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Microchimica Acta

, 185:495 | Cite as

HKUST-1 metal-organic framework for dispersive solid phase extraction of 2-methyl-4-chlorophenoxyacetic acid (MCPA) prior to its determination by ion mobility spectrometry

  • Masoumeh Mohammadnejad
  • Zahra Gudarzi
  • Shokoofeh Geranmayeh
  • Vahideh Mahdavi
Original Paper
  • 55 Downloads

Abstract

The authors describe a method for the extraction of the herbicide 2-methyl-4-chlorophenoxyacetic acid (MCPA) from agricultural products. The metal organic framework (MOF) HKUST-1 (a copper(II) benzene-1,3,5-tricarboxylate) was used as a sorbent for efficient clean-up and preconcentration of MCPA. The effects of pH value, stirring time, amount of sorbent on extraction were optimized by central composite design. Ultrasonic waves were used for desorption procedure and its advantage was demonstrated for an increase in extraction recovery. Corona discharge ion mobility spectrometry (IMS) was then applied for fast and sensitive determination of MCPA. The method was validated in terms of sensitivity, recovery and reproducibility. Under the optimum conditions the calibration plot is linear between 0.035–0.200 μg. L−1. The detection limit is 10 ng L−1, with relative standard deviations of <5%. Real samples (water, soil and agricultural product) were spiked and then analyzed by this method, and the results revealed efficient solid phase extraction and recovery.

Graphical abstract

Schematic presentation of a procedure for extraction of an organochlorine pesticide (2-methyl-4-chlorophenoxyacetic acid) from agriculture products using the HKUST-1 metal-organic framework prior to determination by ion mobility spectrometry based on its ionization in drift cell.

Keywords

2-Methyl-4-chlorophenoxyacetic acid MCPA Ion mobility spectrometry Metal organic framework MOF Dispersive solid phase extraction Central composite design Porous material Water analysis Agriculture products 

Notes

Acknowledgements

The authors acknowledge the Research Council of Alzahra University.

Compliance with ethical standards

The author(s) declare that they have no competing interests.

Supplementary material

604_2018_3014_MOESM1_ESM.doc (692 kb)
ESM 1 (DOC 691 kb)

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Copyright information

© Springer-Verlag GmbH Austria, part of Springer Nature 2018

Authors and Affiliations

  • Masoumeh Mohammadnejad
    • 1
  • Zahra Gudarzi
    • 1
  • Shokoofeh Geranmayeh
    • 1
  • Vahideh Mahdavi
    • 2
  1. 1.Department of ChemistryAlzahra UniversityTehranIran
  2. 2.Pesticide Research DepartmentIranian Research Institute of Plant ProtectionTehranIran

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