Contributions to Mineralogy and Petrology

, Volume 159, Issue 5, pp 731–751 | Cite as

Geochemical characteristics and Sr–Nd–Hf isotope compositions of mantle xenoliths and host basalts from Assab, Eritrea: implications for the composition and thermal structure of the lithosphere beneath the Afar Depression

  • Mengist Teklay
  • Erik E. Scherer
  • Klaus Mezger
  • Leonid Danyushevsky
Open Access
Original Paper

Abstract

The Afar Depression offers a rare opportunity to study the geodynamic evolution of a rift system from continental rifting to sea floor spreading. This study presents geochemical data for crustal and mantle xenoliths and their alkaline host basalts from the region. The basalts have enriched REE patterns, OIB-like trace element characteristics, and a limited range in isotopic composition (87Sr/86Sr = 0.70336–0.70356, εNd = +6.6 to +7.0, and εHf = +10.0 to +10.7). In terms of trace elements and Sr–Nd isotopes, they are similar to basalts from the Hanish and Zubair islands in the southern Red Sea and are thus interpreted to be melts from the Afar mantle. The gabbroic crustal xenoliths vary widely in isotope composition (87Sr/86Sr = 0.70437–0.70791, εNd = −8.1 to +2.5, and εHf = −10.5 to +4.9), and their trace element characteristics match those of Neoproterozoic rocks from the Arabian–Nubian Shield and modern arc rocks, suggesting that the lower crust beneath the Afar Depression contains Neoproterozoic mafic igneous rocks. Ultramafic mantle xenoliths from Assab contain primary assemblages of fresh ol + opx + cpx + sp ± pl, with no alteration or hydrous minerals. They equilibrated at 870–1,040°C and follow a steep geothermal gradient consistent with the tectonic environment of the Afar Depression. The systematic variations in major and trace elements among the Assab mantle xenoliths together with their isotopic compositions suggest that these rocks are not mantle residues but rather series of layered cumulate sills that crystallized from a relatively enriched picritic melt related to the Afar plume that was emplaced before the eruption of the host basalts.

Keywords

Afar Depression Xenoliths Cumulates Rifting Sr–Nd–Hf isotopes 

Introduction

Mantle xenoliths, together with orogenic peridotites, represent the only direct samples of the mantle. Due to their rapid eruption, these rocks usually freeze in the mineralogical and chemical signatures that they acquired during crystallization or re-equilibration at their depth of origin. Hence, they provide crucial evidence of the nature of the lithospheric mantle at the time of their eruption (e.g., Pearson et al. 2004 and references therein). Mantle xenoliths from continental rift areas, in addition to sampling very thin lithosphere, can constrain the local geothermal gradient and the extent of interaction between asthenosphere and lithosphere. Furthermore, they can supply direct compositional information on deep-seated sources and may constrain the metasomatic history and PT conditions of melting, which are important parameters associated with the rifting process. A promising area for the study of continental rifting processes and the transition between continental rifting and sea floor spreading is the Afar volcanic province, because it is actively undergoing continental break-up.

The Afar volcanic province is the second youngest large igneous province worldwide and its magmatic activity coincided with the onset of rifting of Arabia from Africa, a process that continues along the Red Sea and Gulf of Aden axes, and in the Afar Depression. The Afar Depression, whose tectonic and magmatic activity is attributed to a deep-seated mantle plume that impinged upon the lithosphere at 30 Ma, represents the advanced transitional stage between continental rifting and sea floor spreading, and constitutes one of the largest currently active continental igneous provinces (e.g., Schilling et al. 1992; Hoffman et al. 1997). Hence, the Afar Depression offers the unique opportunity for studying the geodynamic evolution of a major rift system from continental break-up to sea floor spreading.

New geochemical and Sr–Nd–Hf isotope data for host basalts, crustal xenoliths, and mineral separates from mantle xenoliths from the Assab area of the Afar Depression document and constrain the chemical and isotopic signature of the lithosphere beneath Afar and the potential relationship between the Assab rocks and mantle xenoliths from Ethiopia, Yemen, Saudi Arabia, Egypt, and Jordan. The data are also used to evaluate the potential contributions of the lithospheric mantle as a source of flood and intraplate volcanism and to unravel the petrogenesis of the Assab mantle xenoliths, addressing the question of whether they represent cumulates or residues.

Geologic setting

The Afar Depression is the triple-rift junction of the Red Sea, Gulf of Aden and East African rift systems (Fig. 1) and has been subjected to rapid crustal spreading as evidenced by numerous NNW–SSE fissures (Fig. 1). With the exception of the Danakil block in Eritrea and the Ali Sabieh block in Djibouti, it is floored by dominantly basaltic volcanic rocks that are related to rifting (Pilger and Rösler 1975). Basement rocks, Neoproterozoic metamorphic rocks of the Arabian–Nubian Shield, and Paleozoic–Mesozoic sedimentary strata crop out only in the Danakil and Ali Sabieh blocks. With the exception of these older rocks, the surface of the Afar region consists only of volcanic rocks, Upper Tertiary continental and lacustrine sediments, and Quaternary marine sediments (Barberi and Varet 1977). The oldest volcanic rocks (>4 Ma) crop out mainly in the Ali Sabieh block and south of the Danakil block (Barberi and Varet 1977; Audin et al. 2004). These are overlain by the Afar stratoid series (<4 Ma; Civetta et al. 1974; Audin et al. 2004 and references therein), which is exposed throughout the depression. Younger fissural basalts overlie the Afar stratoid series along the axial ranges (<1 Ma; Manighetti et al. 2001) and at the edges of the depression along the transverse tectonic trends (Fig. 1). The tectonic structures and volcanic activity in the axial range are manifestations of a propagating rift that extends from the Red Sea to the East African rift (Barberi and Varet 1977).
Fig. 1

a Distribution of Cenozoic volcanism in part of the Afar volcanic province (modified after Pik et al. 1998; Bertrand et al. 2003; Ukstins Peate et al. 2005) and b schematic structural map of Afar Depression (modified after Barberi and Varet 1977; Manighetti et al. 1998) showing study area (star). EA Erta’Ale, TA Tat’Ali, AL Alayta, MH Manda Hararo, MI Manda Inakir, AG Asal-Ghoubbet, Tad Gulf of Tadjoura, MER Main Ethiopian Rift

Transverse activity (<1 Ma) was most intense south of the Danakil block (Civetta et al. 1975) including the Assab range volcanic area, located between the central Afar Depression and the Red Sea (Fig. 1). These are recent volcanic rocks located along E–W fracture systems that are transversal relative to the main NNW trend of the depression. Civetta et al. (1974) have reported a 0.6 Ma K–Ar age and a 0.285 Ma 230Th age for the Assab transverse volcanic range rocks. The composition of these lavas ranges from ankaramitic to hawaiitic basalt (De Fino et al. 1973). Thus, in contrast to the axial range of central Afar, which is characterized by intense NNW–SSE tectonic activity and a less alkaline (transitional) volcanism, the less faulted Assab area is characterized by transverse E–W tectonics and by markedly more alkaline volcanism. Civetta et al. (1974, 1975) have suggested that the marginal alkalic basalts erupted through a thin continental-type crust, whereas the axial volcanism developed in an area that had already become a mid-oceanic ridge setting. Some of the Assab lava flows and spatter cones contain mafic and ultramafic nodules (De Fino et al. 1973). These range from harzburgite and spinel lherzolite to plagioclase peridotite, pyroxenite, and gabbro (Cimmino et al. 1976; Piccardo and Ottonello 1978; Ottonello et al. 1978, 1980). For this study, host basalts and xenoliths were collected from about 5 km NW of the port city of Assab at Mt. El Taghi (Fig. 1). The xenoliths have diameters from ~3 to 9 cm with an average of about 6 cm and all are fresh with no visible alteration in hand specimens or thin sections.

Analytical procedures

All samples were cut into slabs, trimmed to remove weathered surfaces, and then crushed gently in many stages using a steel mortar and pestle to separate mineral grains from each other while breaking them as little as possible. Whole rock powders of the host basalts and crustal xenoliths were produced in an agate mill. Grains of clinopyroxene, orthopyroxene, olivine, and plagioclase were separated by sieving and hand-picking under a binocular microscope. Before dissolution, clean, visibly inclusion-free mineral grains were washed with cold HCl in an ultrasonic bath, and then repeatedly rinsed with deionized water.

