Journal of Solid State Electrochemistry

, Volume 16, Issue 3, pp 1219–1228 | Cite as

Fabrication parameter-dependent morphologies of self-organized ZrO2 nanotubes during anodization

  • Dong Fang
  • Jingang Yu
  • Zhiping Luo
  • Suqin Liu
  • Kelong Huang
  • Weilin Xu
Original Paper

Abstract

Zirconia (ZrO2) nanotubes have been synthesized using a facile anodizing process in organic electrolyte systems containing a low content of fluoride. The nanotube architecture evolution was recorded at different anodization periods (1–24 h) by scanning electron microscopy. A compact layer was found between the Zr substrate and its upper tubular layer after 1 h of anodization, whereas after further anodization for 3 h the compact layer disappeared. Meanwhile, ZrO2 nanotubes turned to a uniform structure from top to bottom. However, after 18–24-h-long anodization, the uniform tubular layer was replaced by a random layer composed of various structural defects. Since the compact layer was not completely dissolved, the retained compact layer yielded O-rings with double walls on the outer surface of the nanotubes.

Keywords

Anodization Electron microscopy Fabrication parameter Mechanism Morphology ZrO2 nanotube 

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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • Dong Fang
    • 1
    • 2
  • Jingang Yu
    • 2
  • Zhiping Luo
    • 3
  • Suqin Liu
    • 2
  • Kelong Huang
    • 2
  • Weilin Xu
    • 1
  1. 1.Key Lab of Green Processing and Functional Textiles of New Textile Materials, Ministry of EducationWuhan Textile UniversityWuhanChina
  2. 2.College of Chemistry and Chemical EngineeringCentral South UniversityChangshaPeople’s Republic of China
  3. 3.Microscopy and Imaging Center and Materials Science and Engineering ProgramTexas A&M UniversityCollege StationUSA

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