Abstract
Although zircon is the most widely used geochronometer to determine the crystallisation ages of granites, it can be unreliable for low-temperature melts because they may not crystallise new zircon. For leucocratic granites U–Pb zircon dates, therefore, may reflect the ages of the source rocks rather than the igneous crystallisation age. In the Proterozoic Capricorn Orogen of Western Australia, leucocratic granites are associated with several pulses of intracontinental magmatism spanning ~800 million years. In several instances, SHRIMP U–Pb zircon dating of these leucocratic granites either yielded ages that were inconclusive (e.g., multiple concordant ages) or incompatible with other geochronological data. To overcome this we used SHRIMP U–Th–Pb monazite geochronology to obtain igneous crystallisation ages that are consistent with the geological and geochronological framework of the orogen. The U–Th–Pb monazite geochronology has resolved the time interval over which two granitic supersuites were emplaced; a Paleoproterozoic supersuite thought to span ~80 million years was emplaced in less than half that time (1688–1659 Ma) and a small Meso- to Neoproterozoic supersuite considered to have been intruded over ~70 million years was instead assembled over ~130 million years and outlasted associated regional metamorphism by ~100 million years. Both findings have consequences for the duration of associated orogenic events and any estimates for magma generation rates. The monazite geochronology has contributed to a more reliable tectonic history for a complex, long-lived orogen. Our results emphasise the benefit of monazite as a geochronometer for leucocratic granites derived by low-temperature crustal melting and are relevant to other orogens worldwide.
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Introduction
Leucocratic granites are peraluminous [i.e., alumina saturation index (ASI) = molar Al2O3/(CaO + Na2O + K2O) > 1; Scaillet et al. 2016; Zen 1986] rocks containing <5 vol.% mafic minerals (Le Maitre 1989). They are typically derived from low-temperature (<750 °C; Ayres et al. 1997; Scaillet et al. 1995) partial melting of crustal sources without direct mass input from the mantle (Gao et al. 2017; Patiño and Harris 1998). Leucocratic granites are common in intracontinental and collisional settings and typically account for a small proportion of all granites in orogenic belts (Gilotti and McClelland 2005; Harrison et al. 1999; Kemp and Hawkesworth 2003). However, they are important for determining the tectonic history of orogenic belts (Crowley et al. 2008) as they commonly form during periods of crustal thickening (Brown 1994). Kemp and Hawkesworth (2003) divided leucocratic granites into two types on the basis of their Sr concentrations: a low-Sr (<200 ppm Sr) type formed by melting in the upper continental crust (e.g., leucogranites of the Himalayan Orogen), and the less common high-Sr (250–450 ppm) types related to deeper crustal sources (e.g., Glenelg River Complex, southeastern Australia).
Dating leucocratic, low-temperature granites (sensu lato) using U–Pb zircon geochronology can be challenging due to the zircon population being dominated by inherited grains (Bea et al. 2007; Harrison et al. 1999; Miller et al. 2003; Schärer et al. 1986). Experimental studies have shown that zircon solubility is mainly governed by temperature and melt composition, and for typical peraluminous melts zircon solubility ranges from ~100 ppm dissolved at 750 °C to 1300 ppm at 1020 °C (Boehnke et al. 2013; Watson and Harrison 1983). This means that the low solubility of Zr in low-temperature (<800 °C) crustal melts limits the amount of zircon that can dissolve during partial melting and re-precipitate during crystallisation. These findings are consistent with observations that low-temperature granites (mean 766 ± 24 °C) with abundant inherited zircon typically have lower Zr concentrations (80–150 ppm) compared with high-temperature granites (200–800 ppm, mean 837 ± 48 °C) with minimal inheritance (Miller et al. 2003).
Although zircon is most widely used to constrain crystallisation ages of granites, monazite geochronology has been employed sporadically to date the crystallisation age of granites (e.g., Grosse et al. 2009; Harrison et al. 1999; Kusiak et al. 2014; Miller and Mittlefehldt 1982; Parrish and Tirrul 1989; Townsend et al. 2001; Williams et al. 1983). However, there has been little attempt to systematically evaluate the suitability of monazite for geochronology of leucocratic granite types even though monazite appears to be common in a range of granites (Bea 1996; Montel 1993; Rapp and Watson 1986). The stability of monazite is considered to be dependent on pressure, temperature, bulk rock chemistry and interacting fluid chemistry (Budzyń et al. 2011; Poitrasson et al. 1996). It has been suggested that monazite is stable in host compositions that are low in Ca (<0.7%) in contrast to higher Ca (>1.8%) which favour allanite growth (Lee and Dodge 1964; Montel 1993; Parrish 1990), although monazite and allanite do coexist in peraluminous granites (Broska et al. 2000). Furthermore, although not widespread, instances of monazite inheritance in granites have been documented (Copeland et al. 1988; Parrish 1990).