Major and minor elements in the host basalts and crustal xenoliths were analyzed at the University of Bonn by XRF. Typical precisions on major element concentrations are better than 5% and better than 10% for minor and trace elements. Loss on ignition (LOI) values were less than 1.1 wt%. Many samples, however, gained mass during ignition via oxidation of FeO to Fe2O3 and, therefore, have negative LOI values (Table 1). This occurs if the mass increase as a result of the oxidation of Fe is greater than the mass of OH lost on ignition. Negative LOI values are thus consistent with the absence of OH-bearing alteration minerals in the petrographically fresh host basalts and crustal xenoliths. Furthermore, there is no correlation between LOI and the concentrations of mobile elements such as Rb and K in either the host basalts or crustal xenoliths, suggesting that alteration processes have not affected their chemistry.
Table 1

Major oxides and trace element abundances of host basalts and crustal xenoliths as determined by XRF

 

Host basalt

Crustal xenolith

Sample no.:

AE01B/06

AE04B/06

AE05B/06

AE06B/06

AE07B/06

AE08B/06a

AE10B/06a

AE12B/06a

AE01A/06

AE01C/06

AE01D/06

AE02/06

AE04/06

Rock type:

Basalt

Basalt

Basalt

Basalt

Basalt

Basalt

Basalt

Basalt

Gabbro

Gabbro

Gabbro

Norite

Norite

Lat. N:

13°02′00″

13°01′53″

13°01′48″

13°01′46″

13°01′49″

13°02′03″

13°02′03″

13°02′03″

13°02′00″

13°02′00″

13°02′00″

13°01′58″

13°01′53″

Long. E:

42°39′37″

42°39′43″

42°39′41″

42°39′37″

42°39′29″

42°39′40″

42°39′40″

42°39′40″

42°39′37″

42°39′37″

42°39′37″

42°39′42″

42°39′43″

Major oxides (wt%)

 SiO2

46.1

46.0

46.1

46.8

49.0

48.2

48.2

47.0

48.9

49.9

47.9

52.2

49.1

 TiO2

3.10

3.17

3.02

3.01

2.02

2.56

2.55

2.50

0.28

0.53

0.27

1.54

1.15

 Al2O3

15.5

15.7

15.3

15.7

15.5

15.6

15.5

15.0

16.6

16.9

20.1

17.5

18.9

 Fe2O3b

12.6

12.4

12.7

12.5

10.4

11.3

11.1

11.3

6.69

7.50

6.12

11.0

12.0

 MnO

0.19

0.19

0.18

0.18

0.18

0.19

0.19

0.19

0.11

0.13

0.10

0.19

0.17

 MgO

7.75

7.62

8.08

8.07

6.89

7.48

7.41

8.14

11.5

9.82

10.6

6.65

4.61

 CaO

9.92

9.99

9.98

9.62

9.66

9.60

9.71

9.97

14.0

13.6

13.4

7.18

9.48

 Na2O

3.29

3.16

3.12

3.23

3.51

3.27

3.21

2.90

1.66

1.95

2.06

3.59

3.98

 K2O

1.09

1.07

0.99

1.05

1.67

1.38

1.37

1.21

0.06

0.11

0.08

0.33

0.20

 P2O5

0.612

0.608

0.537

0.530

0.601

0.519

0.525

0.500

0.008

0.031

0.014

0.262

0.139

 SO3

0.236

0.086

0.584

0.083

0.012

0.034

0.024

0.054

0.012

0.012

0.012

0.160

0.014

 LOI

−0.33

−0.04

0.01

−0.43

0.55

−0.09

0.05

0.84

−0.18

−0.07

−0.25

−0.24

1.07

 Total

100.2

100.2

100.8

100.6

100.2

100.3

100.1

99.9

99.7

100.5

100.5

100.6

100.9

Trace elements (ppm)

 Sc

27

21

21

25

19

14

33

17

33

33

18

22

26

 V

276

278

289

274

183

255

249

266

124

169

81

249

279

 Cr

200

176

216

220

308

309

316

336

717

537

398

126

55

 Co

42

47

43

40

27

47

36

48

44

40

39

31

32

 Ni

120

111

140

135

118

209

189

234

125

110

159

35

21

 Cu

54

51

63

74

40

116

108

113

3

7

17

23

23

 Zn

96

91

91

101

80

85

77

86

37

47

31

115

78

 Ga

23

24

21

21

17

12

20

17

15

15

10

21

26

 Rb

21

22

18

21

40

32

36

29

2

4

2

2

2

 Sr

545

575

527

536

606

601

612

593

391

414

445

749

768

 Y

36

29

30

31

24

23

24

24

11

11

7

18

10

 Zr

224

229

212

226

283

273

276

275

19

34

21

83

43

 Nb

38

42

39

34

55

56

57

50

2

2

3

15

2

 Ba

316

312

288

328

459

413

423

404

55

115

49

516

168

aCarapace

bTotal iron as Fe2O3

For the host basalts and crustal xenoliths, the concentrations of the REE and additional trace elements were determined by inductively coupled plasma mass spectrometry (ICPMS) at ACTlabs, Canada. The analytical data are presented in Table 2 together with the mean values of the international standard BIR-1 obtained during the course of this study.
Table 2

Trace element abundances of host basalts and crustal xenoliths as determined by ICPMS

 

Sample no.

