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Contribution of long-term hydrothermal experiments for understanding the smectite-to-chlorite conversion in geological environments

  • Régine Mosser-RuckEmail author
  • Isabella Pignatelli
  • Franck Bourdelle
  • Mustapha Abdelmoula
  • Odile Barres
  • Damien Guillaume
  • Delphine Charpentier
  • Davy Rousset
  • Michel Cathelineau
  • Nicolas Michau
Original Paper

Abstract

The smectite-to-chlorite conversion is investigated through long-duration experiments (up to 9 years) conducted at 300 °C. The starting products were the Wyoming bentonite MX80 (79 % smectite), metallic iron and magnetite in contact with a Na–Ca chloride solution. The predominant minerals in the run products were an iron-rich chlorite (chamosite like) and interstratified clays interpreted to be chlorite/smectite and/or corrensite/smectite, accompanied by euhedral crystals of quartz, albite and zeolite. The formation of pure corrensite was not observed in the long-duration experiments. The conversion of smectite into chlorite over time appears to take place in several steps and through several successive mechanisms: a solid-state transformation, significant dissolution of the smectite and direct precipitation from the solution, which is over-saturated with respect to chlorite, allowing the formation of a chamosite-like mineral. The reaction mechanisms are confirmed by X-ray patterns and data obtained on the experimental solutions (pH, contents of Si, Mg, Na and Ca). Because of the availability of some nutrients in the solution, total dissolution of the starting smectite does not lead to 100 % crystallization of chlorite but to a mixture of two dominant clays: chamosite and interstratified chlorite/smectite and/or corrensite/smectite poor in smectite. The role of Fe/(Fe + Mg) in the experimental medium is highlighted by chemical data obtained on newly formed clay particles alongside previously published data. The newly formed iron-rich chlorite has the same composition as that predicted by the geothermometer for diagenetic to low-grade metamorphic conditions, and the quartz + Fe-chlorite + albite experimental assemblage in the 9-year experiment is close to that fixed by water–rock equilibrium.

Keywords

Chlorite Corrensite Hydrothermal experiment Iron–clay interaction Hydrothermal metamorphism Diagenetic system 

Notes

Acknowledgments

We are grateful to the Paul Scherrer Institute, Swiss Light Source, and especially to Benjamin Watts. This research was financially supported by ANDRA – Agence Nationale pour la gestion des Dechets RadioActifs (the French National Agency for the Management of Radioactive Waste). Alice Williams is greatly thanked for proof reading the paper and her corrections of English. The authors wish also to thank O. Müntener, editor in chief, and the anonymous reviewers for comments and suggestions that greatly improved the paper.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Régine Mosser-Ruck
    • 1
    Email author
  • Isabella Pignatelli
    • 2
  • Franck Bourdelle
    • 3
  • Mustapha Abdelmoula
    • 4
  • Odile Barres
    • 1
  • Damien Guillaume
    • 5
  • Delphine Charpentier
    • 6
  • Davy Rousset
    • 7
  • Michel Cathelineau
    • 1
  • Nicolas Michau
    • 8
  1. 1.Faculté des sciences et technologiesGeoRessources UMR-CNRS 7359, Université de LorraineVandœuvre-lès-NancyFrance
  2. 2.CRPG Université de Lorraine, CNRS/INSU UMR 7358Vandœuvre-lès-NancyFrance
  3. 3.Laboratoire Génie Civil et géo-Environnement (LGCgE)Université Lille 1Villeneuve-d’Ascq cedexFrance
  4. 4.Laboratoire de Chimie Physique et Microbiologie pour l’Environnement (LCPME) UMR-CNRS 7564Université de LorraineVillers-lès-NancyFrance
  5. 5.LMV, UMR 6524, Faculté des Sciences et TechniquesSaint Etienne Cedex 02France
  6. 6.Chrono-Environnement UMR-CNRS 6249Université de Franche-ComtéBesançon CedexFrance
  7. 7.Institut National de Recherche et de Sécurité (I.N.R.S)Vandœuvre-lès-NancyFrance
  8. 8.Agence nationale pour la gestion des déchets radioactifs (ANDRA), Parc de la Croix BlancheChâtenay-Malabry CedexFrance

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