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Microchimica Acta

, 186:807 | Cite as

Carbon fibers coated with urchin-like copper sulfide for nonenzymatic voltammetric sensing of glucose

  • Murugan Keerthi
  • Bhuvanenthiran Mutharani
  • Shen-Ming ChenEmail author
  • Palraj Ranganathan
Original Paper
  • 95 Downloads

Abstract

Urchin-like CuS was grown on xanthan gum-derived carbon nanofibers to obtain a sensor for enzyme-free electrochemical sensing of glucose. The unique nanostructure of the sensor provides a large specific surface, more electrocatalytically active sites, and high electrical conductivity. The voltammetric response to glucose, best measured at around 57 mV (vs. Ag/AgCl (E/V)) in 0.1 M NaOH solution, covers two linear ranges, one from 0.1–125 μM, another from 0.16 to 1.2 mM. The sensitivity is quite high (23.7 μA mM−1 cm−2), and the detection limit is low (19 nM at S/N = 3). The sensor has high selectivity against potentially interfering molecules such as fructose, appreciable operational stability, excellent durability, and good repeatability (with relative standard deviations of 2.3%). It was successfully applied to the determination of glucose in diluted serum samples.

Graphical abstract

Schematic representation of electrochemical detection of glucose based on the use of a screen printed carbon electrode (SPCE) modified with CuS and xanthan gum-derived carbon nanofibers (XGCNFs).

Keywords

Xanthan gum derived carbon Copper sulfide Electrochemical detection Enzyme-free biosensor Human blood serum 

Notes

Acknowledgements

This project was supported by the Ministry of Science and Technology (MOST 106-2113-M-027-003), Taiwan, ROC.

Compliance with ethical standards

Conflict of interest

There are no conflicts of interest to declare.

Supplementary material

604_2019_3915_MOESM1_ESM.docx (358 kb)
ESM 1 (DOCX 358 kb)

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Copyright information

© Springer-Verlag GmbH Austria, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Department of Chemical Engineering and BiotechnologyNational Taipei University of TechnologyTaipeiTaiwan, Republic of China
  2. 2.Institute of Organic and Polymeric Materials and Research and Development Center for Smart Textile TechnologyNational Taipei University of TechnologyTaipeiTaiwan, Republic of China

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