AE01B/06

AE04B/06

AE05B/06

AE06B/06

AE07B/06

AE08B/06a

AE10B/06a

AE12B/06a

AE01A/06

AE01C/06

AE01D/06

AE02/06

AE04/06

AE06B/06b

AE10B/06b

AE10B/06b

BIR-1 measured

BIR-1 recommended

V

271

254

257

254

161

212

208

207

122

161

86

228

254

250

214

202

320

313

Cr

150

140

170

170

210

220

220

250

640

440

330

100

40

170

230

210

390

380

Co

38

37

38

37

26

32

31

34

40

33

36

22

25

36

32

30

51

51

Ni

120

110

130

120

90

160

140

180

120

90

140

30

30

110

150

140

170

170

Cu

40

40

40

50

40

90

90

90

20

20

BD

20

20

60

90

90

120

130

Zn

90

90

90

100

70

70

70

70

40

50

40

100

70

90

70

70

70

70

Ga

19

19

19

19

15

16

16

16

11

13

12

20

19

19

17

16

16

16

Rb

20

20

18

19

34

30

28

26

BD

BD

BD

BD

BD

19

29

28

BD

0.3

Sr

499

531

497

507

536

549

547

539

400

394

426

689

690

504

560

534

109

108

Y

31.9

31.8

30.7

31.2

24.9

27.7

27.4

27.0

4.50

8.90

4.10

14.9

6.40

31.3

28.1

26.8

16.2

16.0

Zr

202

205

190

204

242

250

243

240

7

21

9

58

20

203

249

236

14

16

Nb

35.2

37.6

32.7

34.7

46.8

48.6

47.7

46.9

BD

1.60

0.40

8.30

1.70

34.8

48.9

46.5

0.50

0.60

Cs

0.2

0.2

0.2

0.2

0.2

0.4

0.3

0.4

BD

BD

BD

BD

BD

0.2

0.3

0.3

BD

0.005

Ba

328

370

300

328

519

435

441

423

71

103

64

522

209

329

453

429

7

7

La

32.8

32.7

29.4

30.8

45.7

43.3

44.0

42.2

1.23

3.13

1.81

23.0

4.80

31.4

44.4

43.5

0.78

0.62

Ce

70.8

70.5

63.9

66.5

90.9

89.3

89.8

87.6

3.32

7.24

3.86

41.8

9.20

67.5

90.8

88.7

2.08

1.95

Pr

8.69

8.82

8.05

8.31

10.5

10.6

10.5

10.4

0.43

1.06

0.53

4.80

1.13

8.42

10.6

10.5

0.40

0.38

Nd

38.4

38.3

34.8

35.7

40.6

42.7

42.7

42.3

2.16

5.33

2.63

19.5

4.90

36.0

43.2

42.2

2.53

2.50

Sm

8.43

8.38

7.85

7.93

7.46

8.00

8.19

8.15

0.67

1.49

0.72

3.47

1.09

7.95

8.24

8.14

1.14

1.10

Eu

2.94

2.92

2.77

2.78

2.47

2.68

2.72

2.72

0.439

0.751

0.471

2.72

1.12

2.77

2.75

2.69

0.563

0.540

Gd

8.26

8.10

7.91

7.83

6.49

7.13

7.25

7.34

0.87

1.68

0.77

3.16

1.18

7.86

7.36

7.14

1.86

1.85

Tb

1.31

1.29

1.25

1.25

0.97

1.09

1.10

1.11

0.14

0.29

0.13

0.48

0.20

1.23

1.11

1.10

0.42

0.36

Dy

7.08

6.89

6.86

6.77

5.27

5.85

5.92

5.93

0.86

1.76

0.82

2.78

1.24

6.74

5.97

5.86

2.73

2.50

Ho

1.25

1.22

1.22

1.20

0.98

1.08

1.09

1.09

0.17

0.35

0.16

0.57

0.26

1.21

1.09

1.09

0.57

0.57

Er

3.36

3.32

3.32

3.28

2.70

2.96

3.01

3.02

0.50

1.00

0.46

1.72

0.79

3.29

3.00

3.02

1.78

1.70

Tm

0.458

0.444

0.449

0.450

0.375

0.407

0.418

0.411

0.069

0.140

0.063

0.262

0.121

0.452

0.420

0.417

0.275

0.260

Yb

2.76

2.68

2.69

2.72

2.32

2.47

2.53

2.50

0.40

0.85

0.39

1.80

0.83

2.74

2.58

2.47

1.73

1.65

Lu

0.387

0.381

0.386

0.386

0.352

0.363

0.374

0.370

0.056

0.126

0.059

0.289

0.134

0.392

0.370

0.377

0.256

0.260

Hf

5.2

5.3

5.1

5.3

6.0

6.1

6.1

6.1

0.30

0.80

0.30

1.6

0.60

5.3

6.2

6.1

0.60

0.60

Ta

2.87

2.99

2.62

2.73

3.88

3.82

3.88

3.82

0.01

0.08

0.02

0.49

0.11

2.72

3.93

3.84

0.03

0.04

Pb

BD

BD

BD

7

BD

BD

BD

BD

BD

BD

BD

30

BD

7

BD

BD

BD

3

Th

2.61

2.67

2.46

2.62

4.41

4.06

4.10

4.10

0.05

0.12

BD

0.23

0.08

2.61

4.15

4.05

0.07

0.03

U

0.88

0.84

0.81

0.87

0.90

1.20

1.20

1.19

0.05

0.07

0.06

0.16

0.10

0.86

1.21

1.19

0.02

0.01

BD below detection limit

aCarapace

bDuplicate analysis

Major and minor element concentrations in mineral separates were measured using the JEOL JXA8900 electron microprobe at the University of Münster. All minerals were analyzed at 15 kV and 15 nA using a focused beam. Counting times for all elements were 10 s for the peaks and 5 s for the backgrounds except for Na and K, which were counted for 5 and 2.5 s, respectively. All mineral probe analyses presented are averages of three to six individual spots. The analytical data for the minerals are presented in Table 4a (electronic supplementary material).

Trace element concentrations in clinopyroxene, orthopyroxene, and olivine were measured by laser ablation (LA) ICPMS at CODES, University of Tasmania, using a New-Wave Research UP193 Nd-YAG (193 nm) laser coupled to an Agilent 7500cs quadrupole mass spectrometer. Analyses were performed in a He atmosphere by ablating 100 μm diameter spots at a rate of 10 shots/s using a laser power of ~3.5 J/cm2. The mass spectrometer was tuned to enhance the sensitivity for mid- to high-mass isotopes (80–240 amu), and to minimize molecular oxide species production by ablating an NIST612 glass. The low level of molecular oxide production (e.g., 232Th16O+/232Th+ < 0.2%) obviates the need to correct any of the analyte signal intensities for interfering species. Each analysis involves sequential peak hopping through the mass spectrum, with a dwell time of 20 ms on each mass measured. The analysis time for each sample was 90 s, comprising a 30 s background measurement and 60 s analysis with the laser on. Data reduction followed standard methods (Longerich et al. 1996) using the NIST612 glass as a primary reference material and 43Ca (Ca analyzed by electron microprobe) as the internal standard. The USGS BCR-2 glass was used as a secondary reference material and measured before and after the mineral measurements. The trace element data for minerals are presented in Table 4b (electronic supplementary material) together with mean values of the international standards BCR-2 obtained during the course of this study. All analyses were normalized to the recommended values of BCR-2.

The concentrations of Sm, Nd, Rb, and Sr as well as the isotope compositions of Nd and Sr were determined by isotope dilution TIMS at the Institut für Mineralogie, University of Münster. Neodymium and Sr measurements were normalized to 146Nd/144Nd = 0.7219 and 86Sr/88Sr = 0.1194, respectively, using the exponential law. La Jolla Nd and NBS-987 Sr standards measured during the course of this study yielded mean values of 0.511861 ± 17 (2SE, n = 12) and 0.710244 ± 37 (2SE, n = 9), for 143Nd/144Nd and 87Sr/86Sr, respectively. Lutetium and Hf concentrations as well as the isotopic composition of Hf were determined by MC-ICPMS at the Institut für Mineralogie, University of Münster. Hafnium isotopic ratios were normalized to 179Hf/177Hf = 0.7325 using the exponential law and are reported relative to 176Hf/177Hf = 0.282163 for the JMC-475 standard. The 2SD external reproducibility of 176Hf/177Hf for unknowns was estimated from the relationship between the external (2SD) reproducibility and internal run statistics (2SE) of standards analyzed at a variety of signal intensities (see Bizzarro et al. 2003). This resulted in the relationship 2SD (external) = ~2.3 × 2SE (internal). For isotope dilution measurements of Lu concentrations, the 176Lu/175Lu values were corrected for 176Yb interference and mass bias using the naturally occurring Yb in the samples (Blichert-Toft et al. 2002).

All isotope data for host basalts, crustal xenoliths, and mineral separates of mantle xenoliths are presented in Table 3. Epsilon parameters (εNd and εHf) were calculated relative to the CHUR parameters of Bouvier et al. (2008, i.e., 143Nd/144Nd = 0.512630 and 176Hf/177Hf = 0.282785).
Table 3

Sr–Nd–Hf isotope data for host basalts, crustal and mantle xenoliths

Sample no.

Sm (ppm)

Nd (ppm)

147Sm/144Nd

143Nd/144Nd

εNda

Rb (ppm)

Sr (ppm)

87Rb/86Sr

87Sr/86Sr

Lu (ppm)

Hf (ppm)

176Lu/177Hf

176Hf/177Hf

εHfa

Host basalt

 AE01B/06

   

0.512987(5)

7.0

   

0.703358(7)

   

0.283080(4)

10.4

 AE04B/06

   

0.512985(3)

6.9

   

0.703431(7)

   

0.283079(4)

10.4

 AE05B/06

   

0.512986(4)

6.9

   

0.703492(9)

   

0.283087(3)

10.7

 AE06B/06

   

0.512978(2)

6.8

   

0.703382(7)

   

0.283083(4)

10.5

 AE07B/06

   

0.512983(4)

6.9

   

0.703517(9)

   

0.283087(4)

10.7

 AE08B/06

   

0.512974(3)

6.7

   

0.703411(6)

   

0.283069(3)

10.0

 AE10B/06

   

0.512977(6)

6.8

   

0.703489(10)

   

0.283076(3)

10.3

 AE12B/06

   

0.512967(2)

6.6

   

0.703563(7)

   

0.283067(4)

10.0

Crustal xenolith

 AE01A/06

0.615

2.01

0.1851

0.512687(8)

1.1

0.261

420

0.0018

0.704374(14)

0.057

0.279

0.0291

0.282905(13)

4.2

 AE01C/06

1.29

4.55

0.1714

0.512667(7)

0.7

0.894

418

0.0062

0.704951(16)

0.118

0.689

0.0243

0.282923(7)

4.9

 AE01D/06

0.622

2.25

0.1674

0.512759(9)

2.5

0.431

448

0.0028

0.704519(13)

0.053

0.374

0.0201

0.282897(13)

4.0

 AE02/06

3.16

17.3

0.1108

0.512213(10)

−8.1

0.525

752

0.0020

0.707906(13)

0.259

1.56

0.0236

0.282489(6)

−10.5

 AE04/06

1.02

4.42

0.1390

0.512711(6)

1.6

0.874

764

0.0033

0.704977(14)

0.121

0.614

0.0280

0.282807(21)

0.8

Mantle xenolith

 Clinopyroxene

  AE08/06

0.998

2.74

0.2202

0.512928(29)

5.8

   

0.703444(8)

0.158

0.504

0.0445

0.283116(8)

11.7

  AE09/06

0.846

1.80

0.2842

0.512947(7)

6.2

   

0.703805(6)

0.174

0.401

0.0615

0.283197(9)

14.6

    

0.512943(31)

6.1

   

0.703839(14)

     

  AE10/06

0.900

2.44

0.2234

0.512930(31)

5.9

   

0.703448(8)

0.153

0.398

0.0546

0.283112(12)

11.6

  AE11/06

0.760

2.41

0.1907

0.512882(18)

