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Contributions to Mineralogy and Petrology

, Volume 161, Issue 5, pp 777–789 | Cite as

Helium irradiation study on zircon

  • Lutz NasdalaEmail author
  • Dieter Grambole
  • Jens Götze
  • Ulf Kempe
  • Tamás Váczi
Original Paper

Abstract

Synthetic ZrSiO4 and (mildly to strongly radiation-damaged) natural zircon samples were irradiated with 8.8 MeV 4He2+ ions (fluences in the range 1 × 1013–5 × 1016 ions/cm2). For comparison, an additional irradiation experiment was done with 30 MeV 16O6+ ions (fluence 1 × 1015 ions/cm2). The light-ion irradiation resulted in the generation of new (synthetic ZrSiO4) or additional (mildly to strongly metamict natural samples) damage. The maximum extent of the damage is observed in a shallow depth range approximately 32–33 μm (8.8 MeV He) and ~12 μm (30 MeV O) below the sample surface, i.e. near the end of the ion trajectories. These depth values, and the observed damage distribution, correspond well to defect distribution patterns as predicted by Monte Carlo simulations. The irradiation damage is recognised from the notable broadening of Raman-active vibrational modes, lowered interference colours (i.e. decreased birefringence), and changes in the optical activity (i.e. luminescence emission). At very low damage levels, a broad-band yellow emission centre is generated whereas at elevated damage levels, this centre is suppressed and samples experience a general decrease in their emission intensity. Most remarkably, there is no indication of notable structural recovery in pre-damaged natural zircon as induced by the light-ion irradiation, which questions the relevance of alpha-assisted annealing of radiation damage in natural zircon.

Keywords

Zircon Ion irradiation Radiation damage Raman spectroscopy Luminescence 

Notes

Acknowledgments

Samples investigated in this study were kindly made available by J.M. Hanchar (synthetic ZrSiO4), W. Hofmeister (M144, M146, N17), and A.K. Kennedy (G168). Thanks are due to A. Wagner for the excellent sample preparation. We are indebted to W. Hofmeister and T. Häger for the opportunity to use the confocal Raman spectrometer of the Institute for Gemstone Research, Mainz, Germany. Constructive comments of two anonymous experts are gratefully acknowledged. This research was supported financially by the European Commission through contract no. MEXC-CT-2005-024878 and Research Infrastructures Transnational Access (RITA) grant no. 025646, and the Austrian Science Fund (FWF), grant P20028-N10.

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Copyright information

© Springer-Verlag 2010

Authors and Affiliations

  • Lutz Nasdala
    • 1
    Email author
  • Dieter Grambole
    • 3
  • Jens Götze
    • 4
  • Ulf Kempe
    • 4
  • Tamás Váczi
    • 1
    • 2
  1. 1.Institut für Mineralogie und KristallographieUniversität WienViennaAustria
  2. 2.Institute for NanotechnologyBay Zoltán Foundation for Applied ResearchMiskolcHungary
  3. 3.Institut für Ionenstrahlphysik und MaterialforschungDresdenGermany
  4. 4.Institut für MineralogieTU Bergakademie FreibergFreibergGermany

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