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Palladium/norbornene cooperative catalysis for ortho/ipso multifunctionalization of carbazoles

  • Farnaz JafarpourEmail author
  • Sara Izadidana
  • Mehran Ghasemi
Original Paper
  • 4 Downloads

Abstract

Palladium-catalyzed/norbornene-mediated direct functionalization of carbazoles is disclosed. The method offers an approach to a wide variety of alkyl- and alkenyl-substituted biologically interesting carbazole derivatives from carbazole halides, alkyl halides, and acrylates. Three new C–C bonds are formed at 2-, 3-, and 4-positions of carbazoles via two C–H activation reactions and a Heck-type functionalization in one pot.

Graphic abstract

Keywords

Alkylation C–H activation Carbazole Norbornene Palladium 

Notes

Acknowledgements

We acknowledge the financial support from University of Tehran.

Supplementary material

706_2019_2501_MOESM1_ESM.docx (3.2 mb)
Supplementary material 1 (DOCX 3310 kb)

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Copyright information

© Springer-Verlag GmbH Austria, part of Springer Nature 2019

Authors and Affiliations

  1. 1.School of Chemistry, College of ScienceUniversity of TehranTehranIran

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