Advertisement

Applied Magnetic Resonance

, Volume 44, Issue 10, pp 1181–1198 | Cite as

The Observation and Dynamics of 1H NMR Spin Noise in Methanol

  • Antoni Jurkiewicz
Article

Abstract

The observation of 1H spin noise in relation to prior established magnetization and radiation damping has revealed a correlated dynamics. The spin noise of methyl satellites in 13C-enriched methanol was observed in the presence of an antiphase magnetization, created by the combination of 1H–13C J coupling evolution and radiofrequency (RF) pulses. A gradient pulse was applied to remove residue spin coherence coming from the RF pulses, and as a result spin noise phenomena were uncovered. While magnetization was in an inverted metastable state, the spin–spin relaxation time was shortened to prevent a super radiation burst. The relation between magnetization, radiation damping, and absorption or emission of the spin noise of methyl satellites has been studied. In relation to magnetization and radiation damping, spin noise bump and dip have been observed simultaneously in the same molecule. Both can be created through a proper inversion of magnetization. The revealed spin noise dynamics of spin system coupling to the probe circuit via radiation damping allows performance of a transformation from dip into bump by proper application of pulses combined with 1H–13C J coupling evolution.

Keywords

Nuclear Magnetic Resonance Lattice Relaxation Dynamic Nuclear Polarization Nuclear Magnetic Resonance Signal Spin Relaxation Time 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    F. Bloch, Phys. Rev. 70, 460–474 (1946)ADSCrossRefGoogle Scholar
  2. 2.
    T. Sleator, E.L. Hahn, C. Hilbert, J. Clarke, Phys. Rev. Lett. 55, 1742–1745 (1985)ADSCrossRefGoogle Scholar
  3. 3.
    T. Sleator, E.L. Hahn, C. Hilbert, J. Clarke, Phys. Rev. B 36, 1969–1980 (1987)ADSCrossRefGoogle Scholar
  4. 4.
    M.A. McCoy, R.R. Ernst, Chem. Phys. Lett. 195(5, 6), 587–593 (1989)ADSCrossRefGoogle Scholar
  5. 5.
    M. Gueron, J.L. Leroy, J. Magn. Reson. 85, 209–215 (1989)Google Scholar
  6. 6.
    M. Gueron, Magn. Reson. Med. 19, 31–41 (1991)CrossRefGoogle Scholar
  7. 7.
    T.R. Field, A.D. Bain, Appl. Magn. Reson. 38, 167–178 (2010)CrossRefGoogle Scholar
  8. 8.
    N. Muller, A. Jerschow, Proc. Natl. Acad. Sci. USA 103(18), 6790–6792 (2006)ADSCrossRefGoogle Scholar
  9. 9.
    P. Giraudeau, N. Muller, A. Jerschow, L. Frydman, Chem. Phys. Lett. 489, 107–112 (2010)ADSCrossRefGoogle Scholar
  10. 10.
    M. Nausner, J. Schlagnitweit, V. Smrecki, X. Yang, A. Jerschow, N. Muller, J. Magn. Reson. 198, 73–79 (2009)ADSCrossRefGoogle Scholar
  11. 11.
    D.I. Hoult, N.S. Ginsberg, J. Magn. Reson. 148, 182–199 (2001)ADSCrossRefGoogle Scholar
  12. 12.
    J. Schlagnitweit, N. Muller, J. Magn. Reson. 224, 78–81 (2012)ADSCrossRefGoogle Scholar
  13. 13.
    A. Abragam, M. Goldman, Rep. Prog. Phys. 41, 395–467 (1978)Google Scholar
  14. 14.
    R.A. Wind, M.J. Duijvestijn, C. van der Lugt, A. Manenschijn, Prog. Nucl. Magn. Reson. Spectrosc. 17, 33–67 (1985)CrossRefGoogle Scholar
