Advertisement

Journal of Solid State Electrochemistry

, Volume 9, Issue 11, pp 717–731 | Cite as

Electrochemical studies of bi- and polymetallic complexes featuring acetylide based bridging ligands

  • Paul J. Low
  • Rachel L. Roberts
  • Richard L. Cordiner
  • František Hartl
Review

Abstract

Acetylide-based bridging ligands have been widely used in the preparation of complexes that display a degree of electronic interaction between metal-based redox groups located at the ligand termini. The electrochemical response of these systems has been selectively reviewed, with a focus on the variation in properties that accompany changes in the structure of the bridging ligand and the nature of the metal groups.

Keywords

Acetylide Metal complex Mixed-valence chemistry 

References

  1. 1.
    Allen GC, Hush NS (1967) Prog Inorg Chem 8:357Google Scholar
  2. 2.
    Robin MB, Day P (1967) Adv Inorg Radiochem 10:247Google Scholar
  3. 3.
    Hush NS (1985) Coord Chem Rev 64:135CrossRefGoogle Scholar
  4. 4.
    Prassides K (ed) (1991) Mixed valency systems—applications in chemistry, physics and biology. Kluwer, DordrechtGoogle Scholar
  5. 5.
    Crutchley RJ (1994) Adv Inorg Chem 41:273CrossRefGoogle Scholar
  6. 6.
    Astruc D (1995) Electron transfer and radical processes in transition metal chemistry. VCH, New YorkGoogle Scholar
  7. 7.
    Ward MD (1995) Chem Soc Rev 24:121CrossRefGoogle Scholar
  8. 8.
    Ceccon A, Santi S, Orian L, Bisello A (2004) Coord Chem Rev 248:683CrossRefGoogle Scholar
  9. 9.
    Long NJ, Williams CK (2003) Angew Chem Int Ed 42:2586CrossRefGoogle Scholar
  10. 10.
    Osella D, Milone L, Nervi C, Ravera M (1995) J Organomet Chem 488:1CrossRefGoogle Scholar
  11. 11.
    Bruce MI, Low PJ (2004) Adv Organomet Chem 50:179CrossRefGoogle Scholar
  12. 12.
    Kingsborough RP, Swager TM (1999) Prog Inorg Chem 48:123Google Scholar
  13. 13.
    Lang H (1994) Angew Chem Int Ed Engl 33: 547CrossRefGoogle Scholar
  14. 14.
    Lang H, George DSA, Rheinwald G (2000) Coord Chem Rev 206:101CrossRefGoogle Scholar
  15. 15.
    Bunz UHF, Rubin Y, Tobe Y (1999) Chem Soc Rev 28:107CrossRefGoogle Scholar
  16. 16.
    Bard A, Faulkner LR (1980) Electrochemical methods: fundamentals and applications. Wiley, New YorkGoogle Scholar
  17. 17.
    Cruetz C (1983) Prog Inorg Chem 30:1Google Scholar
  18. 18.
    Brunschwig BS, Cruetz C, Sutin N (2002) Chem Soc Rev 31:168CrossRefPubMedGoogle Scholar
  19. 19.
    Richardson DE, Taube H (1984) Coord Chem Rev 60:107CrossRefGoogle Scholar
  20. 20.
    Demanis KD, Hartshorn DC, Meyer TJ (2001) Chem Rev 101:2655CrossRefPubMedGoogle Scholar
  21. 21.
    Nelson SF (2000) Chem Eur J 6:581CrossRefGoogle Scholar
  22. 22.
