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Microchimica Acta

, Volume 181, Issue 15–16, pp 1931–1938 | Cite as

Magnetic ion imprinted polymer nanoparticles for the preconcentration of vanadium(IV) ions

  • Azam Aliakbari
  • Mostafa M. Amini
  • Kheirollah Mehrani
  • Hamid Reza Moghadam Zadeh
Original Paper

Abstract

An ion imprinted polymer coated onto magnetite (Fe3O4) nanoparticles is shown to be a useful magnetic sorbent for the fairly selective preconcentration of vanadium. The sorbent was prepared by radical copolymerization of 3-(triethoxysilyl)propyl methacrylate (the monomer), ethylene glycol dimethacrylate (the cross-linker), and the vanadium(IV) complex of 1-(2-pyridylazo-2-naphthol) in the presence of magnetite nanoparticles. The material was characterized by IR spectroscopy, scanning electron microscopy, and thermal analysis. The vanadium(IV) ions were removed from the imprint by a solution containing thiourea and HCl, and the eluent was submitted to AAS. The analytical efficiency and relative standard deviation are 99.4 and ±2.3 %, respectively, under optimum conditions, and the limit of detection is 20 ng mL−1. The method was successfully applied to the preconcentration and determination of vanadium(IV) ions in crude oil.

Figure

An ion imprinted polymer is coated on to magnetite nanoparticles as a useful magnetic sorbent for the fairly selective preconcentration of vanadium which can be used for vanadium determination in crude oil.

Keywords

Vanadium determination Fe3O4 magnetic nanoparticle Ion imprinted polymer Crude oil 

Notes

Acknowledgments

The financial support of Iranian National Science Foundation (Grant No. 91002839) is gratefully acknowledged.

Supplementary material

604_2014_1279_MOESM1_ESM.pdf (182 kb)
ESM 1 (PDF 182 kb)

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Copyright information

© Springer-Verlag Wien 2014

Authors and Affiliations

  • Azam Aliakbari
    • 1
  • Mostafa M. Amini
    • 1
  • Kheirollah Mehrani
    • 2
  • Hamid Reza Moghadam Zadeh
    • 2
  1. 1.Department of ChemistryShahid Beheshti University, G.C.TehranIran
  2. 2.Department of ChemistryIslamic Azad University, Science and Research BranchTehranIran

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