Journal of Solid State Electrochemistry

, Volume 18, Issue 8, pp 2267–2277 | Cite as

Electrochemical behavior of silver thin films interfaced with yttria-stabilized zirconia

  • Michèle Fee
  • Spyridon Ntais
  • Arnaud Weck
  • Elena A. Baranova
Original Paper


Thin silver films (100–800 nm) were deposited by physical vapor deposition (PVD) on yttria-stabilized zirconia solid electrolyte. The electric percolation as a function of the film thickness was studied during deposition and annealing using a two-electrode in-situ resistance measurement technique. Electrical percolation was achieved in as-deposited films greater than 5.4 ± 0.4 nm; however, thermal treatment (550 °C in air) resulted in film dewetting for Ag films as thick as 500 nm and formation of electronically isolated Ag nanoparticles, as was confirmed by SEM and XPS. In thermally treated samples, stable electronic conductivity associated with a continuous percolated network was only observed in samples greater than 600 nm in thickness. The effect of polarization on the electrochemical reactions at the three-phase (electrode-gas-electrolyte) and two-phase (electrode-electrolyte) boundaries of the electrode was investigated by solid electrolyte cyclic voltammetry (SECV) at 350 °C and P O2 = 6 kPa. With the application of positive potential, silver oxide (Ag2O) was found to form along the three-phase boundary and then extends within the bulk of the electrode with increasing anodic potentials. By changing the hold time at positive potential, passivating oxide layers are formed which results in a shift in favor of the oxygen evolution reaction at the working electrode. This oxide forms according to a logarithmic rate expression with thick oxides being associated with decrease in current efficiency for subsequent oxide formation.


Silver Thin film PVD Yttria-stabilized zirconia Cyclic voltammetry Percolation 



Financial support from the Natural Science and Engineering Research Council (NSERC), Canada is gratefully acknowledged.


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Copyright information

© Springer-Verlag Berlin Heidelberg 2014

Authors and Affiliations

  • Michèle Fee
    • 1
  • Spyridon Ntais
    • 1
  • Arnaud Weck
    • 2
  • Elena A. Baranova
    • 1
  1. 1.Department of Chemical and Biological Engineering, Centre for Catalysis Research and Innovation (CCRI)University of OttawaOttawaCanada
  2. 2.Department of Mechanical EngineeringUniversity of OttawaOttawaCanada

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