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Microchimica Acta

, 186:821 | Cite as

A glassy carbon electrode modified with a nanocomposite prepared from Pd/Al layered double hydroxide and carboxymethyl cellulose for voltammetric sensing of hydrogen peroxide

  • Gozal Fazli
  • Sedigheh Esmaeilzadeh BahabadiEmail author
  • Laleh Adlnasab
  • Hamid Ahmar
Original Paper
  • 54 Downloads

Abstract

A Pd/Al layered double hydroxide/carboxymethyl cellulose nanocomposite (CMC@Pd/Al-LDH) was fabricated using carboxymethyl cellulose as a green substrate via co-precipitation method. The synthesized nanocomposite was characterized using different methods such as scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray powder diffraction, transmission electron microscopy, and electrochemical techniques. A glassy carbon electrode (GCE) was then modified with the suspended composite to obtain an electrochemical sensor for hydrogen peroxide (H2O2). The voltammetric (cathodic) current of the modified GCE was measured at −380 mV (vs. Ag/AgCl), at the scan rate of 50 mV.s−1. Results show a linear dynamic range of 1 to 120 μM, and a 0.3 µM limit of detection (at S/N = 3). Intraday and interday relative standard deviations are in the ranges of 4.9–5.4% and 6.8–7.3%, respectively. The sensor was applied for the determination of H2O2 in basil extracts, milk, and spiked river water samples. The recoveries are between 96.60 and 102.30%.

Graphical abstract

A Pd/Al layered double hydroxide/carboxymethyl cellulose nanocomposite (CMC@Pd/Al-LDH) was fabricated via co-precipitation method and was characterized using scanning electron microscopy, Energy-dispersive X-ray spectroscopy, X-ray powder diffraction, transmission electron microscopy and electrochemical techniques. CMC@Pd/Al-LDH was used to fabricate H2O2 electrochemical sensor.

Keywords

H2O2 Electrochemical sensor Co-precipitation synthesis Modified electrode Electro-catalytic reduction Basil extract Milk sample Differential pulse voltammetry Optimization 

Notes

Acknowledgements

This work was supported by University of Zabol [Grant number: UOZ-GR-9618-20].

Compliance with ethical standards

Conflict of interest

 The author(s) declare that they have no competing interests.

Supplementary material

604_2019_3967_MOESM1_ESM.docx (580 kb)
ESM 1 (DOCX 579 kb)

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Copyright information

© Springer-Verlag GmbH Austria, part of Springer Nature 2019

Authors and Affiliations

  • Gozal Fazli
    • 1
  • Sedigheh Esmaeilzadeh Bahabadi
    • 1
    Email author
  • Laleh Adlnasab
    • 2
  • Hamid Ahmar
    • 3
  1. 1.Department of Biology, Faculty of ScienceUniversity of ZabolZabolIran
  2. 2.Department of Chemistry, Chemistry and Petrochemistry Research CenterStandard Research InstituteKarajIran
  3. 3.Department of Chemistry, Faculty of ScienceUniversity of ZabolZabolIran

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