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Journal of Solid State Electrochemistry

, Volume 10, Issue 5, pp 293–319 | Cite as

Stress generation and fracture in lithium insertion materials

  • John Christensen
  • John Newman
Original Paper

Abstract

A mathematical model that calculates volume expansion and contraction and concentration and stress profiles during lithium insertion into and extraction from a spherical particle of electrode material has been developed. The maximum stress in the particle has been determined as a function of dimensionless current, which includes the charge rate, particle size, and diffusion coefficient. The effects of pressure-driven diffusion and nonideal interactions between the lithium and host material have also been described. The model predicts that carbonaceous particles will fracture in high-power applications such as hybrid-electric vehicle batteries.

Keywords

Lithium Radial Stress Partial Molar Volume Lithium Concentration Exchange Current Density 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

This work was supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of FreedomCAR and Vehicle Technologies of the US Department of Energy under Contract No. DE-AC02-05CH11231.

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Copyright information

© Springer-Verlag 2006

Authors and Affiliations

  1. 1.Department of Chemical EngineeringUniversity of CaliforniaBerkeleyUSA

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