Microchimica Acta

, 186:742 | Cite as

Solid-phase microextraction of triazine herbicides via cellulose paper coated with a metal-organic framework of type MIL-101(Cr), and their quantitation by HPLC-MS

  • Yanxiao Jiang
  • Pinyi Ma
  • Huilan Piao
  • Zucheng Qin
  • Shuo Tao
  • Ying Sun
  • Xinghua Wang
  • Daqian SongEmail author
Original Paper


Cellulose paper was coated with the metal-organic framework MIL-101(Cr) in a chitosan matrix and utilized for thin-film microextraction (TFME). The coated paper possesses excellent extraction efficiency for the triazine herbicides atraton, desmetryn, secbumeton, prometon, ametryn, dipropetryn, and dimethametryn. High-performance liquid chromatography-tandem mass spectrometry was applied to quantify target analytes. The effects of mass ratio of MIL-101(Cr) to chitosan, sample pH value, time of adsorption and desorption, and type and volume of desorption solvent on extraction efficiency were optimized. Under the optimal conditions, the method has limits of detection between 1.5 and 22 ng·L−1. The recoveries of triazines from spiked tap water, drinking water, lake water and river water range from 77.0 to 125.3%, with relative standard deviations of <17.4%.

Graphical abstract

Cellulose paper was modified with metal-organic framework MIL-101(Cr)/chitosan by using a simple, efficient and environmentally friendly approach. The modified cellulose paper was then used as a novel extraction phase in thin-film microextraction (TFME).


Metal organic framework (MOF) Thin film microextraction (TFME) Coated paper Triazine herbicides 



The financial support of Industrial Innovation Funds of Jilin Province of China (No. 2018C034-1) and Science and Technology Developing Foundation of Jilin Province of China (No. 20180201050YY) are greatly appreciated by all authors.

Compliance with ethical standards

Competing interests

The author(s) declare that they have no competing interests.

Supplementary material

604_2019_3889_MOESM1_ESM.doc (647 kb)
ESM 1 (DOC 647 kb)


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Copyright information

© Springer-Verlag GmbH Austria, part of Springer Nature 2019

Authors and Affiliations

  1. 1.College of ChemistryJilin UniversityChangchunChina
  2. 2.Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical EngineeringLiaocheng UniversityLiaochengChina

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