4.9

   

0.704048(8)

0.091

0.487

0.0265

0.283107(14)

11.4

  AE14/06

0.722

1.80

0.2422

0.512911(15)

5.5

   

0.703694(9)

0.127

0.304

0.0594

0.283136(12)

12.4

  AE15/06

0.538

0.924

0.3521

0.512950(12)

6.2

   

0.703774(7)

0.130

0.213

0.0868

0.283258(12)

16.7

         

0.703733(35)

     

  AE16/06

0.698

1.48

0.2860

0.513042(5)

8.0

   

0.703104(5)

0.140

0.275

0.0725

0.283349(10)

19.9

    

0.513050(49)

8.2

   

0.703140(11)

     

  AE17/06

0.885

1.93

0.2777

0.512855(26)

4.4

   

0.704091(8)

0.128

0.249

0.0726

0.283105(11)

11.3

  AE18/06

1.16

2.80

0.2505

0.512897(9)

5.2

   

0.703963(6)

     

  AE19/06

0.897

2.98

0.1822

0.512880(8)

4.9

   

0.703371(7)

0.099

0.360

0.0389

0.283156(9)

13.1

    

0.512863(21)

4.6

         

  AE20/06

0.643

1.30

0.2987

0.512950(11)

6.2

   

0.703644(7)

0.166

0.244

0.0965

0.283273(10)

17.3

  AE21/06

1.07

2.56

0.2534

0.512859(7)

4.5

   

0.703978(7)

0.126

0.513

0.0349

0.283073(10)

10.2

 Orthopyroxene

  AE14/06

        

0.705827(15)

0.034

0.036

0.1359

0.283200(24)

14.7

  AE15/06

         

0.038

0.027

0.1989

0.283262(24)

16.9

  AE16/06

        

0.703856(15)

0.043

0.043

0.1408

0.283274(19)

17.3

 Plagioclase

  AE11/06

        

0.704031(10)

     

  AE17/06

        

0.704066(8)

     

  AE22/06

        

0.703998(6)

     

aεNd and εHf are calculated relative to the CHUR parameters of Bouvier et al. (2008, i.e., 143Nd/144Nd = 0.512630 and 176Hf/177Hf = 0.282785)

Mineralogy and equilibration temperatures and pressures

Host basalts

The host basalts are fine-grained, vesicular, and porphyritic with olivine (Fo77–86), plagioclase (An56–67), and diopsidic clinopyroxene (Mg# 69–79; Table 4a) phenocrysts set in a groundmass of plagioclase, pyroxene, olivine, and opaque phases. They also show pilotaxitic and glomero-porphyritic textures. The host basaltic carapaces adhering to mantle xenoliths (i.e., the thin skins of basalt which encrust xenolith samples AE08B, 10B, 12B, 18B, and 20B) are very fine-grained, vesicular, and vitrophyric with microphenocrysts of dominantly plagioclase and olivine with minor clinopyroxene. They also show pilotaxitic texture. Most samples also contain plagioclase and pyroxene xenocrysts.

Crustal xenoliths

The crustal xenoliths are coarse-grained, layered, granular olivine gabbros (samples AE01A, C, and D) containing olivine (Fo72–79), orthopyroxene (Mg# 72–78), diopsidic clinopyroxene (Mg# 76–81), and plagioclase (An65–71), and norites (samples AE02 and 04) containing olivine (Fo69), orthopyroxene (Mg# 60–62), and plagioclase (An45; Table 4a).

Mantle xenoliths

The ultramafic xenoliths contain a primary assemblage of ol + opx + cpx + sp ± pl; no hydrous minerals were observed. The 15 investigated xenoliths were subdivided into four groups on the basis of their mineralogy: dunite (AE13, 19, and 20: olivine > 90%; orthopyroxene + clinopyroxene + spinel < 10%), spinel lherzolite (AE08, 09, 10, 12, 18, and 21: olivine 45–65%, orthopyroxene 7–15%, clinopyroxene 25–35%, and spinel < 7%), plagioclase-free pyroxenite (AE14, 15, and 16: olivine 5–10%, orthopyroxene 20–45%, clinopyroxene 50–70%, and spinel < 5%) and plagioclase–spinel pyroxenite (AE11, 17, and 22: olivine 12–25%, orthopyroxene 20–30%, clinopyroxene 40–50%, spinel < 15%, and plagioclase 3–10%). These rocks are dominantly protogranular, characterized by coarse olivine and pyroxene grains, and rarely equigranular. Weak porphyroclastic texture is observed in some samples as manifested by kink bands in olivine and rare aggregates of several olivine crystals having similar orientation that were likely produced by recrystallization of larger olivine grains. All minerals occur as anhedral or (rarely) euhedral crystals and show no alteration. Grain boundaries are usually curvilinear except where localized recrystallization has produced polygonal mineral grains having straight boundaries that meet at 120°. The clinopyroxene in the plagioclase–spinel pyroxenites is leaf green (in hand specimen) whereas in the other xenoliths it is emerald green and sometimes displays exsolution lamellae. Diffuse to well-defined clinopyroxene-rich layers (bands) are commonly observed. Spinel typically occurs as small grains at grain boundaries as anhedral (vermicular) interstitial crystals and as inclusions. In the plagioclase–spinel pyroxenites, spinel also occurs as worm-like, cuneiform grains in pyroxene. Furthermore, euhedral (samples AE19 and 17) and poikilitic (sample AE12) spinel grains are found in the dunites, spinel lherzolites, and plagioclase–spinel pyroxenites. The color of spinel ranges from reddish-brown in the dunites to brown in the lherzolites and plagioclase-free pyroxenites, to green in plagioclase–spinel pyroxenites, with some grains having opaque rims. Thin, spinel-rich layers are observed in some samples. Symplectitic intergrowths of spinel and plagioclase are common in the plagioclase–spinel pyroxenites, suggesting a decompression reaction:
$$ \begin{gathered} {\text{spinel}} + {\text{clinopyroxene}} + {\text{orthopyroxene}} = {\text{plagioclase}} + {\text{olivine}} \hfill \\ ({\text{MgAl}}_{2} {\text{O}}_{4} + {\text{CaMgSi}}_{2} {\text{O}}_{6} + 2{\text{MgSiO}}_{3} = {\text{CaAl}}_{2} {\text{Si}}_{2} {\text{O}}_{8} + 2{\text{Mg}}_{2} {\text{SiO}}_{4} ). \hfill \\ \end{gathered} $$

In most samples, sponge-like textures are observed in spinel and pyroxene, and sometimes in olivine as well. In addition, trace amounts of plagioclase occur as discrete reaction products both in the dunites and lherzolites. Veins and pockets of silicate and carbonate (former) melts containing crystals of olivine, plagioclase, carbonate, and opaque phases ± pyroxene are also common in most samples.

Equilibration temperatures calculated using the two-pyroxene thermometer of Brey and Köhler (1990) range from 870 to 1,040°C (Table 4a; Fig. 2). No well-constrained geobarometers exist for the estimation of equilibration pressures in spinel peridotites or pyroxenites. This is due to the lack of suitable equilibria associated with a high volume change. However, several authors have attempted to calibrate single-phase geobarometers that are mainly based on clinopyroxene compositions. So far, these are the only way to independently estimate equilibration pressures in spinel facies ultramafic rocks. The 0.8–2.0 GPa pressures calculated using the clinopyroxene barometer of Mercier (1980) are only approximations of relative equilibration pressures (Table 4a; Fig. 2). Nevertheless, this barometer does yield relatively lower pressures for the plagioclase–spinel pyroxenites as compared to the lherzolites and dunites, which is petrologically reasonable. Furthermore, the estimation of equilibration pressures for the Assab xenoliths by fitting to the ocean plate geotherm of Wylie (1981), which is in agreement with the tectonic environment of the Afar Depression being transitional between continental rifting and sea floor spreading, gave similar results; i.e., the plagioclase–spinel pyroxenites equilibrated at lower pressures as compared to the lherzolites and dunites.
Fig. 2

Estimated PT of equilibration for the Assab peridotites and pyroxenites using the two-pyroxene thermometer of Brey and Köhler (1990) and the single clinopyroxene geobarometer of Mercier (1980). Geotherms and peridotite transitions are from Wylie (1981) and McGuire (1988 and references therein). Sources of data for Assab: Cimmino et al. (1976), Piccardo and Ottonello (1978), Ottonello et al. (1978, 1980)

Results

Major and trace elements

Host basalts

All analyzed host lavas are nepheline-normative alkaline basalts and show a narrow compositional variability suggesting that the degree of fractional crystallization among the basalts was limited. The basalts contain 7–8 wt% MgO, 10–13 wt% Fe2O3 (total, all Fe calculated as Fe3+), ~15.5 wt% Al2O3, ~9.8 wt% CaO, and ~3.3 wt% Na2O (Table 1). These host basalts have a low Mg# (0.58–0.61), and low Ni (111–234 ppm) and Cr (176–336 ppm) contents, suggesting that they underwent fractional crystallization before eruption and are therefore not primary melts. The relatively wider ranges in Ni, Cr, and Sc (Table 1) and the decrease of CaO/Al2O3 with decreasing MgO indicate the importance of olivine, clinopyroxene, and plagioclase fractionation in producing the small amount of compositional variation observed among the basalts.