    Mines GA, Roberts JA, Hupp JT (1992) Inorg Chem 31:125CrossRefGoogle Scholar
  23. 23.
    Vance FW, Stone RV, Stern CL, Hupp JT (2000) Chem Phys 253:313CrossRefGoogle Scholar
  24. 24.
    Szeghalmi AV, Erdmann M, Engel V, Schmitt M, Amthor S, Kriegisch V, Nöll G, Stahl R, Lambert C, Leusser D, Stalke D, Zabel M, Popp J (2004) J Am Chem Soc 126:7834CrossRefPubMedGoogle Scholar
  25. 25.
    Coropceanu V, Malagoli M, André JM, Brédas JL (2001) J Chem Phys 115:10409CrossRefGoogle Scholar
  26. 26.
    Salaymeh F, Berhane S, Yusof R, de la Rosa R, Fung EY, Matamoros R, Lau KW, Zheng Q, Kober EM, Curtis JC (1993) Inorg Chem 32:3895CrossRefGoogle Scholar
  27. 27.
    Hush NS (1967) Prog Inorg Chem 8:391Google Scholar
  28. 28.
    Badger B, Brocklehurst B (1970) Trans Faraday Soc 66:2939CrossRefGoogle Scholar
  29. 29.
    Low PJ, Bruce MI (2002) Adv Organomet Chem 48:71Google Scholar
  30. 30.
    Mochida T, Yamazaki S (2002) J Chem Soc Dalton Trans 3559Google Scholar
  31. 31.
    Lavanda C, Bechgaard K, Cowan DO (1976) J Org Chem 41:2700CrossRefGoogle Scholar
  32. 32.
    Adams RD, Qu B, Smith MD, Albright TA (2002) Organometallics 21:2970CrossRefGoogle Scholar
  33. 33.
    McAdam CJ, Brunton JJ, Robinson BH, Simpson J (1999) J Chem Soc Dalton Trans 2487Google Scholar
  34. 34.
    Adams RD, Qu B, Smith MD (2002) Organometallics 21:3867CrossRefGoogle Scholar
  35. 35.
    Jutzi P, Kleinebekel B (1997) J Organomet Chem 545–546:573Google Scholar
  36. 36.
    Levanda C, Cowan DO, Leitch C, Bechgaard K (1974) J Am Chem Soc 96:6788CrossRefGoogle Scholar
  37. 37.
    McManis GE, Gochev A, Nielson RM, Weaver MJ (1989) J Phys Chem 93:7733CrossRefGoogle Scholar
  38. 38.
    Delgado-Pena F, Talham DR, Cowan DO (1983) J Organomet Chem 253:C43CrossRefGoogle Scholar
  39. 39.
    Powers MJ, Meyers TJ (1978) J Am Chem Soc 100:4393CrossRefGoogle Scholar
  40. 40.
    Kramer JA, Hendrickson DN (1980) Inorg Chem 19:3330CrossRefGoogle Scholar
  41. 41.
    Altmann M, Friedrich J, Beer F, Reuter R, Enkelmann V, Bunz UHF (1997) J Am Chem Soc 119:1472CrossRefGoogle Scholar
  42. 42.
    Adams RD, Qu B, Smith MD (2002) Organometallics 21:3867CrossRefGoogle Scholar
  43. 43.
    Adams RD, Qu B, Smith MD (2002) Organometallics 21:4847CrossRefGoogle Scholar
  44. 44.
    Adams RD, Qu B, Smith MD, Albright TA (2002) Organometallics 21:2970CrossRefGoogle Scholar
  45. 45.
    Adams RD, Qu B, Smith MD (2001) Inorg Chem 40:2932CrossRefPubMedGoogle Scholar
  46. 46.
    Adams RD, Qu B (2000) Organometallics 19:2411CrossRefGoogle Scholar
  47. 47.
    Adams RD, Qu B, Smith MD (2001) J Organomet Chem 637–639:514CrossRefGoogle Scholar
  48. 48.
    Adams RD, Qu B (2001) J Organomet Chem 619:271CrossRefGoogle Scholar
  49. 49.
