Bulletin of Volcanology

, 82:6 | Cite as

Pre-eruptive magmatic processes associated with the historical (218 ± 14 aBP) explosive eruption of Tutupaca volcano (southern Peru)

  • Nélida Manrique
  • Pablo SamaniegoEmail author
  • Etienne Médard
  • Federica Schiavi
  • Jersy Mariño
  • Céline Liorzou
Research Article


Magma recharge into a differentiated reservoir is one of the main triggering mechanisms for explosive eruptions. Here we describe the petrology of the eruptive products of the last explosive eruption of Tutupaca volcano (southern Peru) in order to constrain the pre-eruptive physical conditions (P-T-XH2O) of the Tutupaca dacitic reservoir. We demonstrate that prior to the paroxysm, magma in the Tutupaca dacitic reservoir was at low temperature and high viscosity (735 ± 23 °C), with a mineral assemblage of plagioclase, low-Al amphibole, biotite, titanite, and Fe-Ti oxides, located at 8.8 ± 1.6 km depth (233 ± 43 MPa). The phenocrysts of the Tutupaca dacites show frequent disequilibrium textures such as reverse zonation, resorption zones, and overgrowth rims. These disequilibrium textures suggest a heating process induced by the recharge of a hotter magma into the dacitic reservoir. As a result, high-Al amphibole and relatively high-Ca plagioclase phenocryst rims and microlites were formed and record high temperatures from just before the eruption (840 ± 45 °C). Based on these data, we propose that the recent eruption of Tutupaca was triggered by the recharge of a hotter magma into a highly crystallized dacitic magma reservoir. As a result, the resident dacitic magma was reheated and remobilized by a self-mixing process. These magmatic processes induced an enhanced phase of dome growth that provoked destabilization of the NE flank, producing a debris avalanche and its accompanying pyroclastic density currents.


Tutupaca Magma recharge Self-mixing Thermobarometry 



This work is part of a Peruvian-French cooperation programme carried out between the Instituto Geológico, Minero y Metalúrgico (INGEMMET, Peru), and the Institut de Recherche pour le Développement (IRD, France). We warmly thank F. van Wyk de Vries for improvements to the English in the manuscript. We are grateful to P. Ruprecht and an anonymous reviewer for their constructive comments and J. Fierstein and J. Taddeucci for the editorial handling. This is Laboratory of Excellence ClerVolc contribution no. 381.

