Microchimica Acta

, Volume 180, Issue 11–12, pp 1117–1125 | Cite as

A nanosized cadmium(II)-imprinted polymer for use in selective trace determination of cadmium in complex matrices

  • Mohammad Behbahani
  • Mozhgan Barati
  • Majid Kalate Bojdi
  • Ali Reza Pourali
  • Akbar Bagheri
  • Nasim Akbari Ghareh Tapeh
Original Paper

Abstract

We describe a nanosized Cd(II)-imprinted polymer that was prepared from 4-vinyl pyridine (the functional monomer), ethyleneglycol dimethacrylate (the cross-linker), 2,2′-azobisisobutyronitrile (the radical initiator), neocuproine (the ligand), and Cd(II) (the template ion) by precipitation polymerization in acetonitrile as the solvent. The imprinted polymer was characterized by X-ray diffraction, thermogravimetric analysis, differential thermal analysis, and scanning electron microscopy. The maximum adsorption capacity of the nanosized sorbent was calculated to be 64 mg g−1. Cadmium(II) was then quantified by FAAS. The relative standard deviation and limit of detection are 4.2 % and 0.2 μg L−1, respectively. The imprinted polymer displays improve selectivity for Cd(II) ions over a range of competing metal ions with the same charge and similar ionic radius. This nanosized sorbent is an efficient solid phase for selective extraction and preconcentration of Cd(II) in complex matrices. The method was successfully applied to the trace determination of Cd(II) in food and water samples.

Figure

We describe a nanosized ion-imprinted polymer (IIP) for the selective preconcentration of Cd(II) ions. The nanosized-IIP was characterized by X-ray diffraction, Fourier transform IR spectroscopy, thermogravimetric and differential thermal analysis, and by scanning electron microscopy.

Keywords

Cadmium Ion imprinted polymer Nanosized Precipitation polymerization Selective preconcentration 

Supplementary material

604_2013_1036_MOESM1_ESM.doc (64 kb)
ESM 1 (DOC 64 kb)