    Adams RD, Qu B (2001) J Organomet Chem 620:303CrossRefGoogle Scholar
  50. 50.
    Adams RD, Qu B (2000) Organometallics 19:4090CrossRefGoogle Scholar
  51. 51.
    Adams RD, Qu B (2000) Organometallics 19:2411CrossRefGoogle Scholar
  52. 52.
    Bruce MI, Skelton BW, White AH, Zaitseva NN (2002) J Organomet Chem 650:188CrossRefGoogle Scholar
  53. 53.
    Bruce MI, Zaitseva NN, Skelton BW, White AH (2002) J. Chem Soc Dalton Trans 1678Google Scholar
  54. 54.
    Champeil E, Draper SM (2001) J Chem Soc Dalton Trans 1440Google Scholar
  55. 55.
    Koridze AA, Zdanovich VI, Lagunova VYu, Petukhova II, Dolgushin FM (2000) Russ Chem Bull 49:1321Google Scholar
  56. 56.
    Duffy N, McAdam J, Nervi C, Osella D, Ravera M, Robinson B, Simpson J (1996) Inorg Chim Acta 247:99CrossRefGoogle Scholar
  57. 57.
    McAdam JC, Duffy NW, Robinson BH, Simpson J (1996) Organometallics 15:3935CrossRefGoogle Scholar
  58. 58.
    Yam VWW, Fung WKM, Wong KMC, Lau VCY, Cheung KK (1998) Chem Commun 777Google Scholar
  59. 59.
    For lead references see Fox MA, MacBride JAH, Peace RJ, Wade K (1998) J Chem Soc Dalton Trans 401Google Scholar
  60. 60.
    Fox MA, Paterson MAJ, Nervi C, Galeotti F, Puschmann H, Howard JAK, Low PJ (2001) Chem Commun 1610Google Scholar
  61. 61.
    Osella D, Milone L, Nervi C, Ravera M (1998) Eur J Inorg Chem 1473Google Scholar
  62. 62.
    Le Guennic B, Costuas K, Halet JF, Nervi C, Paterson MAJ, Fox MA, Roberts RL, Albesa-Jove D, Puschmann H, Howard JAK, PJ Low (2004) Comp Rendus Chem 2005, DOI:10.1016/j.crci.2005.03.016Google Scholar
  63. 63.
    Wedge TJ, Herzog A, Huertas R, Lee MW, Knobler CB, Hawthorne MF (2004) Organometallics 23:482CrossRefGoogle Scholar
  64. 64.
    Chawdhury N, Long NJ, Mahon MF, Ooi L, Raithby PR, Rooke S, White AJP, Williams DJ, Younas M (2004) J Organomet Chem 689:840CrossRefGoogle Scholar
  65. 65.
    Thomas KRJ, Lin JT, Wen YS (2000) Organometallics 19:1008CrossRefGoogle Scholar
  66. 66.
    Wong WY, Lu GL, Ng KF, Choi KH, Lin Z (2001) J Chem Soc Dalton Trans 3250Google Scholar
  67. 67.
    Wong WY, Ho KY, Choi KH (2003) J Organomet Chem 670:17CrossRefGoogle Scholar
  68. 68.
    Wong WY, Lu GL, Ng KF, Wong CK, Choi KH (2001) J Organomet Chem 637-639:159CrossRefGoogle Scholar
  69. 69.
    Zhu Y, Wolf MO (2000) J Am Chem Soc 122:10121CrossRefGoogle Scholar
  70. 70.
    Engtrakul C, Sita LR (2001) Nano Lett 1:541CrossRefGoogle Scholar
  71. 71.
    Field LD, George AV, Laschi F, Malouf EY, Zanello P (1992) J Organomet Chem 435:347CrossRefGoogle Scholar
  72. 72.
    Lavastre O, Plass J, Bachmann P, Gusemi S, Moinet C, Dixneuf PH (1997) Organometallics 16:184CrossRefGoogle Scholar
  73. 73.
