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Efficient Referencing of FSLG CPMAS HETCOR Spectra Using 2D 1H–1H MAS FSLG

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Abstract

FSLG CPMAS HETCOR is a 2D solid-state NMR experiment which provides structural information and conformational correlation between a 1H and an X-nucleus. However, practical application of the experiment suffers from the chemical shift referencing problem on the indirect 1H dimension. In our paper, we present a novel 1H–1H MAS FSLG-based approach and its application to reference the FSLG CPMAS HETCOR which overcomes the 1H referencing in the 2D 1H-X HETCOR experiment. This approach works excellently irrespective of the sample type over a wide range of temperature.

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Acknowledgements

Financial support by the Deutsche Forschungsgemeinschaft under contract Bu-911-24-2 is gratefully acknowledged.

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Authors and Affiliations

  1. Eduard-Zintl Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, 64287, Darmstadt, Germany

    Bharti Kumari, Martin Brodrecht, Torsten Gutmann, Hergen Breitzke & Gerd Buntkowsky

  2. Institute of Chemistry and Center for Interdisciplinary Nanostructure Science and Technology, University of Kassel, Heinrich-Plett Straße 40, 34132, Kassel, Germany

    Torsten Gutmann

Authors
  1. Bharti Kumari
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  2. Martin Brodrecht
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  3. Torsten Gutmann
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  4. Hergen Breitzke
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  5. Gerd Buntkowsky
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Correspondence to Hergen Breitzke or Gerd Buntkowsky.

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Kumari, B., Brodrecht, M., Gutmann, T. et al. Efficient Referencing of FSLG CPMAS HETCOR Spectra Using 2D 1H–1H MAS FSLG. Appl Magn Reson 50, 1399–1407 (2019). https://doi.org/10.1007/s00723-019-01156-2

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  • DOI: https://doi.org/10.1007/s00723-019-01156-2

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