Leucocratic granites are widespread in the Proterozoic Gascoyne Province, Capricorn Orogen of Western Australia, and apparently formed during several episodes of magmatism (Sheppard et al. 2010b). The crystallisation ages of several leucocratic granites are not well defined by U–Pb zircon geochronology, which has created uncertainty about the duration and distribution of some of the granite supersuites and related orogenic events in the province. In this paper we use SHRIMP U–Th–Pb monazite geochronology to re-evaluate the emplacement ages of these granites in order to obtain reliable igneous crystallisation ages consistent with the existing geological framework. In turn, this provides better constraints on the duration of granitic magmatism and magma production rates and allows for a more complete magmatic and tectonothermal history of the orogen to be established.
Regional geology
The study area is located in the Capricorn Orogen in Western Australia (Fig. 1), which records the Paleoproterozoic assembly of the West Australian Craton by c. 1950 Ma (Johnson et al. 2011; Occhipinti et al. 2004). Five subsequent, episodic intracontinental reworking and reactivation events spanning nearly 1.5 billion years have shaped the current architecture of this orogen (Bodorkos and Wingate 2007; Korhonen et al. 2015; Sheppard et al. 2005, 2007, 2010a). All of these tectonic events are known from the Gascoyne Province, at the presently exposed western end of the orogen (Fig. 1). Of the five intracontinental reworking events in the Gascoyne Province, two are accompanied by voluminous, mainly high-temperature granitic magmatism (i.e., the Capricorn Orogeny being associated with the 1820–1775 Ma Moorarie Supersuite, and the Mangaroon Orogeny with the 1680–1620 Ma Durlacher Supersuite), whereas a third, spatially restricted event (the Edmundian Orogeny) was accompanied solely by leucocratic granitic magmatism (995–955 Ma Thirty-Three Supersuite) (Sheppard et al. 2010b).
The 1820–1775 Ma Moorarie Supersuite was emplaced during the Capricorn Orogeny (Sheppard et al. 2010a, b) and comprises batholiths and plutons of weakly peraluminous, biotite-bearing monzogranite and granodiorite, with minor syenogranite, tonalite and quartz diorite, although, biotite (–muscovite–tourmaline)-bearing monzogranite is common in the southern Gascoyne Province. Most granites of the Moorarie Supersuite contain little or no xenocrystic zircon so that their igneous crystallisation ages are well constrained. A number of undated plutons have also been assigned to the supersuite on the basis of their field relationships, including a pluton of leucocratic granodiorite 12 km long by 5 km wide in the Errabiddy Shear Zone, which marks the boundary between the Yilgarn Craton and Gascoyne Province (Figs. 1, 2a). The pluton, referred to as the Erong Granite, cuts across Paleoproterozoic (c. 1950 Ma) migmatitic structures in surrounding metamorphic rocks (Occhipinti et al. 2001). However, previous SHRIMP U–Pb zircon dating of the granodiorite (GSWA 139466) only yielded an Archean maximum crystallisation age (Nelson 2000).
The 1680–1620 Ma Durlacher Supersuite comprises peraluminous biotite–muscovite monzogranite, granodiorite, and syenogranite and some leucocratic muscovite–tourmaline (–biotite) monzogranite (Sheppard et al. 2005, 2010b). Crystallisation ages of the Durlacher Supersuite granites are well constrained by U–Pb zircon geochronology and most granites are older than c. 1659 Ma (Sheppard et al. 2010b) with two main exceptions: the c. 1620 Ma Discretion Granite (Nelson 1998) and one leucocratic sample (Fig. 2b) from the northern Gascoyne Province (GSWA 169092). This leucocratic granite (GSWA 169092) yielded two concordant ages 60 million years apart, none of which could be interpreted unequivocally as the crystallisation age. The younger age component is within error of the igneous crystallisation age of c. 1620 Ma for a batholith (Discretion Granite) about 250 km to the southeast (Fig. 1), and both samples were used to provide a minimum age for the Mangaroon Orogeny (Sheppard et al. 2005).
Intrusion of the 995–955 Ma Thirty-Three Supersuite (Fig. 2c) coincided with deformation and metamorphism of the Edmundian Orogeny within a narrow structural corridor in the centre of the Gascoyne Province (Sheppard et al. 2007). The supersuite crops out over an area 70 km long by 10 km wide and is structurally bound to the north by the Ti Tree Shear Zone (Fig. 2c). The Thirty-Three Supersuite comprises muscovite (–tourmaline) metamonzogranite, biotite-muscovite (–tourmaline) monzogranite and granodiorite and a belt of muscovite-tourmaline and rare-element bearing pegmatites (Sheppard et al. 2010b). Crystallisation ages for Thirty-Three Supersuite granites have proven difficult to resolve via U–Pb zircon geochronology due to the presence of copious xenocrystic zircon. Early indications were that the granites belonged to the Paleoproterozoic Durlacher Supersuite (Culver 2001). This appeared to be consistent with the fact that the leucocratic granites and pegmatites do not intrude Mesoproterozoic sedimentary rocks of the Bangemall Supergroup within the Ti Tree Shear Zone (Fig. 2c). However, later in situ monazite geochronology showed that the granites cut metamorphic fabrics formed at 1030–990 Ma (Sheppard et al. 2007).