    Beljonne D, Colbert MCB, Raithby PR, Friend RH, Bredas JL (1996) Synth Met 81:179CrossRefGoogle Scholar
  74. 74.
    Le Narvor N, Lapinte C (1995) Organometallics 14:634CrossRefGoogle Scholar
  75. 75.
    Colbert MCB, Lewis J, Long NJ, Raithby PR, Younus M, White AJP, Williams DJ, Payne NN, Yellowlees L, Beljonne D, Chawdhury N, Friend RH (1998) Organometallics 17:3034CrossRefGoogle Scholar
  76. 76.
    Hurst SK, Cifuentes MP, McDonagh AM, Humphrey MG, Samoc M, Luther-Davies B, Asselberghs I, Persoons A (2002) J Organomet Chem 642:259CrossRefGoogle Scholar
  77. 77.
    Back S, Lutz M, Spek AL, Lang H, van Koten G (2001) J Organomet Chem 620:227CrossRefGoogle Scholar
  78. 78.
    Hurst SK, Ren T (2002) J Organomet Chem 660:1CrossRefGoogle Scholar
  79. 79.
    Le Narvor N, Toupet L, Lapinte C (1995) J Am Chem Soc 117:7129CrossRefGoogle Scholar
  80. 80.
    Le Stang S, Paul F, Lapinte C (2000) Organometallics 19:1035CrossRefGoogle Scholar
  81. 81.
    Roué S, Lapinte C, Bataille T (2004) Organometallics 23:2558CrossRefGoogle Scholar
  82. 82.
    Kaim W, Kasack V (1990) Inorg Chem 29:4696CrossRefGoogle Scholar
  83. 83.
    Roberts RL (2005) Electrochemical and structural studies of organometallic acetylide complexes, PhD Thesis, University of DurhamGoogle Scholar
  84. 84.
    Le Guennic B (2002) Composés organométalliques et inorganométalliques: Etude théorique des relations structure – nombre d’électrons, Thèse pour le grade de Doctuer de L’Université de Rennes 1Google Scholar
  85. 85.
    Fink H, Long MJ, Martin AJ, Opromolla G, White AJP, Williams DJ, Zanello P (1997) Organometallics 16:2646CrossRefGoogle Scholar
  86. 86.
    Flanagan JB, Margel S, Baird AJ, Anson FC (1978) J Am Chem Soc 100:4248CrossRefGoogle Scholar
  87. 87.
    Long NJ, Martin AJ, de Biani FF, Zanello P (1998) J Chem Soc Dalton Trans 2017Google Scholar
  88. 88.
    Long NJ, Martin AJ, White AJP, Williams DJ, Fontani M, Laschi F, Zanello P (2000) J Chem Soc Dalton Trans 3387Google Scholar
  89. 89.
    Weyland T, Lapinte C, Frapper G, Calhorda MJ, Halet JF, Toupet L (1997) Organometallics 16:2024CrossRefGoogle Scholar
  90. 90.
    Weyland T, Costuas K, Toupet L, Halet JF, Lapinte C (2000) Organometallics 19:4228CrossRefGoogle Scholar
  91. 91.
    Weyland T, Costuas K, Mari A, Halet JF, Lapinte C (1998) Organometallics 17:5569CrossRefGoogle Scholar
  92. 92.
    Weyland T, Ledoux I, Brasselet S, Zyss J, Lapinte C (2000) Organometallics 19:5235CrossRefGoogle Scholar
  93. 93.
    Hurst SK, Cifuentes MP, Humphrey MG (2002) Organometallics 21:2353CrossRefGoogle Scholar
  94. 94.
    Bonvoisin J, Launay JP, Van der Auweraer M, De Schryver FC (1994) J Phys Chem 98:5053CrossRefGoogle Scholar
  95. 95.
    Osella D, Gobetto R, Nervi C, Ravera M, D’Amato R, Russo MV (1998) Inorg Chem Commun 1:239CrossRefGoogle Scholar
