Contributions to Mineralogy and Petrology

, Volume 163, Issue 4, pp 591–609 | Cite as

Experimental determination of F and Cl partitioning between lherzolite and basaltic melt

  • Célia Dalou
  • Kenneth T. Koga
  • Nobumichi Shimizu
  • Julien Boulon
  • Jean-Luc Devidal
Original Paper

Abstract

We experimentally determined F and Cl partition coefficients together with that of 19 trace elements (including REE, U-Th, HFSE and LILE) between basaltic melt and lherzolite minerals: olivine, orthopyroxene, clinopyroxene, plagioclase and garnet. Under conditions from 8 to 25 kbars and from 1,265 to 1,430°C, compatibilities of F and Cl are globally ordered as DCpx/melt > DOpx/melt > DGrt/melt > DOl/melt > DPlag/melt, and DFmineral/melt is larger than DClmineral/melt. Four other major results were brought to light. (1) Chlorine partition coefficients positively correlate with the jadeite component in orthopyroxene, and increase of the CaTs component promotes Cl incorporation in clinopyroxene. (2) Variations of fluorine partition coefficients correlate strongly with melt viscosity. (3) F and Cl partition coefficients correlate with the Young’s modulus (E0) of pyroxene octahedral sites (M sites) and with Raman vibrational modes of pyroxenes. This demonstrates a fundamental interaction between the M site of pyroxenes and the incorporation of F and Cl. (4) We also determined the parameters of the lattice-strain model applied to 3+ cation trace elements for the two M sites in orthopyroxene and clinopyroxene: D0M1, D0M2, r0M1r0M2E0M1 and E0M2.

Keywords

Fluorine Chlorine Partition coefficients Lherzolite minerals Basaltic melt Substitution Lattice-strain model 

Supplementary material

410_2011_688_MOESM1_ESM.pdf (333 kb)
PDF (332 KB)

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Copyright information

© Springer-Verlag 2011

Authors and Affiliations

  • Célia Dalou
    • 1
    • 2
    • 3
  • Kenneth T. Koga
    • 1
    • 2
    • 3
  • Nobumichi Shimizu
    • 4
  • Julien Boulon
    • 5
  • Jean-Luc Devidal
    • 1
    • 2
    • 3
  1. 1.Laboratoire Magmas et VolcansClermont Université, Université Blaise PascalClermont-FerrandFrance
  2. 2.CNRS, UMR 6524, LMVClermont-FerrandFrance
  3. 3.IRD, R 163, LMVClermont-FerrandFrance
  4. 4.Woods Hole Oceanographic InstitutionWoods HoleUSA
  5. 5.Laboratoire de Météorologie PhysiqueClermont Université, Université Blaise PascalClermont-FerrandFrance

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