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Monatshefte für Chemie - Chemical Monthly

, Volume 149, Issue 4, pp 765–771 | Cite as

Synthesis of 1,2,4-triaza-3,5-diphospholidines

  • Bernd H. Müller
  • Katharina Konieczny
  • Martha Höhne
  • Anke Spannenberg
  • Normen Peulecke
  • Jan-Ole Moritz
  • Marleen Winterberg
  • Uwe Rosenthal
Original Paper
  • 118 Downloads

Abstract

1,2,4-Triaza-3,5-diphospholidines were synthesized by highly selective cyclization reactions between N,N-bis[chloro(phenyl)phosphino]methylamine and 1,2-disubstituted hydrazines. Three examples of molecular structures are discussed against the background of configurational isomers and the potential of the title compounds as versatile cyclic ligands with chelating P–N–P motif.

Graphical abstract

Keywords

Heterocycles Phosphorus compounds Cyclizations Ligands Crystal structure 

Supplementary material

706_2017_2082_MOESM1_ESM.pdf (2.1 mb)
Supplementary material 1 (PDF 2187 kb)

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Copyright information

© Springer-Verlag GmbH Austria 2017

Authors and Affiliations

  • Bernd H. Müller
    • 1
  • Katharina Konieczny
    • 1
  • Martha Höhne
    • 1
  • Anke Spannenberg
    • 1
  • Normen Peulecke
    • 1
  • Jan-Ole Moritz
    • 1
  • Marleen Winterberg
    • 1
  • Uwe Rosenthal
    • 1
  1. 1.Leibniz Institute for Catalysis at the University of RostockRostockGermany

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