  96. 96.
    Jones SC, Coropceanu V, Barlow S, Kinnibrugh T, Timofeeva T, Brédas JL, Marder SR (2004) J Am Chem Soc 126:11782CrossRefPubMedGoogle Scholar
  97. 97.
    Khan MS, Mandhury MRA, Al-Suti MK, Al-Battashi FR, Al-Saadi S, Ahrens B, Bjernemose JK, Mahon MF, Raithby PR, Younis M, Chawdhury N, Kohler A, Marseglia EA, Tedesco E, Feeder N, Teat SJ (2004) Dalton Trans 2377Google Scholar
  98. 98.
    Khan MS, Al-Suti MK, Mandhury MRA, Ahrens B, Bjernemose JK, Mahon MF, Male L, Raithby PR, Friend RH, Kohler A, Wilson JS (2003) Dalton Trans 65Google Scholar
  99. 99.
    Khan MS, Mandhury MRA, Al-Suti MK, Ahrens B, Mahon MF, L Male, Raithby PR, Boothby CE, Kohler A (2003) Dalton Trans 74Google Scholar
  100. 100.
    Khan MS, Mandhury MRA, Al-Suti MK, Feeder N, Nahar S, Kohler A, Friend RH, Wilson PJ, Raithby PR (2002) J Chem Soc Dalton Trans 2441Google Scholar
  101. 101.
    Khan MS, Mandhury MRA, Al-Suti MK, Hisahm AK, Raithby PR, Ahrens B, Mahon MF, Male L, Marseglia EA, Tedesco E, Friend RH, Kohler A, Feeder N, Teat SJ (2002) J Chem Soc Dalton Trans 1358Google Scholar
  102. 102.
    Bruce MI, Halet JF, Le Guennic B, Skelton BW, Smith ME, White AH (2003) Inorg Chim Acta 350:175CrossRefGoogle Scholar
  103. 103.
    Jones ND, Wolf MO, Giaquinta DM (1997) Organometallics 16:1352CrossRefGoogle Scholar
  104. 104.
    Zhu Y, Clot O, Wolf MO, Yap GPA (1998) J Am Chem Soc 120:1812CrossRefGoogle Scholar
  105. 105.
    Colbert MCB, Lewis J, Long NJ, Raithby PR, White AJP, Williams DJ (1997) J Chem Soc Dalton Trans 99Google Scholar
  106. 106.
    Lebreton C, Touchard D, LePichon L, Daridor A, Toupet L, Dixneuf PH (1998) Inorg Chim Acta 272:188CrossRefGoogle Scholar
  107. 107.
    Belen’kaya AG, Dolgushin FM, Peterleitner MG, Petrovskii PV, Krivykh VV (2002) Russ Chem Bull 51:170CrossRefGoogle Scholar
  108. 108.
    Sato M, Shintate H, Kawata Y, Sekino M, Katada M, Kawata S (1994) Organometallics 13:1956CrossRefGoogle Scholar
  109. 109.
    Sato M, Iwai A, Watanabe M (1999) Organometallics 18:3208CrossRefGoogle Scholar
  110. 110.
    Bruce MI, de Montigny F, Jevric M, Lapinte C, Skelton BW, Smith ME, White AH (2004) J Organomet Chem 689:2860CrossRefGoogle Scholar
  111. 111.
    Berry JF, Cotton FA, Lu TB, Murillo CA, Roberts BK, Wang XP (2004) J Am Chem Soc 126:7082CrossRefPubMedGoogle Scholar
  112. 112.
    Berry JF, Cotton FA, Lei P, Lu T, Murillo CA (2003) Inorg Chem 42:3534CrossRefPubMedGoogle Scholar
  113. 113.
    Xu GL, DeRosa MC, Crutchley RJ, Ren T (2004) J Am Chem Soc 126:3728CrossRefPubMedGoogle Scholar
  114. 114.
    Xu G, Ren T (2001) Organometallics 20:2400CrossRefGoogle Scholar
  115. 115.