Primitive mantle-normalized multi-element and REE patterns for the host basalts are shown in Fig. 3a. All basalts display enriched REE patterns, (Ce/Yb)N ranging from 6.2 to 10.3, and very slight positive Eu-anomalies (1.07–1.08). All samples are characterized by strong enrichment in the most highly incompatible elements coupled with enrichments of the moderately incompatible elements relative to HREE and Y.
Fig. 3

Primitive mantle-normalized multi-element (a, c, e) and chondrite-normalized REE (b, d, f) patterns for the Assab host basalts (basaltic carapaces and sample AE07B/06, dashed lines; a, b), crustal xenoliths and representative Neoproterozoic and Miocene gabbros (dashed lines; c, d) from Eritrea and Yemen, respectively (Teklay et al. 2001; Chazot and Bertrand 1993), and clinopyroxene (solid lines) and orthopyroxene (dashed lines) from mantle xenoliths (e, f). Normalizing values are from McDonough and Sun (1995)

The Sr–Nd–Hf isotope ratios of the host basalts are quite similar (Table 3) and there is no increase in Sr or decrease in Nd or Hf isotope ratios with decreasing Mg# that would be expected in rocks affected by crustal contamination. Hence, in these rocks, ratios of incompatible elements having similar distribution coefficients should reflect the source characteristics and the magmatic processes that have affected the host basalts. Detailed observations of the host basalts show the presence of two groups (Tables 1, 2; Fig. 3a, b). The basaltic carapaces (AE08B, 10B, and 12B) and sample AE07B are relatively more alkaline (higher Na2O + K2O) and, for a given MgO content, show higher abundances in all incompatible elements except Ti, Y, and HREE (Tables 1, 2; Fig. 3a). They also tend to have higher Mg#, Cr, and Ni contents. However, the ratios of highly incompatible elements that have crystal/melt partition coefficients close to 0 (e.g., Ba/Nb, Ba/La, Nb/La, Nb/Th, and Cs/Rb) that are not likely to be modified by partial melting and fractional crystallization processes are similar for both groups (Tables 1, 2; Fig. 3a). These, together with the similar Sr–Nd–Hf isotope ratios, suggest the same homogenous source for both groups. On the other hand, ratios of highly to moderately incompatible elements (e.g., La/Yb, Nb/Zr, Nb/Y, Ba/Zr), which are modified during partial melting but not during typical degrees of fractional crystallization, differ between the two groups, suggesting a variable degree or depth of melting. The high values of these ratios [e.g., (Ce/Yb)N = 9.2–10.3 vs. 6.2–6.9] in combination with relatively lower Y and HREE abundances for the basaltic carapaces (AE08B, 10B, and 12B) and sample AE07B suggest that these samples have been formed by relatively lower degrees of partial melting or at greater depth.

Crustal xenoliths

The three gabbro xenoliths (AE01A, C, and D) have similar chemical compositions: ~10.5 wt% MgO, ~13.5 wt% CaO, ~6.8 wt% Fe2O3 (total), low TiO2 (0.2–0.5%), slightly enriched REE patterns, (Ce/Yb)N between 2.2 and 2.6, and positive Eu-anomalies (1.45–1.93; Fig. 3b, d). The two norite xenoliths (AE02 and 04) have higher TiO2 (~1.3 wt%), ~11.5 wt% Fe2O3 (total), and lower MgO (<7 wt%) and CaO (~8 wt%). They also have relatively enriched REE patterns, with (Ce/Yb)N ranging from 2.9 to 6.1, and pronounced positive Eu-anomalies (2.5–3.0). In addition to their departures from smooth curves, the spidergrams for the gabbroic crustal rocks show marked depletions in the high field strength elements (HFSE: e.g., Zr, Hf, Ta, Nb), Th, and U and high LREE/HFSE. Furthermore, their relative enrichments in large ion lithophile elements (LILE: e.g., Ba, Sr, Pb) lead to positive anomalies and high values in LILE/HFSE and LILE/LREE (Fig. 3b).

Mantle xenoliths

Bulk compositions of mantle xenoliths may provide valuable constraints on the nature of the lithospheric mantle, but this record can be overprinted by a range of processes that contribute conflicting geochemical signatures to an individual xenolith. We avoided these possible complications by analyzing core compositions of large clear grains to evaluate the primary mineralogy of the lithosphere under the Assab region. The cores are remarkably homogeneous and separate grains from a single rock sample are homogenous within the analytical error, indicating the absence of post-crystallization reactions between minerals and melt in the analyzed grains.

Olivine. The forsterite content of olivine ranges from Fo92 in the dunites to Fo79 in the plagioclase–spinel pyroxenites. Nickel, Cr, and V correlate positively with—and Co and Mn correlate negatively with—forsterite content (Tables 4a, b; Fig. 4). Furthermore, equilibration temperatures also correlate positively with the forsterite content of olivine (Fig. 4). The concentrations of most incompatible trace elements in olivine are below detection limits (Table 4b).
Fig. 4

NiO, equilibration T, Cr, and Mg# of clinopyroxene, orthopyroxene, and spinel versus forsterite content of co-existing olivine. Sources of data as in Fig. 2

Orthopyroxene. The Mg# of orthopyroxene ranges from 80 in the plagioclase–spinel pyroxenites to 91 in the dunites. The proportions of enstatite correlate positively with forsterite content of the co-existing olivine (Fig. 4). Nickel, Cr, and Sc correlate positively with—and Ti, Al, Co, and Mn correlate negatively with—the Mg# of the orthopyroxene (Tables 4a, b; Fig. 5). Furthermore, equilibration temperatures also correlate positively with Mg#. Orthopyroxene from all xenolith types shows depleted REE patterns, with (Ce/Yb)N ranging from 0.004 to 0.063 (Fig. 3f). Primitive mantle-normalized multi-element patterns of the orthopyroxene separates are shown in Fig. 3e. Positive K and Ti anomalies and negative Sr anomalies are evident in Fig. 3e.
Fig. 5

Clinopyroxene (left) and orthopyroxene (right) Al2O3, and Cr2O3 versus Mg#. Symbols and sources of data as in Fig. 4

Clinopyroxene. The clinopyroxene is Al–Cr-diopside with 0.28–1.56 wt% Cr2O3, 3.15–6.83 wt% Al2O3, 0.10–0.84 wt% TiO2, and 0.38–0.91 wt% Na2O. The Mg# ranges from 81 to 92 and correlates positively with the forsterite content of co-existing olivine and the Mg# of co-existing orthopyroxene (Table 4a; Fig. 4). As with the orthopyroxene, the clinopyroxene in the dunites has a higher Mg#, higher Cr2O3, and lower Al2O3, Na2O, and TiO2 than in the other xenolith types (Table 4a; Fig. 5). The clinopyroxene predominantly has depleted chondrite-normalized REE patterns, with (Ce/Yb)N ranging from 0.19 to 0.69 (Fig. 3f). Only clinopyroxene from samples AE11 and AE19 shows slightly enriched REE patterns, with (Ce/Yb)N values of 1.10 and 1.41, respectively. Primitive mantle-normalized multi-element patterns for the clinopyroxene are shown in Fig. 3e where negative anomalies for Ba, Nb, K, Pb, Sr, Zr, and Ti are evident.

Spinel. The Mg# of spinel ranges from 59 to 73 and correlates with the forsterite content of the co-existing olivine and the Mg# of the co-existing ortho- and clinopyroxene (Table 4a; Fig. 4). The reddish-brown spinel in the dunites is Cr2O3-rich (26.4–40.4 wt%) and Al2O3-poor (27.3–42.0 wt%), the green spinel in the plagioclase–spinel pyroxenites is Cr2O3-poor (0.8–5.7 wt%) and Al2O3-rich (59.0–64.5 wt%), and the brown spinel in the lherzolites and plagioclase-free pyroxenites has intermediate compositions (Table 4a). Hence, the spinels in the four types of xenoliths can be distinguished from each other by color and Cr#.

