Applied Magnetic Resonance

, Volume 41, Issue 2–4, pp 205–220 | Cite as

Spin Chemistry Investigation of Peculiarities of Photoinduced Electron Transfer in Donor–Acceptor Linked System

  • I. M. Magin
  • N. E. Polyakov
  • E. A. Khramtsova
  • A. I. Kruppa
  • A. A. Stepanov
  • P. A. Purtov
  • T. V. Leshina
  • Yu. P. Tsentalovich
  • M. A. Miranda
  • E. Nuin
  • M. L. Marin
Article

Abstract

Photoinduced intramolecular electron transfer in linked systems, (R,S)- and (S,S)-naproxen-N-methylpyrrolidine dyads, has been studied by means of spin chemistry methods [magnetic field effect and chemically induced dynamic nuclear polarization (CIDNP)]. The relative yield of the triplet state of the dyads in different magnetic field has been measured, and dependences of the high-field CIDNP of the N-methylpyrrolidine fragment on solvent polarity have been investigated. However, both (S,S)- and (R,S)-enantiomers demonstrate almost identical CIDNP effects for the entire range of polarity. It has been demonstrated that the main peculiarities of photoprocesses in this linked system are connected with the participation of singlet exciplex alongside with photoinduced intramolecular electron transfer in chromophore excited state quenching.

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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • I. M. Magin
    • 1
  • N. E. Polyakov
    • 1
  • E. A. Khramtsova
    • 1
    • 2
  • A. I. Kruppa
    • 1
  • A. A. Stepanov
    • 1
  • P. A. Purtov
    • 1
    • 2
  • T. V. Leshina
    • 1
  • Yu. P. Tsentalovich
    • 3
  • M. A. Miranda
    • 4
  • E. Nuin
    • 4
  • M. L. Marin
    • 4
  1. 1.Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia
  3. 3.International Tomography Center, Siberian Branch of the Russian Academy of SciencesNovosibirskRussia
  4. 4.Instituto de Tecnología Química, UPV-CSICUniversidad Politécnica de ValenciaValenciaSpain

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