Zircon and quartz inclusions in garnet used for complementary Raman thermobarometry: application to the Holsnøy eclogite, Bergen Arcs, Western Norway
- 432 Downloads
Mineral inclusions are common and have been widely used to investigate complex geological history. When a rock undergoes cooling and decompression after the entrapment of an inclusion into a host mineral, residual pressure may develop within the inclusion because of the differences in thermal expansivity and compressibility between the inclusion and host. By combining laser Raman spectroscopy and experimental data relating hydrostatic pressure and Raman shift, it is possible to estimate the entrapment pressure–temperature (P–T) conditions using an isotropic elastic model. In this study, we report Raman spectroscopic data on both zircon and quartz inclusions in garnet host from the Holsnøy eclogite, Bergen Arcs, Norway. Averaged residual pressures based on different Raman peaks for zircon and quartz inclusions are obtained to be ca. 0.6 GPa and ca. 0.65 GPa respectively. Using the equation of state for zircon and quartz, the entrapment P–T conditions are constrained to be 1.7–1.9 GPa, 680–760 °C, consistent with previous estimates based on phase equilibria. Heating/cooling experiments are performed on an entrapped zircon inclusion. A clear trend is found between the residual zircon inclusion pressure and the externally controlled temperature. We show that the residual zircon inclusion pressure sealed in garnet host is very sensitive to the entrapment temperature, and can be used as a Raman thermometer. The effects of laser heating and the thermo-elastic anisotropy of zircon inclusion are quantified and discussed.
KeywordsZircon Inclusion Raman spectroscopy Thermobarometry Eclogite
H. Austrheim is sincerely acknowledged for providing the thin-section samples. S. Simonsen is thanked for her technical support with SEM/EDS. XZ thanks S. Cionoiu, H. Wang and J. Szczepański for helpful discussions. This project has been supported by the Early-Postdoc Mobility Fellowship of Swiss National Science Foundation (SNSF) (P2EZP2_172220) to XZ, and the European Union’s Horizon 2020 Research and Innovation Programme under the ERC Advanced Grant Agreement no. 669972, ‘Disequilibrium Metamorphism’ (‘DIME’) to BJ. MD acknowledges PGI-NRI project no. 61-9015-1601-00-0. We thank D. Rubatto for editorial work and two anonymous reviewers for their helpful comments.
- Angel RJ, Gonzalez-Platas J, Alvaro M (2014a) EosFit7c and a Fortran module (library) for equation of state calculations. Zeitschrift fur Krist 229:405–419Google Scholar
- Angel RJ, Murri M, Mihailova B, Alvaro M (2018) Stress, strain and Raman shifts. Zeitschrift für Krist 234:129–140Google Scholar
- Barkoff DW, Ashley KT, Steele-macinnis M (2018) Pressures of skarn mineralization at casting copper, Nevada, USA, based on apatite inclusions in garnet. Geology 1:638Google Scholar
- Bass JD (1995) Elasticity of minerals, glasses, and melts. In: Mineral physics & crystallography: a handbook of physical constants, vol 2. pp 45–63Google Scholar
- Eshelby JD (1957) The determination of the elastic field of an ellipsoidal inclusion, and related problems. In: Proceedings of the royal society of London. Series A. Mathematical and physical sciences, vol 241. pp 376–396Google Scholar
- Fei Y (1995) Thermal expansion. In: Mineral physics and crystallography: a handbook of physical constants, vol 2. pp 29–44Google Scholar
- Liu L, Mernagh TP (1992) High pressure Raman study of the a-quartz forms of SiO2 and GeO2 at room temperature. High Temp Press 24:13–21Google Scholar
- Murri M, Mazzucchelli ML, Campomenosi N et al (2018) Raman elastic geobarometry for anisotropic mineral inclusions. Am Miner 103:1869–1872Google Scholar
- Spear FS (1995) Metamorphic phase equilibria and presure-temperature-time-paths. In: Monographs. Mineralogical Society of America. ISBN 0-939950-34-0Google Scholar