Plagioclase. The anorthite content of the plagioclase in the spinel–plagioclase pyroxenites ranges from An64 to An81. The anorthite content of the plagioclase that occurs as a discrete reaction product in the lherzolites (e.g., sample AE09 = An78) also lies within this range (Table 4a).

Sr–Nd–Hf isotope ratios

The Sr–Nd–Hf isotope ratios of host basalts, crustal xenoliths, and mineral separates from the mantle xenoliths (clinopyroxene, orthopyroxene, and plagioclase) are given in Table 3 and shown in Figs. 6 and 7. The host basalts all have similar Sr–Nd–Hf isotope ratios: 87Sr/86Sr = 0.70336–0.70356, εNd = +6.6 to +7.0, and εHf = +10.0 to +10.7 (Fig. 6). Clinopyroxene from mantle xenoliths displays a limited range in isotope composition: 87Sr/86Sr = 0.70310–0.70409, εNd = +4.4 to +8.0, and εHf = +10.2 to +19.9 (Fig. 7). Orthopyroxene from the plagioclase-free pyroxenites has 87Sr/86Sr = 0.70386–0.70583 and εHf = +14.7 to +17.3, and the plagioclase from the plagioclase–spinel pyroxenites has 87Sr/86Sr = 0.70400–0.70407 (Table 3). In contrast, the gabbroic crustal xenoliths show wider ranges: 87Sr/86Sr = 0.70437–0.70791, εNd = −8.1 to +2.5, and εHf = −10.5 to +4.9 (Table 3; Fig. 6). The clinopyroxene separates from the Assab mantle xenoliths are compatible with 30 Ma Sm–Nd and Lu–Hf reference lines (Fig. 8). This is the time of plume impingement on the base of the lithosphere in this region. In contrast, the whole rock gabbros (crustal xenoliths) spread along steeper, Neoproterozoic reference lines (Fig. 8).
Fig. 6

Sr–Nd–Hf isotope data for the Assab host basalts and crustal xenoliths compared to basalts from the Afar volcanic province. Sources of data: Assab (Barberi et al. 1980; Betton and Civetta 1984), Hanish and Zubair islands (Volker et al. 1997), Erta’Ale (Barrat et al. 1998), Ramad sea mount (Volker et al. 1997), Yemen (Bertrand et al. 2003), and fields for 19°–23°N Red Sea MORB (http://www.petdb.org/), older Afar basalts (>10 Ma, i.e., Mabla and older basalts, Barrat et al. 1993; Deniel et al. 1994), and Assab clinopyroxene (this study). Note the breaks in the axes

Fig. 7

Sr–Nd–Hf isotope data for clinopyroxene from Assab peridotites and pyroxenites. For comparison, data are shown for clinopyroxene from other xenoliths: Assab (Betton and Civetta 1984 and the two whole rock spinel peridotites with the highest Sr isotope ratios from Ottonello et al. 1978), Ethiopia (Roger et al. 1999), Jordan (Shaw et al. 2007), Saudi Arabia (Henjes-Kunst et al. 1990; Blusztajn et al. 1995), Yemen (Baker et al. 2002), and Zabargad island (Brueckner et al. 1988)

Fig. 8

Sm–Nd (a) and Lu–Hf (b) isochron diagrams showing Assab crustal gabbroic xenoliths and clinopyroxene separates from mantle xenoliths in relation to clinopyroxene separates from mantle xenoliths from Saudi Arabia (Henjes-Kunst et al. 1990) and Jordan (Shaw et al. 2007), and Zabargad island peridotites (Brueckner et al. 1988). The Assab mantle xenoliths plot near ~30 Ma reference lines, whereas the crustal gabbroic xenoliths and the other mantle xenoliths and peridotites from the region plot near Proterozoic reference lines (e.g., ~0.75–0.80 Ga for the Sm–Nd system or ~1.5 Ga for the Lu–Hf system)

Discussion

Host basalts

Quaternary volcanism in the Afar Depression is manifested mainly as two distinct types of volcanic structures. One is characterized by axial ranges that display topographic, seismic, and gravimetric similarities to mid-oceanic spreading ridges. These volcanic units, which are less than a million years old, are typically produced by basaltic fissure eruptions occurring along NW–WNW-aligned axes. The other type of volcanic structure is characterized by ranges that are transverse to the main tectonic trend of the depression. These are marked by alignments of scoria cones and basaltic flows along an E–W to NE–SW direction, and include the Assab range and the islands of Hanish and Zubair (Fig. 1). These transverse volcanic structures are considered to be the equivalents of oceanic fracture zones and are contemporaneous with volcanism at the axial ranges (Barberi and Varet 1977). It is well documented that the transverse tectonic structures of the Afar Depression are characterized by alkaline basaltic volcanism that contrasts with the transitional basaltic volcanism of the axial ranges (De Fino et al. 1973; Barberi et al. 1974; Civetta et al. 1975). Basalts from the transverse tectonic structures have the highest abundances of most highly incompatible trace elements, suggesting that they were derived by a lower degree of melting than the axial range basalts (Fig. 9a). Geochemical variations in the Afar Depression (axial ranges and transverse volcanic structures) have been variously interpreted to reflect derivation from a vertically zoned mantle source (Barberi et al. 1980; Betton and Civetta 1984), and to be the result of mixing between the depleted Red Sea MORB source and an enriched plume source (Hart et al. 1989; Schilling et al. 1992; Barrat et al. 1998).
Fig. 9

a Trace element patterns, b Nb/Th and Ba/Yb versus epsilon Nd, and Ti/Eu versus Ce/Yb for Assab host basalts as compared to basalts from Ramad seamount, Erta’Ale, and islands of Hanish and Zubair. Basalts from Assab and islands of Hanish and Zubair plot close to the enriched Ramad and do not extend into the fields for older (>10 Ma) Afar or Tadjoura basalts, whereas the Erta’Ale basalts extend to the field of the older Afar basalts that is dominated with a significant contribution from a subcontinental lithosphere. Symbols and sources of data as in Fig. 6

Figure 6 presents the Sr–Nd isotope compositions of basalts having >5 wt% MgO from the Assab region, Erta’Ale, and the islands of Hanish and Zubair (in the southern Red Sea axial trough), together with typical Red Sea N-MORB (19°–23°N), and the Ramad enriched component. The Assab host basalts have Sr–Nd isotope values that are similar to those of the Hanish and Zubair basalts, and they also have trace element patterns that parallel those of the Hanish and Zubair basalts despite having slightly higher abundances of the most highly incompatible elements due to a lower degree of melting (Fig. 9a). Basalts from the transverse tectonic structures, including the Assab host basalts, and basalts from Hanish and Zubair islands have somewhat more depleted Sr–Nd isotope values as compared to basalts from the axial ranges, i.e., the Erta’Ale basalts (Fig. 6). Figure 9b clearly shows that neither the Assab host basalts nor the basalts from Hanish and Zubair islands require a contribution from a third component that dominates the older (>10 Ma) Afar basalts or a contribution from the Tadjoura component. Hence, the Assab host basalts, like the basalts from the Hanish and Zubair islands, seem to be predominantly derived from melting of the enriched Ramad mantle component.

The two distinct types of volcanic structures in the Afar Depression, the axial ranges and the transverse volcanic structures, are related in space and time. However, they show different melting conditions and isotopic characteristics. The basalts of the transverse volcanic structures are characterized by depleted Sr and Nd isotopic signatures, and by either lower degrees of melting or greater depths of melting. In contrast, the basalts of the axial ranges have relatively enriched Sr and Nd isotopic signatures and likely originated by melting at shallow depth or by greater extents of melting. We suggest that both are from the same Afar mantle source as represented by the Ramad seamount, but some basalts of the axial ranges have been more contaminated by the high 87Sr/86Sr and low 143Nd/144Nd subcontinental lithosphere (Fig. 9a, b).

A closer inspection of the Sr isotope variations of the Assab host basalts and basalts from the islands of Hanish and Zubair (Fig. 6b, inset) shows a trend toward higher 87Sr/86Sr values at similar 143Nd/144Nd values for the Assab host basalts. These rocks also trend towards higher Ce/Yb and lower Ti/Eu (Fig. 9c). The criteria proposed by Rudnick et al. (1993) for recognition of the signature of carbonate-related metasomatism include high LREE/HREE, very high Zr/Hf and very low Ti/Eu. Thus, the higher Sr isotope ratios measured in the Assab host basalts may indicate that their source has been more affected by carbonate-related metasomatism than the source of the Hanish and Zubair basalts.

