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Microchimica Acta

, 186:36 | Cite as

Colorimetric detection of chromium(VI) using graphene oxide nanoparticles acting as a peroxidase mimetic catalyst and 8-hydroxyquinoline as an inhibitor

  • Nguyen Ngoc Nghia
  • Bui The Huy
  • Yong-Ill LeeEmail author
Original Paper
  • 114 Downloads

Abstract

A method is described for the colorimetric determination of chromate [chromium(VI)]. It is based on the use of graphene oxide (GO) nanoparticles acting as a peroxidase mimic. A blue color is generated by oxidation of 3,3,5,5-tetramethylbenzidine by H2O2 which is catalyzed by GO. This color-forming reaction is prevented in the presence of 8-hydroxyquinoline (8-HQ). However, in the presence of Cr(VI), the blue color will be formed from TMB owing to the oxidation of the inhibitor 8-HQ by Cr(VI). The color can be measured by a spectrophotometry (at 652 nm) or detected visually. Under optimal experimental conditions, response is linear in the 50 to 430 nM range of chromate concentration, and the limit of detection is 5.8 nM (at S/N = 3). The assay is highly selective and was successfully applied to the determination of Cr(VI) in spiked water samples.

Graphical abstract

Schematic of the colorimetric assay for Cr(VI). TMB: 3,3,5,5-tetramethylbenzidine

Keywords

Colorimetric assay Carbon nanomaterial Chromate Chelate Graphene oxide 

Notes

Acknowledgments

This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2017R1D1A3B03035530 and NRF-2017R1A2B4006388).

Compliance with ethical standards

The authors declare no competing financial interest.

Supplementary material

604_2018_3169_MOESM1_ESM.doc (561 kb)
ESM 1 (DOC 561 kb)

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Copyright information

© Springer-Verlag GmbH Austria, part of Springer Nature 2018

Authors and Affiliations

  • Nguyen Ngoc Nghia
    • 1
  • Bui The Huy
    • 1
    • 2
  • Yong-Ill Lee
    • 1
    Email author
  1. 1.Department of ChemistryChangwon National UniversityChangwonRepublic of Korea
  2. 2.Institute for Research & DevelopmentDuy Tan UniversityDanangVietnam

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