Supplementary material

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  1. Anderson JL, Smith DR (1995) The effects of temperature and fO2 on the Al-in-hornblende barometer. Am Mineral 80(549):559Google Scholar
  2. Andujar J, Martel C, Pichavant M, Samaniego P, Scaillet B, Molina I (2017) Structure of the plumbing system at Tungurahua volcano, Ecuador: insights from phase equilibrium experiments on July-August 2006 eruption products. J Petrol 58:1249–1278Google Scholar
  3. Bachmann O, Dungan MA (2002) Temperature-induced Al-zoning in horblendes of the Fish Canyon magma, Colorado. Am Mineral 87:723–738Google Scholar
  4. Belousov A (1996) Deposits of the 30 March 1956 directed blast at Bezymianny volcano. Bull Volcanol 57:649–662Google Scholar
  5. Belousov A, Voight B, Belousova M (2007) Directed blasts and blast-generated pyroclastic density currents: a comparison of the Bezymianny 1956, Mount St Helens 1980, and Soufrière Hills, Montserrat 1997 eruptions and deposits. Bull Volcanol 69:701–740Google Scholar
  6. Benavente C, Zerathe S, Audin L, Hall SR, Robert X, Delgado F, Carcaillet J, ASTER Team (2017) Active transpressional tectonics in the Andean forearc of southern Peru quantified by 10Be surface exposure dating of an active fault scarp. Tectonics 36. Google Scholar
  7. Bindeman IN, Davis AM, Drake MJ (1998) Ion microprobe study of plagioclase-basalt partition experiments at natural concentration levels of trace elements. Geochim Cosmochim Acta 62:1175–1193Google Scholar
  8. Blundy J, Holland T (1990) Calcic amphibole equilibria and a new amphibole-plagioclase geothermometer. Contrib Mineral Petrol 104:208–224Google Scholar
  9. Castro JM, Dingwell DB (2009) Rapid ascent of rhyolitic magma at Chaitén volcano, Chile. Nature 461:780–783Google Scholar
  10. Castruccio A, Clavero J, Segura A, Samaniego P, Roche O, Le Pennec JL, Droguett B (2016) Eruptive parameters and dynamics of the April 2015 sub-Plinian eruptions of Calbuco volcano (southern Chile). Bull Volcanol 78:62Google Scholar
  11. Chen Y, Provost A, Schiano P, Cluzel N (2011) The rate of water loss from olivine-hosted melt inclusions. Contrib Mineral Petrol 162:625–636Google Scholar
  12. Cotten J, Le Dez A, Bau M, Caroff M, Maury RC, Dulski P, Fourcade S, Bohn M, Brousse R (1995) Origin of anomalous rare-earth element and Yttrium enrichments in subaerial exposed basalts: evidence from French Polynesia. Chem Geol 119:115–138Google Scholar
  13. Couch S, Sparks RSJ, Carroll MR (2001) Mineral disequilibrium in lavas explained by convective self-mixing in open magma chambers. Nature 41:1037–1039Google Scholar
  14. De Angelis SH, Larsen J, Coombs M (2013) Pre-eruptive magmatic conditions at Augustine volcano, Alaska, 2006: evidence from amphibole geochemistry and textures. J Petrol 54:1939–1961Google Scholar
  15. Erdmann S, Martel C, Pichavant M, Kushnir A (2014) Amphibole as an archivist of magmatic crystallization conditions: problems, potential, and implications for inferring magma storage prior to the paroxysmal 2010 eruption of Mount Merapi, Indonesia. Contrib Mineral Petrol 167:1016Google Scholar
  16. Fidel L, Zavala B (2001) Mapa preliminar de amenaza volcánica del volcán Tutupaca. Boletín 24, Serie C: Geodinámica e Ingeniería Geológica. INGEMMET, p 109Google Scholar
  17. Gaetani GA, O’Leary JA, Shimizu N, Bucholv CE, Newville M (2012) Rapid re-equilibration of H2O and oxygen fugacity in olivine-hosted inclusions. Geology 40:915–918Google Scholar
  18. Giletti BJ, Shanahan TM (1997) Alkali diffusion in plagioclase feldspar. Chem Geol 139:3–20Google Scholar
  19. Ginibre C, Wörner G, Kronz A (2002) Minor- and trace-element zoning in plagioclase: implications for magma chamber processes at Parinacota Volcano, northern Chile. Contrib Mineral Petrol 143:300–315Google Scholar
  20. Hattori K, Sato H (1996) Magma evolution recorded in plagioclase zoning in 1991 Pinatubo eruption products. Am Mineral 81:982–994Google Scholar
