Microchimica Acta

, 185:242 | Cite as

Silver microspheres coated with a molecularly imprinted polymer as a SERS substrate for sensitive detection of bisphenol A

  • Xiaohui Ren
  • Emily C. Cheshari
  • Jingyao Qi
  • Xin Li
Original Paper
  • 138 Downloads

Abstract

An efficient approach is demonstrated for preparing particles consisting of a silver core and a shell of molecularly imprinted polymer (Ag@MIP). The MIP is prepared by using bisphenol A (BPA) as the template and 4-vinylpyridine as the functional monomer. The Ag@MIP fulfills a dual function in that the silver core acts as a SERS substrate, while the MIP allows for selective recognition of BPA. The Ag@MIP is characterized by scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction, thermogravimetric analysis and Raman spectroscopy. The Raman intensity of Ag@MIP is higher than that of bare silver microspheres. The detection limit for BPA is as low as 10−9 mol·L−1.

Graphical abstract

Schematic illustration of the preparation of silver microspheres coated with a molecularly imprinted polymer (Ag@MIPs) for detecting bisphenol A (BPA) by surface enhanced Raman scattering (SERS).

Keywords

Core-shell system Chemical enhancement Electromagnetic enhancement Endocrine-disrupting chemicals Molecular imprinting 

Notes

Acknowledgements

We are grateful for the financial support of this research from the National Natural Science Foundation of China (51579057, 51379052), and State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology (2016DX07).

Compliance with ethical standards

The author(s) declare that they have no competing interests.

Supplementary material

604_2018_2772_MOESM1_ESM.doc (152 kb)
ESM 1 (DOC 152 kb)

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Copyright information

© Springer-Verlag GmbH Austria, part of Springer Nature 2018

Authors and Affiliations

  • Xiaohui Ren
    • 1
  • Emily C. Cheshari
    • 1
    • 2
  • Jingyao Qi
    • 3
  • Xin Li
    • 1
    • 3
  1. 1.MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbinChina
  2. 2.Chemistry and Biochemistry Department, School of Science and Applied TechnologyLaikipia UniversityNyahururuKenya
  3. 3.State Key Laboratory of Urban Water Resource and EnvironmentHarbin Institute of TechnologyHarbinChina

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