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Synthesis of Side Chain Substituted 3-Butylisocoumarins and Absolute Configurations of Natural Isocoumarins from Artemisia dracunculus

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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary.

A series of 3-hydroxy- and 3-bromobutyl-substituted isocoumarins was synthesized. The absolute configurations of three isocoumarin derivatives from Artemisia dracunculus, namely (−)-epoxyartemidin, (−)-2′-methoxydihydroartemidin, and (+)-3′-hydroxyartemidin were determined by chemical means via derivatization, kinetic racemate resolution (Horeau method), and comparison of the circular dichroism (CD) spectra.

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Authors and Affiliations

  1. Institute of Organic Chemistry, University of Vienna, Wien, Austria, , , , , , AU

    Gerda Lutz-Kutschera, Andreas Werner & Otmar Hofer

  2. Comparative Phytochemistry Department, Institute of Botany, University of Vienna, Wien, Austria, , , , , , AT

    Doris Engelmeier, Franz Hadacek & Harald Greger

Authors
  1. Gerda Lutz-Kutschera
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  2. Doris Engelmeier
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  3. Franz Hadacek
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  4. Andreas Werner
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  5. Harald Greger
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  6. Otmar Hofer
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Corresponding author

Correspondence to Otmar Hofer.

Additional information

Deceased

Received March 17, 2003; accepted March 19, 2003 Published online August 18, 2003

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Lutz-Kutschera, G., Engelmeier, D., Hadacek, F. et al. Synthesis of Side Chain Substituted 3-Butylisocoumarins and Absolute Configurations of Natural Isocoumarins from Artemisia dracunculus . Monatshefte für Chemie 134, 1195–1206 (2003). https://doi.org/10.1007/s00706-003-0046-6

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  • DOI: https://doi.org/10.1007/s00706-003-0046-6

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