  21. Hayden LA, Watson EB, Wark DA (2008) A thermobarometer for sphene (titanite). Contrib Mineral Petrol 155:529–540Google Scholar
  22. Hoblitt RP, Miller CD, Vallance JW (1981) Origin and stratigraphy of the deposit produced by the May 18 directed blast. In: Lipman PW, Mullineaux DR (eds) The 1980 eruptions of Mount St. Helens, vol 1250. USGS Prof Paper, Washington, pp 401–419Google Scholar
  23. Holland T, Blundy J (1994) Non-ideal interactions in calcic amphiboles and their bearing on amphibole-plagioclase thermometry. Contrib Mineral Petrol 116:433–447Google Scholar
  24. Holtz F, Sato H, Lewis J, Behrens H, Nakada S (2005) Experimental petrology of the 1991 – 1995 Unzen Dacite, Japan . Part I: phase relations, phase composition and pre-eruptive conditions. J Petrol 46:319–337Google Scholar
  25. Humphreys MCS, Christopher T, Hards V (2009) Microlite transfer by disaggregation of mafic inclusions following magma mixing at Soufrière Hills volcano Montserrat. Contrib Mineral Petrol 157:609–624. CrossRefGoogle Scholar
  26. Johnson MC, Rutherford MJ (1989) Experimental calibration of the aluminum-in-hornblende geobarometer with application to Long Valley caldera (California) volcanic rocks. Geology 17:837–841Google Scholar
  27. Kiss B, Harangi S, Ntaflos T, Mason PRD, Pál-Molnár E (2014) Amphibole perspective to unravel pre-eruptive processes and conditions in volcanic plumbing systems beneath intermediate arc volcanoes: a case study from Ciomadul volcano (SE Carpathians). Contrib Mineral Petrol 167:986Google Scholar
  28. Kono M, Fukao Y, Yamamoto A (1989) Mountain building in the Central Andes. J Geophys Res 94:3891–3905Google Scholar
  29. Lange R, Frey H, Hector J (2009) A thermodynamic model for the plagioclase-liquid hygrometer/thermometer. Am Mineral 94:494–506Google Scholar
  30. Lara LE, Naranjo JA, Moreno H (2004) Rhyodacitic fissure eruption in Southern Andes (Cordón Caulle; 40.5°S) after the 1960 (Mw:9.5) Chilean earthquake: a structural interpretation. J Volcanol Geotherm Res 138:127–138Google Scholar
  31. Lasaga AC (1998). Kinetic theory in the earth sciences. Princetown series in geochemistry. Princeton University Press, Princeton.Google Scholar
  32. Leake BE, Woolley AR, Arps CES, Birch WD, Gilbert MC, Grice JD, Hawthorne FC, Kato A, Kisch HJ, Krivovichev VG, Linthout K, Laird J, Mandarino JA, Maresch WV, Nickel EH, Rock NMS, Schumacher JC, Smith DC, Stephenson CN, Ungaretti L, Whittaker EJW, Youzhi G (1997) Nomenclature of amphiboles: report of the Subcommittee on Amphiboles of the International Mineralogical Association, commission on new minerals and minerals’ names. Am Mineral 82:1019–1037Google Scholar
  33. Lloyd AS, Plank T, Ruprecht P, Hauri EH, Rose W (2012) Volatile loss from melt inclusions in pyroclasts of differing sizes. Contrib Mineral Petrol 165:129–153Google Scholar
  34. Mamani M, Wörner G, Sempere T (2010) Geochemical variation in igneous rocks of the Central Andean orocline (13 °S to 18 °S): tracing crustal thickening and magmas generation through time and space. Geol Soc Am Bull 97:241–254Google Scholar
  35. Mariño J, Samaniego P, Manrique N, Valderrama P, Macedo L (2019) Geología y mapa del Complejo Volcánico Tutupaca. INGEMMET, Boletín, Serie C: Geodinámica e Ingeniería Geológica, 66, 165 p., 2 mapas.Google Scholar
  36. Médard E, Le Pennec JL (2019) Petrologic imaging of the magma chambers that feed super-eruptions. SubmittedGoogle Scholar
  37. Médard E, Le Pennec JL, Francomme JE, Temel A, Nauret F (2013) Reconstructing the magma feeding system of the Cappadocian ignimbrites (Turkey) through amphibole thermobarometry. Goldschmidt conference, FlorenceGoogle Scholar
  38. Morimoto N, Fabries J, Ferguson AK, Ginzburg IV, Ross M, Seifert FA, Zussman J (1988) Nomenclature of pyroxenes. Am Mineral 73:1123–1133Google Scholar
  39. Murphy MD, Sparks RSJ, Barclay J, Carroll MR, Brewer TS, Gene DE (2000) Remobilization of andesite magma by intrusion of mafic magma at the Soufriere Hills Volcano, Montserrat, West Indies. J Petrol 41:21–42Google Scholar
