Journal of Solid State Electrochemistry

, Volume 16, Issue 1, pp 117–126 | Cite as

Synthesis, characterization, and thermoelectric properties of a conducting copolymer of 1,12-bis(carbazolyl)dodecane and thieno[3,2-b]thiophene

  • Ruirui Yue
  • Shuai Chen
  • Congcong Liu
  • Baoyang Lu
  • Jingkun Xu
  • Jianmin Wang
  • Guodong Liu
Original Paper

Abstract

Poly(1,12-bis(carbazolyl)dodecane-co-thieno[3,2-b]thiophene) (P(2Cz-D-co-TT)), a conducting copolymer was synthesized electrochemically by direct anodic oxidation of 1,12-bis(carbazolyl)dodecane (2Cz-D) and thieno[3,2-b]thiophene (TT) in boron trifluoride diethyl ethrate containing 30% (vol) dichloromethane. As-formed copolymers exhibited high redox activity and reversibility and good conductive properties. The emitting property of as-formed copolymer was different from those of respective homopolymers, and could be tuned by changing the initiate monomer feed ratios. Thermoelectric investigations revealed that the electrical conductivities of as-obtained copolymer films were between 0.1 and 0.3 S cm−1 at ambient temperature, lower than that of polythieno[3,2-b]thiophene (PTT) (0.42 S cm−1) but two orders of magnitude higher than that of poly(1,12-bis(carbazolyl)dodecane) (P2Cz-D) (10−3 S cm−1). The Seebeck coefficients and the power factors of the copolymers were improved with different degrees compared with those of PTT and P2Cz-D. As expected, the thermoelectric performance of PTT and P2Cz-D were both improved through copolymerization, which may be beneficial to the exploration and investigation of novel organic thermoelectric materials.

Keywords

Conducting polymers Electrochemical copolymerization Thermoelectric material Polythiophene Polycarbazole 

Notes

Acknowledgements

NSFC (50963002, 51073074 and 60767001) are acknowledged for their financial supports.

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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • Ruirui Yue
    • 1
  • Shuai Chen
    • 1
  • Congcong Liu
    • 1
  • Baoyang Lu
    • 1
  • Jingkun Xu
    • 1
  • Jianmin Wang
    • 2
  • Guodong Liu
    • 2
  1. 1.Jiangxi Key Laboratory of Organic ChemistryJiangxi Science and Technology Normal UniversityNanchangChina
  2. 2.School of Communication and ElectronicsJiangxi Science and Technology Normal UniversityNanchangChina

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