Journal of Solid State Electrochemistry

, Volume 13, Issue 7, pp 1051–1061

The application of synchrotron techniques to the study of lithium-ion batteries

Review

Abstract

This paper gives a brief review of the application of synchrotron X-ray techniques to the study of lithium-ion battery materials. The two main techniques are X-ray absorption spectroscopy (XAS) and high-resolution X-ray diffraction (XRD). Examples are given for in situ XAS and XRD studies of lithium-ion battery cathodes during cycling. This includes time-resolved methods. The paper also discusses the application of soft X-ray XAS to do ex situ studies on battery cathodes. By applying two signal detection methods, it is possible to probe the surface and the bulk of cathode materials simultaneously. Another example is the use of time-resolved XRD studies of the decomposition of reactions of charged cathodes at elevated temperatures. Measurements were done both in the dry state and in the presence of electrolyte. Brief reports are also given on two new synchrotron techniques. One is inelastic X-ray scattering, and the other is synchrotron X-ray reflectometry studies of the surface electrode interface (SEI) on highly oriented single crystal lithium battery cathode surfaces.

References

  1. 1.
    Habib MA, Bockris JO’M (1984) J Electroanal Chem 180:287 doi:10.1016/0368-1874(84)83587-X CrossRefGoogle Scholar
  2. 2.
    Sayers DE, Stern EA, Lytle FW (1971) Phys Rev Lett 27:1204 doi:10.1103/PhysRevLett.27.1204 CrossRefGoogle Scholar
  3. 3.
    Yoon W-S, Grey CP, Balasubramanian M, Yang X-Q, Fischer DA, McBreen J (2004) Electrochem Solid-State Lett 7:A53 doi:10.1149/1.1643592 CrossRefGoogle Scholar
  4. 4.
    Yoon W-S, Balasubramanian M, Chung KY, Yang X-Q, McBreen J, Grey CP, Fischer DA (2005) J Am Chem Soc 127:17479 doi:10.1021/ja0530568 CrossRefGoogle Scholar
  5. 5.
    Yoon W-S, Paik Y, Yang X-Q, Balasubramanian M, McBreen J, Grey CP (2002) Electrochem Solid-State Lett 5:A263 doi:10.1149/1.1513001 CrossRefGoogle Scholar
  6. 6.
    Balasubramanian M, McBreen J, Davidson IJ, Whitfield PS, Kargina I (2002) J Electrochem Soc 149:A176 doi:10.1149/1.1431962 CrossRefGoogle Scholar
  7. 7.
    Ceder G, Chiang Y-M, Sadoway DR, Aydinol MK, Jang Y-I, Huang B (1998) Nature 392:694 doi:10.1038/33647 CrossRefGoogle Scholar
  8. 8.
    Yoon W-S, Kim K-B, Kim M-G, Lee M-K, Shin H-J, Lee J-M, Lee J-S, Yo C-H (2002) J Phys Chem B 106:2526 doi:10.1021/jp013735e CrossRefGoogle Scholar
  9. 9.
    Yoon W-S, Balasubramanian M, Yang X-Q, Fu Z, Fischer DA, McBreen J (2004) J Electrochem Soc 151:A246 doi:10.1149/1.1637896 CrossRefGoogle Scholar
  10. 10.
    Yoon W-S, Chung KY, McBreen J, Zaghib K, Yang X-Q (2004) Electrochem Solid-State Lett 9:A415 doi:10.1149/1.2216619 CrossRefGoogle Scholar
  11. 11.
    Yoon W-S, Balasubramanian M, Yang X-Q, McBreen J, Hanson J (2005) Electrochem Solid-State Lett 8:A83 doi:10.1149/1.1846714 CrossRefGoogle Scholar
  12. 12.
    Balasubramanian M, Johnson CS, Cross JO, Seidler GT, Fister TT, Stern EA, Hamner C, Mariager SO (2007) Appl Phys Lett 91:31904 doi:10.1063/1.2752755 CrossRefGoogle Scholar
  13. 13.
    Hightower A, Ahn CC, Fultz B, Rez P (2000) Appl Phys Lett 77:238 doi:10.1063/1.126936 CrossRefGoogle Scholar
  14. 14.
    Gibbs D, Ocko BM, Zehner DM, Mocherie SGJ (1988) Phys Rev B 38:7303 doi:10.1103/PhysRevB.38.7303 CrossRefGoogle Scholar
  15. 15.
    Ocko BM, Wang J (1990) Phys Rev Lett 68:1466 doi:10.1103/PhysRevLett.65.1466 CrossRefGoogle Scholar
  16. 16.
    Wang J, Robinson IK, Adzic RR (1998) Surf Sci 412–413:374 doi:10.1016/S0039-6028(98)00450-6 CrossRefGoogle Scholar
  17. 17.
    Samant MG, Toney MF, Borges GL, Blum L, Melroy OR (1988) Surf Sci Lett 193:L29 doi:10.1016/0039-6028(88)90314-7 CrossRefGoogle Scholar
  18. 18.
    Nagy Z, You H, Yonco RM, Melendres CA, Yun W, Maroni VA (1991) Electrochim Acta 36:209 doi:10.1016/0013-4686(91)85203-J CrossRefGoogle Scholar
  19. 19.
    Hirayama M, Sonoyama N, Abe T, Minoura M, Ito M, Mori D, Yamada A, Kanno R, Terashima T, Takano M, Tamura K, Mizuki JI (2007) J Power Sources 168:493 doi:10.1016/j.jpowsour.2007.03.034 CrossRefGoogle Scholar
  20. 20.
    Hirayama M, Sonoyama N, Ito M, Minoura M, Mori D, Yamada A, Tamura K, Mizuki JI, Kanno R (2007) J Electrochem Soc 154:A1065 doi:10.1149/1.2778853 CrossRefGoogle Scholar
  21. 21.
    Hirayama M, Sakamoto K, Hiraide T, Mori D, Yamada A, Kanno R, Sonoyama N, Tamura K, Mizuki JI (2007) Electrochim Acta 53:871 doi:10.1016/j.electacta.2007.07.074 CrossRefGoogle Scholar

Copyright information

© Springer-Verlag 2008

Authors and Affiliations

  1. 1.Department of Condensed Matter Physics and Materials ScienceBrookhaven National LaboratoryUptonUSA

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