Gabbroic xenoliths

The crustal xenoliths show the largest variation in Sr–Nd–Hf isotope ratios. Their 87Sr/86Sr ranges from 0.70437 to 0.70791, εNd from −8.3 to +2.4, and εHf from −10.0 to +5.3. They have trace element characteristics and primitive mantle-normalized geochemical patterns similar to those of the Neoproterozoic rocks of the Arabian–Nubian Shield and modern arc rocks. These similarities include enrichment in LILE and depletion in HFSE (Figs. 3c, 10). Furthermore, their high La/Nb values (~2–4.5; Fig. 10) and low Ni contents (<35 ppm) at a Mg# of 40 suggest that the gabbroic xenoliths are subduction-related cumulates (Condie 1999). On Sm–Nd and Lu–Hf isochron diagrams, the crustal xenoliths plot near Proterozoic trends defined by mantle xenolith clinopyroxene separates from the broader region (e.g., Jordan, Saudi Arabia, Yemen, Ethiopia, and Egypt; Fig. 8). Hence, we interpret the Assab mafic lower crustal xenoliths to be part of the Neoproterozoic subduction-related cumulates of the Arabian–Nubian Shield (Teklay 2006).
Fig. 10

Zr and La/Nb versus MgO for gabbroic xenoliths as compared to Neoproterozoic mafic arc rocks from Eritrea (Teklay 2006 and references therein) and Miocene gabbro and dikes from Yemen and Saudi Arabia (Capaldi et al. 1987; McGuire and Coleman 1986; Manetti et al. 1991; Chazot and Bertrand 1993)

Mantle xenoliths

On the basis of major element systematics of bulk samples, the compositional trends of the peridotitic mantle xenoliths have been mostly ascribed to effects of progressive partial melting. For example, the Assab xenoliths have been interpreted to represent residues after various degrees of partial melting (Ottonello et al. 1978; Ottonello 1980). However, as we will explain below, the wide range in the composition of the different minerals in the Assab ultramafic rocks is more suggestive of fractional crystallization processes than partial melting processes. As a consequence, the Assab ultramafic rocks are probably not mantle residues but may rather be sequences of layered cumulates from a relatively enriched picritic melt.

The Mg# of peridotitic mantle olivine is between 88 and 92 and reflects that of the whole rock, which in turn is related to the degree of melt depletion or enrichment. Xenoliths that crystallized from silicate melts are generally Fe-enriched relative to depleted peridotite and hence their olivine has a lower Mg# (Pearson et al. 2004 and references therein). The olivine in the Assab peridotites and pyroxenites ranges down to lower forsterite content (Fo79–92) suggesting that the rocks are crystallization products of silicate melts. Likewise, the Mg#s of orthopyroxene and clinopyroxene in mantle peridotites are typically above 90, suggestive of their residual character. In contrast, the Mg#s of orthopyroxene and clinopyroxene of the Assab xenoliths extend to lower values and vary widely from 80 to 91 and from 81 to 92, respectively.

Figure 11 is a plot of spinel Cr# versus the forsterite content of co-existing olivine showing the olivine–spinel mantle array (OSMA), which was argued by Arai (1994) to be residual in nature. The Assab xenoliths, which plot outside this array toward lower Fo values, are therefore apparently not mantle residues but rather a suite of cumulates. This is further supported by the presence of clinopyroxene- and spinel-rich layers and euhedral spinel crystals in the Assab xenoliths, which constitute structural and textural evidence for accumulation and crystallization from a melt. Note that several xenoliths from the Main Ethiopian Rift (Rooney et al. 2005) also plot to the low-Fo side of OSMA in Fig. 11 and these may be cumulates as well.
Fig. 11

Spinel Cr# and NiO of olivine and Al2O3 and Cr2O3 of co-existing clinopyroxene versus forsterite content in olivine. The Assab mantle xenoliths are compared with those from Ethiopia and Yemen xenoliths, and the Zabargad peridotites. Sources of data: Ethiopia (Bedini et al. 1997; Bedini and Bodinier 1999; Conticelli et al. 1999; Roger et al. 1999; Orlando et al. 2006; Ferrando et al. 2007), Main Ethiopian Rift (MER, Rooney et al. 2005), Yemen (Chazot et al. 1996), Zabargad (Bonatti et al. 1986; Piccardo et al. 1988; Kurat et al. 1993). Olivine–spinel mantle array (OSMA) is from Arai (1994)

Trends in the abundance of compatible transition elements can also be utilized to test cumulate and residue hypotheses. Elements having bulk solid/liquid partition coefficients of 2–10 do not vary much in the residue during (fractional) fusion, whereas fractional crystallization can cause significant abundance changes in cumulates. There are large ranges in compatible element abundances in the minerals of the Assab xenoliths. For example, Cr contents vary by a factor of 4 in olivine (0.26–0.94 wt%), by a factor of 8 in orthopyroxene (0.046–0.35 wt%) and by a factor of 19 in clinopyroxene (5–95 ppm). Within these ranges, Cr contents are in agreement with their corresponding Mg# and largely reflect the amount of fractional crystallization that had already taken place in the melt(s) before the cumulate peridotites and pyroxenites crystallized from them (Tables 4a, b; Fig. 11).

The Mg# of olivine, clinopyroxene, and orthopyroxene, the Cr# of spinel, and the abundances of compatible elements progressively increase with increasing temperature of xenolith equilibration and also relatively with increasing pressure (Tables 4a, b). Such variations are compatible with the Assab xenoliths being sequences of cumulates whose layering was controlled by the order of appearance of the cumulus phases and their relative density. Fractional crystallization and accumulation gave rise to the following main lithotypes: dunite, spinel lherzolite, plagioclase-free pyroxenite, and plagioclase–spinel pyroxenite. The Assab dunites, presumably the early peridotite cumulates, have high-Fo olivine, high Mg# in clinopyroxene and orthopyroxene, and high Cr# in spinel, high compatible element contents (e.g., Ni, Cr), and relatively high average P and T of equilibration. These values generally decrease from dunites through spinel lherzolites to plagioclase–spinel pyroxenites (from early to late cumulates), as is typical for rocks related by differentiation (fractional crystallization) processes. The dunites are apparently derived from the least fractionated liquids, so their olivine, pyroxenes, and spinel have compositions similar to those of their counterparts in dunite and harzburgite residues that remain after partial melting of mantle peridotite.

In anhydrous spinel peridotites, clinopyroxene is the main carrier of REE, Ti, and Zr (Pearson et al. 2004 and references therein). Recognizing that clinopyroxene dominates the bulk distribution coefficients of incompatible elements in anhydrous spinel peridotites, the REE in Assab xenoliths can be used to model fractional crystallization (Fig. 12). Accordingly, about 10–60% of fractional crystallization was needed to form the Assab-layered cumulates (Fig. 12). The results of the crystallization models are illustrative but are not unique. Some xenoliths do have stronger LREE (La and Ce) enrichment than predicted by the model. These xenoliths also show higher Pb, Th, U, and Nb contents and trend towards higher Zr/Hf, La/Zr, and La/Ti values (Tables 4a, b; Fig. 13). These enrichments and trends are not related to the fractional crystallization process, but most likely reflect cryptic metasomatic enrichment in some xenoliths. Carbonate-related metasomatism causes a relative enrichment in LREE and Sr over HREE and HFSE leading to high LREE/HFSE values (Ionov et al. 1993; Ionov 1998). Given the presence of carbonate veins and melt pockets in the samples, the xenoliths that show enrichment in LREE may have been affected by carbonate-related metasomatism. The distinctly higher 87Sr/86Sr ratios of whole rock samples of the Assab spinel peridotites compared to clinopyroxene separates at similar εNd values (Fig. 7) have also been interpreted to result from carbonate-related metasomatism (Ottonello et al. 1978).
Fig. 12

Model fractional crystallization (instantaneous solid) of an enriched source (dashed lines) as compared to REE data from Assab clinopyroxene separates showing that the Assab peridotites and pyroxenites could be formed as cumulates from such a source. The source, C0, is 20% batch melting of a primitive mantle composition (McDonough and Sun 1995) with a starting and melt modes of 0.55 and 0.10 for olivine, 0.25 and 0.20 for orthopyroxene, 0.18 and 0.68 for clinopyroxene, and 0.02 and 0.02 for spinel, after Johnson et al. (1990). Equation for instantaneous solid: \( C_{\text{cpx}} = C_{0} D_{\text{cpx}} F^{{(X_{\text{cpx}} \times D_{\text{cpx}} - 1)}} \), where Xcpx = 0.3. Partition coefficients are taken from Rollinson (1993)

