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Journal of Solid State Electrochemistry

, Volume 18, Issue 5, pp 1215–1221 | Cite as

A flow system for hydrogen peroxide production at reticulated vitreous carbon via electroreduction of oxygen

  • Qian Li
  • Christopher Batchelor-McAuley
  • Nathan S. Lawrence
  • Robert S. Hartshorne
  • Charles J. V. Jones
  • Richard G. ComptonEmail author
Original Paper

Abstract

In this work, a reticulated vitreous carbon electrode (RVCE, 96.5 % porosity, 24 cm−1) was modified with 2-anthraquinonyl groups to electrocatalytically reduce dissolved oxygen in neutral aqueous solution (0.1 M phosphate buffer solution supported with 3 M potassium chloride, pH of 6.7) to hydrogen peroxide (H2O2) at 25 °C under atmospheric pressure. The obtained current density was ca. 3 mA cm−2. For the first time, the oxygen reduction was investigated on a novelly designed RVCE housed in a gravity-feed flow system. Fractional current conversions obtained on the RVC flow cell were compared and contrasted with those on a two-dimensional electrode, viz. a tubular flow electrode. The modified-on catalyst has the benefit in terms of easy separation of the product from the catalyst. The in situ generated low concentration of H2O2 provides potential applications to water purification processes and disinfection for water and food.

Keywords

Electrosynthesis of hydrogen peroxide Reticulated vitreous carbon Electrochemical oxygen reduction Hydrodynamic flow cell Anthraquinonyl surface modification 

Notes

Acknowledgments

We thank Schlumberger Cambridge Research Limited for funding the study.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2013

Authors and Affiliations

  • Qian Li
    • 1
  • Christopher Batchelor-McAuley
    • 1
  • Nathan S. Lawrence
    • 2
  • Robert S. Hartshorne
    • 2
  • Charles J. V. Jones
    • 1
  • Richard G. Compton
    • 1
    Email author
  1. 1.Department of Chemistry, Physical and Theoretical Chemistry LaboratoryOxford UniversityOxfordUK
  2. 2.Schlumberger Cambridge ResearchCambridgeUK

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