Sample descriptions and previous zircon geochronology
Leucocratic granite samples analysed previously using U–Pb zircon geochronology were re-analysed in this study using U–Th–Pb monazite geochronology. Presented below are the original zircon geochronology results for selected peraluminous, leucocratic samples from three generations of Proterozoic magmatism (Table 1). The corresponding monazite geochronology is discussed in the subsequent results section.
GSWA 139466
This sample is a medium-grained, equigranular biotite–muscovite granodiorite that grades into coarser grained granite and pegmatite (Occhipinti et al. 2001). The sample contains minor muscovite and approximately 5% total mafic minerals (biotite, garnet and epidote) (Fig. 3a). Minor sericitisation, quartz recrystallisation and biotite replacement by chlorite is evidence of a weak metamorphic overprint. The zircon crystals are equant to elongate and euhedral pale green to black, 30–250 μm long and 25–80 μm wide, with only a few grains showing subtle internal zoning (Nelson 2000). U–Pb zircon geochronology yielded a date of 2621 ± 9 Ma (all ages in this paper are quoted with 95% uncertainties, unless indicated otherwise) (Nelson 2000). This age is interpreted to represent the age of a xenocrystic population because the pluton intruded 1965–1945 Ma granitic rocks and 2001–1955 Ma metasedimentary rocks (Sheppard et al. 2010b) and crosscuts deformation fabrics related to the 2005–1950 Ma Glenburgh Orogeny (Figs. 2a, 3a). The granodiorite is overprinted by Neoproterozoic (c. 900 Ma) mylonite zones (Occhipinti and Reddy 2009), but this is the only minimum constraint on its age. The low whole-rock Zr content (60 ppm; Table 1) is characteristic of a rock dominated by inherited zircons (Miller et al. 2003), and the combination of high Sr (369 ppm) and low Rb is consistent with the granite having formed by fluid-fluxed melting of muscovite during crustal anatexis (Gao et al. 2017). The rare-earth elements (La, Ce and Nd) are abundant in the whole rock composition (Table 1).
GSWA 169092
This sample is from a leucocratic granite unit located in the northern Gascoyne Province where it intrudes 1840–1810 and 1760–1680 Ma metasedimentary rocks and is overlain by 1620–1450 Ma siliciclastic rocks (Sheppard et al. 2010b) (Fig. 2b). It is a massive, medium-grained biotite–muscovite monzogranite (Figs. 3b, 4b) with minor muscovite and 5% mafic minerals (chlorite, epidote, tourmaline and garnet). Biotite is partly replaced by chlorite, and minor sericite and undulose extinction in the quartz and recrystallised quartz are indicative of a weak metamorphic overprint. The zircon crystals are euhedral to anhedral, 100–250 μm long and 40–180 μm wide, pale brown, dark brown or black, with only a minority of grains displaying subtle zoning (Nelson 2004). Zircon geochronology yielded two age components, one at 1810 ± 22 and 1681 ± 10 Ma, and one concordant analysis at 1619 ± 15 Ma (1σ) which, at the time, was interpreted as the maximum crystallisation age (Nelson 2004) and used by Sheppard et al. (2005) to constrain the younger limits of the 1680–1620 Ma Mangaroon Orogeny. Although a recent re-interpretation has concluded the younger analysis to represent Pb loss (M. Wingate pers. comm., March 14, 2016), it remained unclear as to whether the 1681 ± 10 Ma population should be interpreted as the crystallization age or a maximum for crystallization. Whole-rock geochemistry of the geochronology sample (Table 1) indicates that it has low Zr (70 ppm) and low Sr (63 ppm) contents and elevated rare-earth element contents ((La, Ce and Nd).