Fig. 13

La/Ti and Zr/Hf versus La/Sm for Assab clinopyroxenes

The limited variation of the Sr–Nd–Hf isotope ratios among the clinopyroxene separates and their correlation of these ratios with the degree of fractionation (Mg# of olivine, clinopyroxene, and orthopyroxene), abundances of compatible elements (Fig. 14), and compatible-to-incompatible element ratios suggest that the Assab cumulates were genetically related and formed relatively recently (<50 Ma). For both Lu–Hf and Sm–Nd systems, the Assab cumulates form general trends that are consistent with 30 Ma reference lines (Fig. 8). This time marks the onset of magmatic activity that was triggered by the impingement of the Afar plume head on the lithosphere of this region (e.g., Hoffman et al. 1997). The initial 143Nd/144Nd and 176Hf/177Hf of the reference lines (i.e., ca. +6 and +12 epsilon units, respectively) are suggestive of a source that was somewhat enriched relative to the average MORB source mantle.
Fig. 14

Sr–Nd–Hf isotope ratios versus forsterite content of olivine (a) and Cr2O3 content of clinopyroxene (b) for Assab mantle xenoliths

Mantle xenolith suites often sample the mantle over a range of pressure and temperature, and because they are transported to the surface with little or no re-equilibration, they are very useful for estimating lithospheric thickness and geothermal gradients (e.g., Rudnick et al. 1998), and in some cases provide evidence for a vertical stratigraphy (e.g., Griffin et al. 1999). The PT estimates for the Assab xenoliths (Fig. 2) scatter near the ocean plate geotherm of Wylie (1981) at higher temperatures than those expected in continental shield geotherms and at lower temperatures than those expected in ocean ridges. This is in agreement with the tectonic environment of the Afar Depression being transitional between continental rifting and sea floor spreading. The higher temperature of the upper mantle material under the Afar is also supported by the results of the magnetotelluric soundings of this area (Berktold et al. 1975).

The crustal structure of the Afar Depression and East African rift as obtained from seismic and gravity data departs from that of typical continental crust in both thickness and velocity distribution in the crust and upper mantle. Seismic (e.g., Makris and Ginzburg 1987; Dugda et al. 2005) and gravity (e.g., Makris and Ginzburg 1987; Tiberi et al. 2005) studies within the Red Sea, Afar, and the Main Ethiopian Rift suggest that the crust beneath the Main Ethiopian Rift and the Afar Depression is continental in nature, but thinned, being thickest (~40 km) under the plateau, and thinner (~32 km) under the Main Ethiopian Rift. The latter crust thins toward the north in the Afar Depression to ~25 km. This thickness of the Afar crust as determined by geophysical methods is similar to the geobarometric estimate for the depth of origin of the Assab plagioclase–spinel pyroxenites (Fig. 2).

In the Afar Depression, the thinned crust is underlain by an upper mantle having an abnormally low velocity of 7.4 km/s, which has been interpreted to indicate the presence of a large intrusive complex there. Inferred densities of 3.0–3.1 g/cc suggest that this complex most likely consists of mantle or a mixture of crust and mantle material (Makris and Ginzburg 1987). Tiberi et al. (2005) have interpreted the higher Bouguer gravity values over the Afar region as being caused by a thin (23 km) and dense crust that was modified by magmatic underplating at the crust–mantle boundary. In the western plateau of Ethiopia, a 15-km-thick layer having a velocity of 7.4 km/s beneath the crust has been interpreted as evidence for magmatic underplating during the Oligocene and/or the Holocene (MacKenzie et al. 2005).

These unusual velocity and gravity characteristics of the crust and upper mantle under the Main Ethiopian Rift and the Afar Depression are most likely a result of the tremendous amount of mafic dykes and sills that make up the crust in this area (e.g., Makris and Ginzburg 1987; MacKenzie et al. 2005; Tiberi et al. 2005). Such unusual seismic velocities (Vp = 7.3–7.8 km/s) at the base of the crust are observed in both continental and oceanic environments. In continental settings, these layers are associated with rift volcanism and are generally interpreted as large, underplated igneous intrusions emplaced before or during rifting (e.g., Farnetani et al. 1996). Furthermore, in provinces affected by plume magmatism, the largest volumes of volcanic rocks are tholeiitic basalts that have lower MgO concentrations indicating the significant degree of crystal fractionation they have undergone before being erupted. In contrast to their occurrence in oceanic environments, picrites are very rare in continental flood basalt provinces, suggesting the great importance of the hidden cumulates in the lower crust and upper mantle compositions of the continental lithosphere. Farnetani et al. (1996) suggested the high-velocity layers beneath oceanic plateaus and hot spot tracks represent fractionated cumulates from picritic mantle melts and are therefore an integral part of plume magmatism. The chemical compositions of the Assab xenoliths are consistent with such an origin and thus these rocks may represent cumulates that crystallized from deep, picritic melts of the Afar plume.

A schematic cross-section of the lithosphere under Afar Depression presented in Fig. 15 summarizes the important conclusions derived from the study of Assab xenoliths. Taken together, the Assab xenoliths’ compositions and estimated PT of origin together with existing geophysical data all suggest that the lithosphere below the Afar Depression consists of an upper crust of lavas, sediment cover, and Neoproterozoic granitic rocks, underlain by a Neoproterozoic mafic igneous lower crust and an upper mantle with cumulate layers and melt.
Fig. 15

Seismic data (a) and schematic cross-section of the upper lithosphere beneath Afar Depression (b). Seismic data are from Ottonello et al. (1978) and the left-hand column showing peridotite phase relations is from McGuire (1988 and references therein)

Conclusions

A detailed geochemical and isotopic study of gabbroic, peridotitic, and pyroxenitic xenoliths and their host basalts from the Assab area, Afar Depression provides important insights into the geodynamic evolution of a rift system, and constrains important aspects of the rifting process, including the local geothermal gradient. The main conclusions of this study can be summarized as follows.

The alkaline host basalts show enriched REE patterns and trace element geochemical characteristics similar to those of ocean island basalts. The basalts define limited ranges in Sr–Nd–Hf isotope ratios that do not correlate with fractionation index, indicating the absence of significant crustal contamination. On the other hand, correlations between isotope and trace element ratios provide evidence for the interaction of the Afar plume and the depleted Red Sea MORB mantle source in the petrogenesis of these host basalts.

The gabbroic crustal xenoliths have the highest 87Sr/86Sr values and the lowest εNd and εHf. They have trace element characteristics that are similar to those of rocks from the Neoproterozoic Arabian–Nubian Shield and modern arcs, i.e., enrichment in the LILE (e.g., Ba, Sr, and Pb) and marked depletions in the HFSE (e.g., Zr, Hf, and Nb). Hence, the lower crust of the Afar Depression is inferred to comprise mostly Neoproterozoic mafic igneous rocks.

The Assab ultramafic xenoliths are not products of crystallization of their host magmas. Rather, they apparently crystallized from an earlier generation of similar magmas. The xenoliths show systematic chemical variations that largely reflect the relative degree of fractional crystallization that their parental melts had already undergone. The fractional crystallization resulted in the formation of layered sequences of cumulates from a relatively enriched, Afar plume-derived, originally picritic melt. The PT estimates for the xenoliths from the Assab region follow a steeper geothermal gradient than that expected for continental shields, consistent with the tectonic environment of the Afar Depression. The Assab mantle xenoliths provide strong evidence for the presence of significant amounts of hidden cumulate rock within the lower crust and upper mantle of the continental lithosphere and account for the rare occurrence of picrites as compared to tholeiitic basalts in continental flood basalt provinces.

Notes

Acknowledgments

This study was conducted while M. Teklay was a recipient of fellowships from the Alexander von Humboldt Stiftung (Georg Forster) and the Deutsche Forschungsgemeinschaft. We kindly acknowledge H. Baier and J. Berndt for their assistance in the laboratory, TIMS, and microprobe analyses, and J. Blundy and S. Klemme for their fruitful discussions. Ruesom Teclemariam is thanked for his support in Assab during sample collection. Finally, we thank Jean-Alix Barrat and an anonymous reviewer, whose insightful comments helped improve the manuscript.

Open Access

This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.

Supplementary material

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Copyright information

© The Author(s) 2009

Authors and Affiliations

  • Mengist Teklay
    • 1
    • 2
  • Erik E. Scherer
    • 2
  • Klaus Mezger
    • 2
  • Leonid Danyushevsky
    • 3
  1. 1.Department of Earth SciencesUniversity of AsmaraAsmaraEritrea
  2. 2.Institut für MineralogieUniversität MünsterMünsterGermany
  3. 3.CODESUniversity of TasmaniaTasmaniaAustralia

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