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Journal of Solid State Electrochemistry

, Volume 16, Issue 11, pp 3401–3421 | Cite as

Oxygen solid electrolyte coulometry (OSEC)

  • V. Vashook
  • J. Zosel
  • U. GuthEmail author
Review

Abstract

The development and utilization of solid electrolyte-based coulometric techniques for the investigation of different oxygen exchange processes of solids or liquids, oxygen or hydrogen permeability through membranes, and generation of gas flows with well-defined oxygen concentration is briefly reviewed. The method based on Faraday’s law may be used alternatively or additionally to thermogravimetry, gas chromatography, chemical analysis, spectroscopy, and X-ray or neutron diffractometry in a wide oxygen partial pressure region (10−20 to 105 Pa) unaffected by temperature. The detection limit of exchanged oxygen is determined by a current- and voltage-measuring technique and is now not lower than 50 ng for devices operating in carrier gas mode.

Keywords

Oxygen solid electrolyte coulometry Oxygen nonstoichiometry Oxygen permeability Oxygen concentration 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  1. 1.Dresden University of TechnologyDresdenGermany

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