GSWA 183287, 183288, and 187401
Sample GSWA 183287 is a medium- to coarse-grained, equigranular muscovite–tourmaline granodiorite with 5% tourmaline and garnet (Figs. 3c, 4c). The presence of partly sericitised plagioclase, recrystallised quartz, and minor myrmekitic textures suggest a thermal overprint. The zircons are typically anhedral, up to 150 μm long, ranging from colourless to brown and most grains have idiomorphic zoning (Kirkland et al. 2009). Zircons from this sample yielded a range of dates between 2085 and 1309 Ma, interpreted as the ages of xenocrystic zircon (Kirkland et al. 2009) because the granite cross-cuts Neoproterozoic metamorphic fabrics in surrounding metasedimentary rocks (Sheppard et al. 2007). GSWA 183288 is a strongly porphyritic medium-grained, biotite-muscovite–tourmaline monzogranite. It contains about 15% biotite and ~2% muscovite and tourmaline combined. Plagioclase is partially sericitised, quartz is recrystallised, minor myrmekite is developed, and biotite is partially replaced by chlorite. Zircons from this sample yielded a dominant age component at 1648 ± 5 Ma (MSWD = 1.1, n = 39/41) with one older analysis at 1755 ± 25 Ma (Wingate et al. in press). This monzogranite also cuts Neoproterozoic metamorphic fabrics, so the dominant zircon population must represent the age of the main source component. In both instances, zircon geochronology was unable to constrain the emplacement age.
Sample GSWA 187401 is a fine- to medium-grained, equigranular tourmaline–muscovite monzogranite that was sampled by GSWA for zircon geochronology, but was not analysed. It contains tourmaline nodules with leucocratic halos (Fig. 4d). The monzogranite contains muscovite, and roughly 5% ferromagnesian minerals (biotite, tourmaline, epidote, and titanite). Recrystallised quartz, minor sericitisation, and myrmekite are indicative of minor post-magmatic deformation (Fig. 3d).
The three samples (183287, 183288 and 187401) have relatively low whole-rock Zr and Sr concentrations (Table 1). Of the three samples, 183287 shows significantly lower abundances of Th, La, Ce, and Nd.
Analytical methods
Monazite from three leucocratic granite samples (GSWA 139466, 169092 and 183287) were separated using standard mineral separation methods (Wingate and Lu 2016), and cast in 25-mm-diameter epoxy mounts which were then polished to expose the interiors of the crystals. No monazite grains were found in sample GSWA 183288. For sample GSWA 187401, polished thin sections were imaged using a scanning electron microscope (SEM) in back-scattered electron (BSE) mode fitted with an energy dispersive X-ray spectrometer (EDS) to identify suitable monazite grains for in situ SHRIMP geochronology. Monazite grains >10 μm across were drilled out in 3-mm-diameter plugs and cast in a single 25-mm epoxy mount. Monazite reference materials FRENCH, Z2908, Z2234, and PD95 were in a separate mount that was cleaned and Au-coated with the sample mounts prior to analysis. Monazite reference OX1 was located on the same mount as the unknowns (183287).
U–Th–Pb analyses of monazite were conducted using a SHRIMP II ion microprobe in the John de Laeter Centre at Curtin University, Perth. Optical and BSE images were used to guide placement of the primary ion beam during SHRIMP analysis. The SHRIMP instrument set-up and operating protocols followed the established procedure for small spot analysis of monazite (Fletcher et al. 2010). A total of six sessions were conducted to obtain the U–Th–Pb data presented here. During all sessions, an O2− primary beam focused through a 30-μm Kohler aperture to produce a spot size ~10 μm, with a beam intensity of 0.2–0.4 nA. The secondary ion system was focused through a 100-μm collector slit onto an electron multiplier to produce mass peaks with flat tops and a mass resolution (M/ΔM at 1% peak height) of >5000 in all sessions. Post-collector retardation lens was activated to reduce stray ions. Squid-2.50.11.02.03 software (Ludwig 2009) was used for initial data reduction, including correction for common Pb. Corrections for matrix effects in 206Pb/238U and 208Pb/232Th, and for instrumental mass fractionation in 207Pb/206Pb, were applied to monazite data (Fletcher et al. 2010). To adjust for analytical bias the respective 1 sigma calibration uncertainty was applied in quadrature to 238U/206Pb and 232Th/208Pb individual analyses (samples 187401 and 183287) prior to the calculation of the weighted mean. Weighted mean dates are reported with 95% confidence limits, whereas individual analyses are presented with 1σ uncertainties. Because our samples span almost a billion years, from the Paleoproterozoic to Neoproterozoic, the choice of isotopic system (207Pb/206Pb, 238U/206Pb, and 232Th/208Pb) is sample dependent (e.g., Kirkland and Wingate 2012). For Paleoproterozoic and older samples the 207Pb/206Pb analysis is typically the most precise and preferred for weighted mean calculation. However, from late Mesoproterozoic 238U/206Pb or 232Th/208Pb ratios provide the most reliable age estimates. The precisions of 238U and 232Th abundances measured by SHRIMP are typically 5–10%.
Monazite geochronology results
SHRIMP U–Th–Pb monazite data are presented in Supplementary Table 3 and are summarised in Table 2, which also includes U–Pb zircon data from previous work for comparison.
