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Microchimica Acta

, 186:630 | Cite as

Core-shell upconversion nanoparticles of type NaGdF4:Yb,Er@NaGdF4:Nd,Yb and sensitized with a NIR dye are a viable probe for luminescence determination of the fraction of water in organic solvents

  • Wen Wang
  • Mingying Zhao
  • Lun WangEmail author
  • Hongqi ChenEmail author
Original Paper
  • 177 Downloads

Abstract

Lanthanide-doped core-shell upconversion nanoparticles (UCNPs) of type NaGdF4:Yb,Er@NaGdF4:Yb,Nd were prepared by the co-precipitation method. The luminescence intensity was further enhanced by adding the sensitizer dye IR-808. If water is added to organic solvents [such as N,N-dimethylformamide (DMF), dimethyl sulfoxide, methanol, acetone, acetonitrile, and ethanol] containing the probe, its luminescence intensity peaking at 545 nm is reduced. The decrease is linearly related to the percentage of water in the respective organic solvent. Water fractions ranging from 0.05% to 10% (volume %) can be sensitively detected, and the detection limit is 0.018% of water in DMF. The detection scheme is mainly attributed to the fact that the transfer of energy from the near-infrared light (NIR) dye to the UCNPs is strongly reduced in the presence of traces of water.

Graphical abstract

The near infrared dye (IR-808) transfer efficiency to NaGdF4:Yb, Er@NaGdF4:Yb, Nd upconversion nanoparticles in water is far less than that in organic phase. Several methods for determination of trace water in organic solvents were developed by using this effect.

Keywords

Upconversion nanoparticles Dye sensitization Luminescent probe Water fraction 

Notes

Acknowledgements

This work was financially supported by natural science foundation of China (21675002), the education commission natural science foundation of Anhui Province (KJ2017ZD25), foundation for innovation team of bioanalytical chemistry and Special and Excellent Research Fund of Anhui Normal University.

Compliance with ethical standards

The author(s) declare that they have no competing interests.

Supplementary material

604_2019_3744_MOESM1_ESM.doc (1.6 mb)
ESM 1 (DOC 1620 kb)

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Copyright information

© Springer-Verlag GmbH Austria, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Anhui Key Laboratory of Chemo-Biosensing, Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials ScienceAnhui Normal UniversityWuhuPeople’s Republic of China

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