References

  1. 1.
    Manahan SE (1994) Environmental chemistry, 6th edn. Lewis Publishers, Boca RatonGoogle Scholar
  2. 2.
    Watson JS (1999) Separation methods for waste and environmental applications. Marcel Dekker, New YorkGoogle Scholar
  3. 3.
    Bruce King R (ed) (1994) Encyclopedia of inorganic chemistry, vol. 1. Wiley, Chichester, 455Google Scholar
  4. 4.
    Philip W (ed) (2005) Encyclopedia of toxicology, 2nd edn. Elsevier Ltd., Oxford, 375Google Scholar
  5. 5.
    Patnaik P (2007) A comprehensive guide to the hazardous properties of chemical substances, 3rd ed. John Wiley & Sons, Inc., 652Google Scholar
  6. 6.
    World Health Organization (1993) IARC monographs on the evaluation of carcinogenic risks to humans, vol. 58, GenevaGoogle Scholar
  7. 7.
    World Health Organization (2006) Guidelines for drinking-water quality, 3rd ed., vol. 1, Recommendations, GenevaGoogle Scholar
  8. 8.
    Official Journal of the European Communities, Council Directive 98/83/EC of 3 November 1998 on the Quality of Water Intended for Human ConsumptionGoogle Scholar
  9. 9.
    Unites States Environmental Protection Agency, National Primary Drinking Water Standards, June 2003Google Scholar
  10. 10.
    Welz B, Sperling M (1999) Atomic absorption spectrometry, 3 compl revth edn. Wiley-VCH, WeinheimGoogle Scholar
  11. 11.
    Bagheri A, Behbahani M, Amini MM, Sadeghi O, Taghizade M, Baghayi L, Salarian M (2012) Simultaneous separation and determination of trace amounts of Cd(II) and Cu(II) in environmental samples using novel diphenylcarbazide modified nanoporous silica. Talanta 89:455–461CrossRefGoogle Scholar
  12. 12.
    Bagheri A, Taghizadeh M, Behbahani M, Asgharinezhad AA, Salarian M, Dehghani A, Ebrahimzadeh H, Amini MM (2012) Synthesis and characterization of magnetic metal-organic frame work (MOF) as a novel sorbent, and its optimization by experimental design methodology for determination of palladium in environmental samples. Talanta 99:132–139CrossRefGoogle Scholar
  13. 13.
    Bagheri A, Behbahani M, Amini MM, Sadeghi O, Tootoonchi A, Dahaghin Z (2012) Preconcentration and separation of ultra-trace palladium ion using pyridine-functionalized magnetic nanoparticles. Microchim Acta 178:261–268CrossRefGoogle Scholar
  14. 14.
    Nabid MR, Sedghi R, Bagheri A, Behbahani M, Taghizadeh M, Oskooie HA, Heravi MM (2012) Preparation and application of poly(2-amino thiophenol)/MWCNTs nanocomposite for adsorption and separation of cadmium and lead ions via solid phase extraction. J Hazard Mater 203–204:93–100CrossRefGoogle Scholar
  15. 15.
    Behbahani M, Taghizadeh M, Bagheri A, Hosseini H, Salarian M, Tootoonchi A (2012) A nanostructured ion-imprinted polymer for the selective extraction and preconcentration of ultra-trace quantities of nickel ions. Microchim Acta 178:429–437CrossRefGoogle Scholar
  16. 16.
    Behbahani M, Bagheri A, Taghizadeh M, Salarian M, Sadeghi O, Adlnasab L, Jalali K (2013) Synthesis and characterisation of nano structure lead (II) ion-imprinted polymer as a new sorbent for selective extraction and preconcentration of ultra trace amounts of lead ions from vegetables, rice, and fish samples. Food Chem 138:2050–2056CrossRefGoogle Scholar
  17. 17.
    Ebrahimzadeh H, Behbahani M, Yamini Y, Adlnasab L, Asgharinezhad AA (2013) Optimization of Cu(II)-ion imprinted nanoparticles for trace monitoring of copper in water and fish samples using a Box–Behnken design. React Funct Polym 73:23–29CrossRefGoogle Scholar
  18. 18.
    Tuzen M, Soylak M, Elci L (2005) Multi-element preconcentration of heavy metal ions by solid phase extraction on chromosorb 108. Anal Chim Acta 548:101–108CrossRefGoogle Scholar
  19. 19.
    Tuzen M, Parlar K, Soylak M (2005) Enrichment/separation of cadmium(II) and lead(II) in environmental samples by solid phase extraction. J Hazard Mater 121:79–87CrossRefGoogle Scholar
  20. 20.
    Soylak M, Narin I (2005) An on-line preconcentration system for cadmium determination in environmental samples by flame atomic absorption spectrometry. Chemia Analityczna (Warsaw) 50:705–715Google Scholar
  21. 21.
    Fritz JS (1999) Analytical solid-phase extraction. Wiley-VCH, New YorkGoogle Scholar
  22. 22.
    Martin-Esteban A (2001) Molecularly imprinted polymers: new molecular recognition materials for selective solid-phase extraction of organic compounds. Fresenius J Anal Chem 370:795–802CrossRefGoogle Scholar
  23. 23.
    Mudiam MKR, Chauhan A, Singh KP, Gupta SK, Jain R, Ch R, Murthy RC (2013) Determination of t, t-muconic acid in urine samples using a molecular imprinted polymer combined with simultaneous ethyl chloroformate derivatization and pre-concentration by dispersive liquid–liquid microextraction. Microchim Acta 405:341–349Google Scholar
  24. 24.
    Junping W, Mingfei P, Guozhen F, Shuo W (2009) Preparation of a novel molecularly imprinted polymer by a sol–gel process for on-line solid-phase extraction coupled with high performance liquid chromatography to detect trace enrofloxacin in fish and chicken samples. Microchim Acta 166:295–302CrossRefGoogle Scholar
  25. 25.
    Turiel E, Martin-Esteban A (2004) Molecularly imprinted polymers: towards highly selective stationary phases in liquid chromatography and capillary electrophoresis. Anal Bioanal Chem 378:1876–1886CrossRefGoogle Scholar
  26. 26.
    Beltran A, Marcé RM, Cormack PAG, Borrull F (2009) Synthesis by precipitation polymerisation of molecularly imprinted polymer microspheres for the selective extraction of carbamazepine and oxcarbazepine from human urine. J Chromatogr A 1216:2248–2253CrossRefGoogle Scholar
  27. 27.
    Li P, Rong F, Yuan C (2003) Morphologies and binding characteristics of molecularly imprinted polymers prepared by precipitation polymerization. Polym Int 52:1799–1806CrossRefGoogle Scholar
  28. 28.
    Wang J, Cormack PAG, Sherrington DC, Khoshdel E (2003) Monodisperse molecularly imprinted polymer microspheres prepared by precipitation polymerization for affinity separation applications. Angew Chem 115:5494–5496CrossRefGoogle Scholar
  29. 29.
    Tamayo FG, Casillas JL, Martin-Esteban A (2003) Highly selective fenuron-imprinted polymer with a homogeneous binding site distribution prepared by precipitation polymerisation and its application to the clean-up of fenuron in plant samples. Anal Chim Acta 482:165–173CrossRefGoogle Scholar
  30. 30.
    Cacho C, Turiel E, Martin-Esteban A, Pérez-Conde C, Cámara C (2004) Characterisation and quality assessment of binding sites on a propazine-imprinted polymer prepared by precipitation polymerization. J Chromatogr B 802:347–353CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Wien 2013

Authors and Affiliations

  • Mohammad Behbahani
    • 1
  • Mozhgan Barati
    • 2
  • Majid Kalate Bojdi
    • 3
  • Ali Reza Pourali
    • 2
  • Akbar Bagheri
    • 1
  • Nasim Akbari Ghareh Tapeh
    • 2
  1. 1.Department of ChemistryShahid Beheshti UniversityTehranIran
  2. 2.School of ChemistryDamghan UniversityDamghanIran
  3. 3.Faculty of ChemistryKharazmi (Tarbiat Moallem) UniversityTehranIran

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