Sample 139466: biotite–muscovite granodiorite
Monazite crystals from this sample are yellow, transparent, and unzoned. They are subhedral to predominantly anhedral and range in size from 50 to >100 μm. Monazite occurs primarily as inclusions in quartz, but is also hosted in plagioclase. Thirteen analyses were carried out on eight monazite grains (Supplementary Table 3). Excluded from age calculations are a single concordant analysis that indicates high common Pb (f 206 > 1%) and another that is >10% discordant. The remaining 11 analyses are <5% discordant and indicate low common Pb. Ten of the 11 analyses indicate well-grouped, measured U and Th concentrations that vary from 350 to 500 ppm and 21,400 to 37,500 ppm, respectively, with Th/U ratios from 54 to 88. They yielded 207Pb/206Pb dates between 1868 and 1787 Ma, with a weighted mean of 1830 ± 19 Ma (MSWD = 2.8). Despite the large MSWD, rejection of additional analyses is not warranted given the uniformity of these monazites in morphology and U–Th composition. Therefore, 1830 ± 19 Ma (Fig. 5a) is considered the best estimate of the timing of monazite growth during magma crystallisation. An old outlier yielded a 207Pb/206Pb date of 1933 ± 7 Ma (1σ), and is interpreted to be a xenocryst.
Sample 169092: biotite–muscovite monzogranite
Monazite is widespread in this rock and occurs as inclusion in quartz, plagioclase, undeformed muscovite, and in biotite. Monazites crystals are >100 μm in size, yellow and transparent, and mainly subhedral and unzoned. Thorium concentrations range from 42,700 to 73,800 ppm, whereas U concentrations are bimodal: 1000–1900 ppm (four analyses) and 3500–7900 ppm (13 analyses). The Th/U ratios range from 8 to 70. Twenty-five analyses were obtained from 14 monazite grains; seven analyses that show >5% discordance are disregarded. A single analysis yielding a date of 1663 ± 2 Ma (1σ) is considered an outlier due to its significantly higher U (17,600 ppm) and lower Th (34,700 ppm) and resultant much lower Th/U (2 vs. 8–70) compared with the range seen in the main population (Supplementary Table 3). The remaining 17 analyses of 14 monazite grains yielded a weighted mean 207Pb/206Pb date of 1682 ± 3 Ma (MSWD = 0.99) (Fig. 5b), interpreted as the age of igneous crystallisation, consistent with the main age component of the initial zircon age.
Sample 187401: tourmaline–muscovite monzogranite
Monazite crystals in this sample show two different morphologies: (i) subhedral crystals 30–60 μm in size, and (ii) larger (>100 μm) anhedral crystals. The anhedral types are typically associated with secondary apatite and show retrogression coronas (e.g., Finger et al. 1998). However, the effect of post-magmatic alteration is not evident from the concordant age data, which ranges from 1058 to 970 Ma (238U/206Pb) across the monazite grains. The subhedral monazite crystals are typically hosted in plagioclase and quartz or are interstitial to the main silicate minerals (Fig. 6). The monazites from this sample have high Th contents, similar to sample 169092, ranging from 39,900 to 80,200 ppm, and with uniformly moderate U, from 1050 to 1900 ppm, consistent with other samples in this study (Supplementary Table 3). Corresponding Th/U values range from 30 to 70. Nineteen analyses were obtained from nine monazite grains (Supplementary Table 3). Six analyses are >5% discordant and/or indicate high common 206Pb (>1%) and, therefore, are not considered in the age calculation. Thirteen analyses of nine monazite grains yielded a single age component with a weighted mean 238U/206Pb date of 1006 ± 14 Ma (MSWD = 2.6) (Fig. 5c). The same group of analyses was also used to calculate a weighted mean 207Pb/206Pb date of 1018 ± 16 (MSWD = 1.5). Excluding an analysis that yielded an imprecise 232Th/208Pb date, 18 analyses give a weighted mean 232Th/208Pb age of 1047 ± 20 (MSWD = 1.5). The weighted mean dates derived from the 207Pb/206Pb and 238U/206Pb decay systems agree within uncertainty and because this sample falls within the Mesoproterozoic-Neoproterozoic boundary either the 207Pb/206Pb or 238U/206Pb could be used to represent the age of crystallisation. However, the individual 238U/206Pb analyses are more precise with uncertainties two to three times lower than for 207Pb/206Pb; therefore, the 238U/206Pb date of 1006 ± 14 Ma is taken as the most reliable estimate of the crystallisation age.