  15. 15.
    R.A. Wind, R.A. Hall, A. Jurkiewicz, H. Lock, G.A. Maciel, J. Magn. Reson. 110(A), 33–37 (1984)Google Scholar
  16. 16.
    V.S. Bajaj, C.T. Farrar, M.K. Hornstein, I. Mastovsky, J. Vieregg, J. Bryant, B. Elena, K.E. Kreischer, R.J. Temkin, R.G. Griffin, J. Magn. Reson. 160, 85–90 (2003)ADSCrossRefGoogle Scholar
  17. 17.
    H. Desvaux, D.J.Y. Marion, G. Huber, P. Berthault, Angew. Chem. 48, 4341–4343 (2009)CrossRefGoogle Scholar
  18. 18.
    J.A. Villanueva-Garibay, G. Annino, P.J. van Bentum, A.P.M. Kentgens, Phys. Chem. Chem. Phys. 12, 5846–5849 (2010)CrossRefGoogle Scholar
  19. 19.
    A. Abragam, The Principles of Nuclear Magnetism (Clarendon Press, Oxford, 1961)Google Scholar
  20. 20.
    A. Vlassenbroek, J. Jeener, P. Broekaert, J. Chem. Phys. 14, 5886–5897 (1995)ADSCrossRefGoogle Scholar
  21. 21.
    N. Bloembergen, R.V. Pound, Phys. Rev. 95, 8–12 (1954)ADSCrossRefGoogle Scholar
  22. 22.
    S. Bloom, J. Appl. Phys. 28, 800–805 (1957)MathSciNetADSCrossRefGoogle Scholar
  23. 23.
    P. Bosiger, E. Brun, D. Meier, Phys. Rev. Lett. 38, 602–605 (1977)ADSCrossRefGoogle Scholar
  24. 24.
    M.P. Augustine, S.D. Bush, E.L. Hahn, Chem. Phys. Lett. 322, 111–118 (2000)ADSCrossRefGoogle Scholar
  25. 25.
    X. Mao, C. Ye, Concepts Magn. Reson. 9(3), 173–187 (1997)CrossRefGoogle Scholar
  26. 26.
    X.A. Mao, J.H. Chen, Phys. Rev. A 60(6), 5140–5143 (1999)ADSCrossRefGoogle Scholar
  27. 27.
    A. Sodickson, W.E. Maas, D.G. Cory, J. Magn. Reson. B110, 298–303 (1996)Google Scholar
  28. 28.
    W.S. Warren, S.L. Hammes, J.L. Bates, J. Chem. Phys. 91(10), 5895–5904 (1989)ADSCrossRefGoogle Scholar
  29. 29.
    E.V. Goldammer, M.D. Zeidler, Ber. Bunsenges. Phys. Chem. 73, 4–15 (1969)Google Scholar
  30. 30.
    S. Mussig, E.U. Franck, M. Holz, Z. Phys. Chemie (Muenchen) 214(7), 957–968 (2000)Google Scholar
  31. 31.
    W.E. Blumberg, Phys. Rev. 119(1), 79–84 (1960)ADSCrossRefGoogle Scholar
  32. 32.
    H.E. Rorschach Jr, Physica 30(1), 38–48 (1964)ADSCrossRefGoogle Scholar
  33. 33.
    I.J. Lowe, D. Tse, Phys. Rev. 166(2), 279–291 (1968)ADSCrossRefGoogle Scholar
  34. 34.
    C.C. Sung, L.G. Arnold, Phys. Rev. B 7(5), 2095–2102 (1973)ADSCrossRefGoogle Scholar
  35. 35.
    U. Gosele, Physica 85B, 317–322 (1977)Google Scholar
  36. 36.
    G.B. Furman, E.M. Kunoff, S.D. Goren, V. Pasquier, D. Tinet, Phys. Rev. 52(14), 10182–10187 (1995)CrossRefGoogle Scholar
  37. 37.
    G.B. Furman, A.M. Panich, A. Yochelis, E.M. Kunoff, S.D. Goren, Phys. Rev. 55(1), 439–444 (1997)ADSCrossRefGoogle Scholar
  38. 38.
    X.A. Mao, J. Guo, C.H. Ye, Chem. Phys. Lett. 222, 417–421 (1994)ADSCrossRefGoogle Scholar
  39. 39.
    J.H. Chen, X.A. Mao, J. Phys. D Appl. Phys. 32, 764–768 (1994)ADSCrossRefGoogle Scholar
  40. 40.
    M.P. Augustine, E.L. Hahn, J. Phys. Chem. B 102, 8229–8238 (1998)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Wien 2013

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of ChicagoChicagoUSA

Personalised recommendations