  40. Mutch EJF, Blundy JD, Tattitch BC, Cooper FJ, Brooker RA (2016) An experimental study of amphibole stability in low-pressure granitic magmas and a revised Al-in-hornblende geobarometer. Contrib Mineral Petrol 171:85Google Scholar
  41. Pallister JS, Hoblitt RP, Reyes AG (1992) A basalt trigger for the 1991 eruptions of Pinatubo volcano? Nature 356:426–428Google Scholar
  42. Peccerillo P, Taylor SR (1976) Geochemistry of Eocene calc-alkaline volcanic rocks from the Kastamonu area, northern Turkey. Contrib Mineral Petrol 58:63–81Google Scholar
  43. Poli S, Schmidt MW (1992) A comment on calcic amphibole equilibria and a new amphibole-plagioclase thermometre by JD Blundy and TJB Holland. Contrib Mineral Petrol 104:208–224Google Scholar
  44. Prouteau G, Scaillet B (2003) Experimental constraints on the origin of the 1991 Pinatubo dacite. J Petrol 44:2203–2241Google Scholar
  45. Ridolfi F, Renzulli A (2012) Calcic amphiboles in calc-alkaline and alkaline magmas: thermobarometric and chemometric empirical equations valid up to 1130oC and 2.2 GPa. Contrib Mineral Petrol 163:877–895Google Scholar
  46. Ridolfi F, Renzulli A, Puerini M (2010) Stability and chemical equilibrium of amphibole in calc-alkaline magmas: an overview, new thermobarometric formulations and application to subduction-related volcanoes. Contrib Mineral Petrol 160:45–66Google Scholar
  47. Rivera M, Thouret JC, Samaniego P, Le Pennec JL (2014) The 2006–2009 activity of Ubinas volcano (Peru): petrology of the 2006 eruptive products and insights into genesis of andesite magmas, magma recharge and plumbing system. J Volcanol Geotherm Res 270:122–141Google Scholar
  48. Rivera M, Martin H, Le Pennec JL, Thouret JC, Gourgaud A, Gerbe MC (2017) Petro-geochemical constraints on the source and evolution of magmas at El Misti volcano (Peru). Lithos 268–271:240–259aGoogle Scholar
  49. Rubin AE, Cooper KM, Till CB, Kent AJR, Costa F, Bose M, Gravley D, Deering C, Cole J (2017) Rapid cooling and cold storage in a silicic magma reservoir recorded in individual crystals. Science 356:1154–1156Google Scholar
  50. Ruprecht P, Bachmann O (2010) Pre-eruptive reheating during magma mixing at Quizapu volcano and the implications for the explosiveness of silicic arc volcanoes. Geology 38:919–922Google Scholar
  51. Ruprecht P, Wörner G (2007) Variable regimes in magma systems documented in plagioclase zoning patterns: El Misti stratovolcano and Andahua monogenetic cones. J Volcanol Geotherm Res 165:142–162Google Scholar
  52. Ruprecht P, Bergantz G, Cooper K, Hildreth W (2012) The crustal magma storage system of Volcán Quizapu, Chile, and the effects of magma mixing on magma diversity. J Petrol 53:801–840. CrossRefGoogle Scholar
  53. Rutherford MJ, Devine JD (1988) The May 18, 1980, Eruption of Mount St. Helens 3. Stability and chemistry of amphibole in the magma chamber. J Geophys Res 93:11949–11959Google Scholar
  54. Rutherford MJ, Devine JD (2003) Magmatic conditions and magma ascent as indicated by hornblende phase equilibria and reactions in the 1995–2002 Soufrière Hills magma. J Petrol 44:1433–1454Google Scholar
  55. Rutherford MJ, Hill P (1993) Magma ascent rates from amphibole breakdown: an experimental study applied to the 1980–1986 Mount St. Helens eruptions. J Geophys Res:98:19667–19685. Google Scholar
  56. Samaniego P, Le Pennec JL, Robin C, Hidalgo S (2011) Petrological analysis of the pre-eruptive magmatic process prior to the 2006 explosive eruptions at Tungurahua volcano (Ecuador). J Volcanol Geotherm Res 199:69–84Google Scholar
  57. Samaniego P, Valderrama P, Mariño J, van Wyk de Vries B, Roche O, Manrique N, Chédeville C, Liorzou C, Fidel L, Malnati J (2015) The historical (218 ± 14 aBP) explosive eruption of Tutupaca volcano (Southern Peru). Bull Volcanol 77:51Google Scholar