    Yip JHK, Wu J, Wong KY, Ho KP, Pun CSN, Vittal JJ (2002) Organometallics 21:5292CrossRefGoogle Scholar
  116. 116.
    Hore LA, McAdam CJ, Kerr JL, Duffy NW, Robinson BH, Simpson J (2000) Organometallics 19:5039CrossRefGoogle Scholar
  117. 117.
    Richardson DE, Taube H (1981) Inorg Chem 20:1278CrossRefGoogle Scholar
  118. 118.
    Cotton FA, Donohue JP, Murillo CA (2003) J Am Chem Soc 125:5436CrossRefPubMedGoogle Scholar
  119. 119.
    Berry JF, Cotton FA, Murillo CA (2004) Organometallics 23:2503CrossRefGoogle Scholar
  120. 120.
    For closely related work see Sheng T, Appelt R, Comte V, Vahrenkamp H (2003) Eur J Inorg Chem 3731Google Scholar
  121. 121.
    Frosch W, Back S, Köhler K, Lang H (2000) J Organomet Chem 601:226CrossRefGoogle Scholar
  122. 122.
    Back S, Pritzkow H, Lang H (1998) Organometallics 17:41CrossRefGoogle Scholar
  123. 123.
    Hayashi Y, Osawa M, Wakatsuki Y (1997) J Organomet Chem 542:241CrossRefGoogle Scholar
  124. 124.
    Neyhart GA, Hupp JT, Curtis JC, Timpson CJ, Meyer TJ (1996) J Am Chem Soc 118:3724CrossRefGoogle Scholar
  125. 125.
    Watzky MA, Macatangay AV, Van Camp RA, Mazzetto SE, Song X, Endicott JF, Buranda T (1997) J Phys Chem 10:8441Google Scholar
  126. 126.
    Younus M, Long NJ, Raithby PR, Lewis J (1998) J Organomet Chem 570:55CrossRefGoogle Scholar
  127. 127.
    Wong KMC, Lam SCF, Ko CC, Zhu N, Yam VWW, Roué S, Lapinte C, Fathallah S, Costuas K, Kahlal S, Halet JF (2003) Inorg Chem 42:7086CrossRefPubMedGoogle Scholar
  128. 128.
    Paul F, Meyer WE, Toupet L, Jiao H, Gladysz JA, Lapinte C (2000) J Am Chem Soc 122:9405CrossRefGoogle Scholar
  129. 129.
    Jiao H, Costuas K, Gladysz JA, Halet JF, Guillemot M, Toupet L, Paul F, Lapinte C (2003) J Am Chem Soc 125:9511CrossRefPubMedGoogle Scholar
  130. 130.
    Low PJ, Rousseau R, Lam P, Udachin KA, Enright GD, Tse JS, Wayner DDM, Carty AJ (1999) Organometallics 18:3885CrossRefGoogle Scholar
  131. 131.
    Cordiner RL, Corcoran D, Yufit DS, Goeta AE, Howard JAK, Low PJ (2003) Dalton Trans 3541Google Scholar
  132. 132.
    Smith ME, Cordiner RL, Albesa-Jové D, Yufit DS, Hartl F, Howard JAK, Low PJ (2005) Can J Chem (in press)Google Scholar
  133. 133.
    Denis R, Toupet L, Paul F, Lapinte C (2000) Organometallics 19:4240CrossRefGoogle Scholar
  134. 134.
    Laidlaw WM, Denning RG (1994) J Chem Soc Dalton Trans 1987Google Scholar

Copyright information

© Springer-Verlag 2005

Authors and Affiliations

  • Paul J. Low
    • 1
  • Rachel L. Roberts
    • 1
  • Richard L. Cordiner
    • 1
  • František Hartl
    • 2
  1. 1.Department of ChemistryUniversity of DurhamDurhamUK
  2. 2.Van’t Hoff Institute for Molecular SciencesUniversity of AmsterdamAmsterdamThe Netherlands

Personalised recommendations