperometric detection

  • Aglaia Raluca Deac
  • Cristina Morar
  • Graziella Liana Turdean
  • Mircea Darabantu
  • Emese Gál
  • Attila Bende
  • Liana Maria Muresan
Original Paper

Abstract

In an attempt to increase the stability and efficiency of hemin-modified electrodes, the present work reports the preparation of a new modified glassy carbon electrode obtained by immobilization of hemin (Hm) on the electrode surface together with a new N-substituted melamine (2,4,6-triamino-1,3,5-triazine) based G-2 dendrimer comprising p-aminophenol as peripheral unit (Den) or with one of its analogues, a melamine G-0 dimer (Dim). Basic structural features, able to determine intimate relationships between Hm and Dim (or Den) at room temperature in solid state, were evidenced with the use of vibrational analysis carried out by FT-IR. This method revealed contacts between Hm and Dim or Den respectively as H-bond interactions, proton-interchange, and π-π stacking interactions. The new modified electrodes were characterized by cyclic voltammetry and electrochemical impedance spectroscopy and tested for amperometric detection of H2O2. In this purpose, GC/Hm-Dim electrode exhibited better catalytic properties than GC/Hm-Den electrode, but lower stability.

Keywords

Hemin-modified electrodes Dendritic melamines Cyclic voltammetry Electrochemical impedance spectroscopy Amperometric detection of H2O2 

Supplementary material

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Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Aglaia Raluca Deac
    • 1
  • Cristina Morar
    • 2
  • Graziella Liana Turdean
    • 1
  • Mircea Darabantu
    • 2
  • Emese Gál
    • 3
  • Attila Bende
    • 4
  • Liana Maria Muresan
    • 1
  1. 1.Department of Chemical Engineering“Babes-Bolyai” UniversityCluj-NapocaRomania
  2. 2.Department of Chemistry“Babes-Bolyai” UniversityCluj-NapocaRomania
  3. 3.Department of Chemistry and Chemical Engineering, Hungarian Line of Study“Babes-Bolyai” UniversityCluj-NapocaRomania
  4. 4.Molecular and Biomolecular Physics DepartmentNational Institute for Research and Development of Isotopic and Molecular TechnologiesCluj-Napoca 5Romania

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