Sample 183287: biotite-muscovite–tourmaline monzogranite
Monazite crystals from this sample are subhedral to anhedral, and yellow and transparent, with an average size of 60 μm (Fig. 7). The crystals occur as inclusions in quartz and plagioclase. Compared with those from sample 187401, monazites from this sample contain significantly lower U and Th concentrations ranging from 250 to 750 ppm and from 14,800 to 40,500 ppm, respectively, but with more uniform and elevated Th/U ratios (52–61, with an average of 54). Sixteen analyses were obtained from seven monazite grains (Supplementary Table 3). For this sample, dates determined from 207Pb/206Pb or 238U/206Pb ratios are significantly more dispersed and discordant than those based on 232Th/208Pb ratios, and several analyses indicate high common 206Pb, whereas common 208Pb (f 208 in Supplementary Table 3) is, with one exception, <1%. Excluding the single analysis with high common 208Pb (>1%), and one old outlier, 14 analyses of six monazites yielded a weighted mean 232Th/208Pb date of 899 ± 10 Ma (MSWD = 1.1) (Supplementary Table 3). Weighted mean dates calculated using 207Pb/206Pb and 238U/206Pb ratios, applying the discordance and common Pb criteria as above (cut-off value at 1% for f 206 and ±5% for discordance), are 907 ± 24 (n = 6, MSWD = 1.3) and 917 ± 25 (n = 6, MSWD = 2.0), respectively. The results show that the 238U/206Pb, 207Pb/206Pb and 232Th/208Pb weighted mean ages are indistinguishable within uncertainty; however, the overall weighted mean is most precise for the 232Th/208Pb system; therefore, for this Neoproterozoic sample, we consider the 232Th/208Pb age of 899 ± 10 Ma to be the best estimate of the age of igneous crystallisation (Fig. 5d).
Discussion
Igneous crystallisation ages for some leucocratic granites are difficult to determine using U–Pb zircon geochronology because these low-temperature crustal melts commonly contain a significant proportion of inherited zircon (e.g., Crowley et al. 2008; Harrison et al. 1999; Scott et al. 2011). The samples in this study contain Zr contents <150 ppm, which according to Miller et al. (2003) is a criterion for potential zircon inheritance in a melt. Due to the historic issue of xenocrystic zircons in the leucocratic granites in the Gascoyne Province, an alternative was required to determine the crystallisation age of these granites. Monazite is a common accessory mineral in a wide variety of granitic rocks, and, in particular, is commonly found as primary monazite in peraluminous leucogranites. Magmatic monazite is distinguished from metamorphic monazite by observing the textural context of the crystals and noticing any effects of post magmatic deformation experienced by the rock. Here we show how obtaining reliable crystallization ages is important to determine the duration and extent of major granitic events and associated orogenic activity.
Assessment of magmatic monazite
Igneous monazite may become unstable during low- to medium-grade regional metamorphism (Townsend et al. 2001) resulting in secondary apatite–allanite coronas (Finger et al. 1998). The in situ monazite crystals in the tourmaline–muscovite monzogranite sample (GSWA 18740) are accompanied by secondary apatite and display some reaction coronas (Fig. 6). Although some monazite crystals in sample 187401 show secondary alteration rims, both monazite inclusions in plagioclase and interstitial monazite yielded similar ages. Although magmatic monazites typically show zoning (Bea 1996; Broska et al. 2000; Crowley et al. 2008; Montel 1993; Townsend et al. 2001), we found that only monazite in the muscovite–tourmaline granodiorite (GSWA 183287) shows zoning (Fig. 7); despite this, small-spot analysis enabled the primary monazite to be targeted and the results show consistent dates across the grains (Supplementary Table 3).
In sample 187401 the monazite crystals hosted in quartz and plagioclase suggest that monazite crystallised with the melt in contrast to inclusions in biotite that may contain inherited monazite (Rapp and Watson 1986). For the grain-mounted samples (139466, 169092 and 183287), monazite is found as inclusions in quartz and plagioclase and, more rarely, in biotite and muscovite or as an interstitial mineral. The results in Copeland et al. (1988) suggested that that monazite inheritance is common in Tertiary S-types granites. Although the original location of the analysed monazite crystals is not known, our data contain only one analysis of inherited monazite (sample 139466) across four granite samples. This confirms the suggestion by Parrish (1990) that monazite inheritance is less common than zircon in granites and, in particular, Precambrian granites.
Typically magmatic monazite shows a consistent pattern of elevated Th and moderate U concentrations. In Fig. 8, the Th and U concentrations of monazite analysed in this study are compared with monazite from other granites. The plot shows that our monazites are consistent with the Th and U signature of igneous monazites presented in other studies. Lower U and Th concentrations distinguish magmatic monazite from hydrothermal monazite and monazite grown during low-temperature metamorphism or mineralisation from the southern Pilbara margin (Rasmussen et al. 2005) and the Abra deposit in the Capricorn Orogen (Zi et al. 2015) (Fig. 8). However, monazite related to medium-grade metamorphism may yield similar Th and U concentrations to magmatic monazite (e.g., U ranges from 1100 to 6700 ppm and Th from 1200 to 104,800 ppm, Sheppard et al. 2007). Although the rocks in this study show signs of minor recrystallisation related to low-grade metamorphic overprints the absence of multiple age populations in individual samples suggest that the post-magmatic effects are minimal. Additionally, the two samples that display minor alteration of monazite (183287 and 187401), these zones could be avoided due to careful placement of the analytical spot. The leucocratic granites lack any evidence of a medium-grade metamorphic overprint (Fig. 3) and demonstrably post-date regional metamorphic fabrics. Therefore, considering the textural context of the monazites and the observed minimal post-magmatic alteration we conclude that the monazites analysed are magmatic in origin.
