Monatshefte für Chemie - Chemical Monthly

, Volume 143, Issue 4, pp 637–642 | Cite as

Synthesis of β-amino alcohols catalyzed by poly(vinyl chloride)-supported Schiff base metal complexes

  • G. Rajesh Krishnan
  • K. Sapna Kajal
  • Krishnapillai Sreekumar
Original Paper
First Online:
Received:
Accepted:

Abstract

Eight transition metal complexes of various Schiff bases supported on poly(vinyl chloride) (PVC) were prepared and characterized. These metal complexes were screened as heterogeneous catalysts in the synthesis of β-amino alcohols by ring opening of epoxides with amines. The best catalyst was identified as a Ni(II) complex of PVC-supported 2-[(2-aminoethylimino)methyl]phenol and it was used in the synthesis of a number of different β-amino alcohols. The catalyst was found to be reusable for up to five cycles.

Graphical abstract

Keywords

Amines Epoxides Catalyst Schiff bases Polymer 
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Notes

Acknowledgments

The authors would like to acknowledge Defense Research and Development Organization, India for financial support and the NMR research centre at the Indian Institute of Science, Bangalore for NMR spectral analysis.

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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • G. Rajesh Krishnan
    • 1
  • K. Sapna Kajal
    • 1
  • Krishnapillai Sreekumar
    • 1
  1. 1.Department of Applied ChemistryCochin University of Science and TechnologyKochiIndia

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