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Journal of Solid State Electrochemistry

, Volume 11, Issue 7, pp 981–992 | Cite as

Electrochemistry and catalytic behavior of immobilized binuclear complexes of copper(II) and nickel(II) with Robson type ligand

  • Nataliya V. RoznyatovskayaEmail author
  • Veronika K. Laurinavichute
  • Galina A. Tsirlina
  • Vladimir M. Mirsky
Original Paper

Abstract

Various systems containing immobilized binuclear copper(II) and nickel(II) complexes with Robson type ligand ([M2L]Cl2) are studied and compared in relation to catalysis of hydrogen peroxide reduction. Molecular complexes adsorbed on mercury and gold, crystalline complexes immobilized in the carbon paste electrode, and complex species entrapped into polyphenol-modified gold electrodes are considered. Electrocatalysis is assumed to result from the formation of H2O2–[M2L]Cl2 adduct, not from mediating redox transformations. Possible geometry of the formed reaction layers supporting adduct formation is discussed.

Keywords

Binuclear copper macrocyclic complex Cyclic voltammetry Adsorption Carbon paste electrodes Electroreduction 

Notes

Acknowledgements

DAAD (German Academic Exchange Service) is acknowledged for the fellowship of N. Roznyatovskaya. This study is also supported partially by the Russian Foundation for Basic Research (grant 05-03-32 381a). We are grateful to the synthesis group of laboratory of Prof. Yu. A. Ustynyuk for providing us with reactants.

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Copyright information

© Springer-Verlag 2006

Authors and Affiliations

  • Nataliya V. Roznyatovskaya
    • 1
    Email author
  • Veronika K. Laurinavichute
    • 1
  • Galina A. Tsirlina
    • 1
  • Vladimir M. Mirsky
    • 2
  1. 1.Department of Electrochemistry, Faculty of ChemistryMoscow State UniversityMoscowRussia
  2. 2.Institute of Analytical Chemistry, Chemo- and BiosensorsUniversity of RegensburgRegensburgGermany

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