Implications of the monazite geochronology
Correctly dating the timing and duration of magmatism is essential both for reconstructing reliable tectonic histories in complex intracratonic orogenic belts and for addressing the thermal history of orogens. Below we examine the wider implications of our new geochronology results.
The life-span of an orogeny
Many Precambrian orogenic belts dominated by low- to medium-grade metamorphic rocks lack direct metamorphic ages (and when biostratigraphy is not available); the ages of granitic supersuites have been used as a proxy for the duration of orogenic events (e.g., the 1680–1620 Ma Durlacher Supersuite, Sheppard et al. 2005). The biotite-muscovite monzogranite (GSWA 169092) in the far north of the province yielded zircon results that were inconclusive and allowed for two possible interpretations of the igneous crystallisation age. However, our monazite geochronology provides an unambiguous igneous crystallisation age of 1682 ± 3 Ma for sample 169092, indicating that it was emplaced during the main stage of magmatism (1688–1659 Ma). There is a lack of evidence for granites younger than c. 1659 Ma in the Durlacher Supersuite in the northern Gascoyne Province suggesting that magma emplacement occurred over a shorter interval (Fig. 9) than previously thought by Sheppard et al. (2005). In turn, new data imply a higher flux of felsic magma generation during intracontinental reworking and that the reworking was of shorter duration than previously supposed. Sample GSWA 169092 and the c. 1620 Ma Discretion Granite was used to provide a younger limit to the Durlacher Supersuite and tectonothermal activity during the Mangaroon Orogeny (Sheppard et al. 2005). However, the Discretion Granite (Fig. 1c) appears to be an episode of felsic magmatism isolated in space and time, and may either belong to a discrete tectonothermal event or be related to a flare-up of intracratonic reworking far to the southeast.
A slow-burning supersuite
The Thirty-Three Supersuite (995–955 Ma) comprises ~420 km2 of leucocratic granite plutons and pegmatites restricted to the central part of the Gascoyne Province. Volumetrically, the supersuite is by far the smallest of the four supersuites in the province. Despite being emplaced in a narrow structural corridor, the timing of the Thirty-Three Supersuite has proven difficult to constrain. The initial zircon geochronology and our new monazite results are discussed below.
Zircon geochronology
Initial U–Pb zircon geochronology for one pluton of the Thirty-Three Supersuite yielded a date of 1652 ± 5 Ma, interpreted as the crystallisation age (sample KC063, a biotite-muscovite-tourmaline monzogranite; Culver 2001). At that time this age appeared to be consistent with the field relationships for two reasons: (1) tectonic fabrics in surrounding metasedimentary rocks cut by the plutons were considered to be Paleoproterozoic, and (2) the leucocratic granites do not intrude the unconformably overlying 1620–1450 Ma metasediments (Fig. 2c). However, later monazite geochronology established that the metamorphic assemblages are actually related to the 1030–950 Ma Edmundian Orogeny and that a large rare-earth-element-bearing pegmatite considered to be associated with the leucocratic granites has an igneous crystallisation age of 954 ± 12 Ma (Sample 117154, Sheppard et al. 2007). Further U–Pb zircon geochronology of the leucocratic granites yielded zircon dates that were interpreted as representing the ages of xenocrystic zircon. A biotite-muscovite–tourmaline monzogranite (183287) yielded zircon populations between 2085 and 1309 Ma (Kirkland et al. 2009), and secondly, a muscovite–tourmaline monzogranite (183288) yielded a single age population 1648 ± 5 Ma (Wingate et al. in press).
Pegmatites
Additional zircon geochronology on pegmatites (samples GSWA 185946, 185945 and 190667) in the area established igneous crystallisation ages, respectively, of 1030 ± 6, 1000 ± 8, and 939 ± 5 Ma (Wingate et al. 2011, 2010a, b) better aligned with the field relationships and existing phosphate geochronology. Furthermore, monazite from a tourmaline-rich schist which is part of a metasomatic halo around a tourmaline-bearing pegmatite dyke yielded a date of 958 ± 16 Ma (Sample GSWA 88475 Fig. 2c; Korhonen et al. 2015).
Monazite geochronology
Our monazite data from two leucocratic samples, of the Thirty-Three Supersuite, yielded Neoproterozoic ages consistent with the metamorphic fabrics in the adjacent rocks. Sample 187401, a tourmaline–muscovite monzogranite, yielded an age of 1006 ± 14 Ma representing the initial stages of magmatism. Furthermore, our results highlight that magmatism continued until c. 899 Ma (sample 183287: biotite-muscovite–tourmaline monzogranite).