  58. Samaniego P, Rivera M, Mariño J, Guillou H, Liorzou C, Zerathe S, Delgado R, Valderrama P, Scao V (2016) The eruptive chronology of the Ampato–Sabancaya volcanic complex (Southern Peru). J Volcanol Geotherm Res 323:110–128Google Scholar
  59. Scaillet B, Evans BW (1999) The 15 June 1991 Eruption of Mount Pinatubo: I. Phase equilibria and pre-eruption P–T–fO2fH2O conditions of the dacite magma. J Petrol 40:381–411Google Scholar
  60. Schiavi F, Bolfan-Casanova N, Withers AC, Médard E, Laumonier M, Laporte D, Flaherty T, Gomez-Ulla A (2018) Water quantification in silicate glasses by Raman spectroscopy: correcting for the effects of confocality, density and ferric iron. Chem Geol 483:312–331Google Scholar
  61. Schmidt MW (1992) Amphibole composition in tonalite as a function of pressure: an experimental calibration of the Al-in-hornblende barometer. Contrib Mineral Petrol 110:304–310Google Scholar
  62. Shane P, Smith VC (2013) Using amphibole crystals to reconstruct magma storage temperatures and pressures for the post-caldera collapse volcanism at Okataina volcano. Lithos 156–159:159–170Google Scholar
  63. Stix J, Torres R, Narváez L, Cortés G, Raigosa J, Gómez D, Castonguay R (1997) A model of Vulcanian eruptions at Galeras volcano, Colombia. J Volcanol Geotherm Res 77:285–303Google Scholar
  64. Sun SS, McDonough WF (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. In: Saunders AD, Norry MJ (eds) Magmatism in the ocean basins. Special Publication 42. Geological Society, London, pp 313–345Google Scholar
  65. Tepley FJ, de Silva S, Salas G (2013) Magma dynamics and petrological evolution leading to the VEI 5 2000 BP eruption of El Misti volcano, Southern Peru. J Petrol 54:2033–2065Google Scholar
  66. Thouret J, Wörner G, Gunnell Y, Singer B, Zhang X, Souriot T (2007) Geochronologic and stratigraphic constraints on canyon incision and Miocene uplift of the Central Andes in Peru. Earth Planet Sci Lett 263:151–166Google Scholar
  67. Valderrama P, Roche O, Samaniego P, van Wyk de Vries B, Bernard K, Mariño J (2016) Dynamic implications of ridges on a debris avalanche deposit at Tutupaca volcano (southern Peru). Bull Volcanol 78:14Google Scholar
  68. Valdivia JG (1847) Fragmentos para la historia de Arequipa. Folletín de “El Deber”, Arequipa, 109–111 pGoogle Scholar
  69. Van Orman JA, Cherniak DJ, Kita NT (2014) Magnesium diffusion in plagioclase: dependence on composition, and implications for thermal resetting of the 26Al–26Mg early solar system chronometer. Earth Planet Sci Lett 385:79–88Google Scholar
  70. Voight B, Komorowski JC, Norton GE, Belousov AB, Belousova M, Boudon G, Francis PW, Franz W, Heinrich P, Sparks RSJ, Young SR (2002) The 1997 Boxing Day sector collapse and debris avalanche, Soufriere Hills Volcano, Montserrat, W.I. In: Druitt T, Kokelaar BP (eds), The eruption of Soufrière Hills Volcano, Montserrat, from 1995 to 1999. Mem Geol Soc London 21:363– 407Google Scholar
  71. Waters LE, Lange RA (2015) An updated calibration of the plagioclase-liquid hygrometer-thermometer applicable to basalts through rhyolites. Am Mineral 100:2172–2184Google Scholar
  72. Zamàcola y Jaúregui JD (1804) Apuntes para la historia de Arequipa. Imp. De La Bolsa-Guañamarca, N. 49. 1888Google Scholar
  73. Zhang X, Liu B, Wang J, Zhang Z, Shi K, Wu S (2014) Adobe photoshop quantification (PSQ) rather than point-counting: a rapid and precise method for quantifying rock textural data and porosities. Comput Geosci 69:62–71Google Scholar

Copyright information

© International Association of Volcanology & Chemistry of the Earth's Interior 2019

Authors and Affiliations

  1. 1.Observatorio Vulcanológico del INGEMMETDirección de Geología Ambiental y Riesgo GeológicoArequipaPeru
  2. 2.Laboratoire Magmas et Volcans, OPGCUniversité Clermont Auvergne-CNRS-IRDClermont-FerrandFrance
  3. 3.Laboratoire Géosciences Océan, Institut Universitaire Européen de la MerUniversité de Bretagne OccidentalePlouzanéFrance

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