The combined monazite and zircon data suggest that magmatism of the Thirty-Three Supersuite spanned about 130 million years (c. 1030–899 Ma) and that leucocratic magmatism outlasted the regional metamorphism in the same structural corridor by c. 100 million years (Fig. 10). Furthermore, given the small area (and likely small volume) of the supersuite, the geochronology implies exceptionally low magma production rates. The monazite and zircon geochronology confirm that the Thirty-Three Supersuite is much younger than c. 1620–1465 Ma metasedimentary rocks of the Edmund Group, despite the absence of pegmatite and leucocratic granite in the Edmund Group in the Ti Tree Shear Zone immediately to the north. Therefore, reworking and magmatism must have been funnelled into a narrow structural corridor south of the shear zone from c. 1030 Ma onwards. This work further highlights the problem of attempting to correlate events across major structures within a complex orogen.
An isolated granite
Sample GSWA 139466 was taken from a biotite–muscovite granodiorite pluton that intruded a crustal-scale shear zone (the Errabiddy Shear Zone). The existing geochronological constraints allowed the pluton to have been emplaced at any time over a c. 1000 million-year interval. Our U–Th–Pb monazite geochronology yielded a date of 1830 ± 19 Ma, interpreted as the age of igneous crystallisation and is consistent with field relationships that show the Erong Granite cutting deformation fabrics formed during the 2005–1950 Ma Glenburgh Orogeny. The new monazite data indicate that the pluton is part of the voluminous Moorarie Supersuite associated with reworking during the Paleoproterozoic Capricorn Orogeny. This study shows that even for an area shaped by multiple episodes of reworking and reactivation monazite is a powerful geochronometer for constructing a more reliable tectonic and magmatic history of a major shear zone.
Conclusions
Our study has highlighted the benefits of using U–Th–Pb monazite geochronology for dating peraluminous leucocratic, low-temperature granites. This study has demonstrated that U–Th–Pb monazite geochronology is preferable for determining the crystallisation ages of Precambrian low-temperature, peraluminous leucocratic granites for the following reasons: (1) new monazite growth occurs readily at a range of P–T conditions remaining robust over time with a closure temperature of 720–750 °C (Copeland et al. 1988); (2) monazite contains high U and Th and incorporates minor common Pb (Townsend et al. 2001); (3) monazite, unlike zircon, generally does not contain inherited cores and is immune from radiogenic Pb loss at low temperatures (Grosse et al. 2009); (4) occurrences of inherited monazite, although common in Tertiary S-type granites (Copeland et al. 1988), are uncommon in Precambrian rocks (Parrish 1990); and (5) magmatic monazite is one of the most common accessory mineral in granites and is abundant in peraluminous compositions (Bea 1996; Montel 1993; Rapp and Watson 1986). Our study has also resolved the duration of two generations of magmatism: in one instance emplacement occurred over a much shorter time interval (~30 million years) implying a higher rate of magma production than previously thought, and second, whereas purely leucocratic granites and pegmatites of the Thirty-Three Supersuite span a remarkably long duration of c. 130 million years implying a very low rate of magma generation. Finally, the use of monazite geochronology was able to narrow the possible window of magmatism to a discrete reworking event significantly reducing the time span previously thought.
Change history
16 August 2017
An erratum to this article has been published.
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Acknowledgements
We thank Simon Johnson and Ian Fitzsimons for their critical and insightful reviews. Zedenka Martelli kindly provided assistance with monazite identification and picking. This manuscript was significantly improved by valuable comments received from an anonymous reviewer. U–Th–Pb measurements were conducted using the SHRIMP ion microprobes at the John de Laeter Centre at Curtin University. Michael Wingate publishes with permission of the Director of the Geological Survey of Western Australia. Australian Research Council Linkage Grant LP130100922 and the Geological Survey of Western Australia (through the Exploration Incentive Scheme) funded this PhD Project.
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Communicated by Franck Poitrasson.
The original version of this article was revised: Figures 1 and 2 were incorrect and they have been corrected.
An erratum to this article is available at https://doi.org/10.1007/s00410-017-1396-3.
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Table 3 Supplementary data showing SHRIMP U–Th–Pb monazite data for samples GSWA 139466, 169092, 187401 and 183287. Supplementary material 1 (XLS 63 kb)
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Piechocka, A.M., Gregory, C.J., Zi, JW. et al. Monazite trumps zircon: applying SHRIMP U–Pb geochronology to systematically evaluate emplacement ages of leucocratic, low-temperature granites in a complex Precambrian orogen. Contrib Mineral Petrol 172, 63 (2017). https://doi.org/10.1007/s00410-017-1386-5
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DOI: https://doi.org/10.1007/s00410-017-1386-5