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Rheologica Acta

, Volume 56, Issue 7–8, pp 661–671 | Cite as

Small-diameter parallel plate rheometry: a simple technique for measuring rheological properties of glass-forming liquids in shear

  • Olli-Ville Laukkanen
Original Contribution

Abstract

The rheological characterization of glass-forming liquids is challenging due to their extreme temperature dependence and high stiffness at low temperatures. This study focuses on the special precautions that need to be taken to accommodate high sample stiffness and torsional instrument compliance in shear rheological experiments. The measurement errors due to the instrument compliance can be avoided by employing small-diameter parallel plate (SDPP) rheometry in combination of numerical instrument compliance corrections. Measurements of that type demonstrate that accurate and reliable rheological data can be obtained by SDPP rheometry despite unusually small diameter-to-gap (d/h) ratios. Specimen preparation for SDPP requires special attention, but then experiments show excellent repeatability. Advantages and some current applications of SDPP rheometry are briefly reviewed. SDPP rheometry is seen as a simple and versatile way to measure rheological properties of glass-forming liquids especially near their glass transition temperature.

Keywords

Rheometry Glass-forming liquids Instrument compliance Measurement repeatability 

Notes

Acknowledgements

Financial support from the Vilho, Yrjö, and Kalle Väisälä Foundation is gratefully acknowledged. The author also wishes to thank Anton Paar GmbH and Malvern Instruments Ltd. for technical support and equipment loans, Prof. Gregory McKenna and Dr. Stephen Hutcheson for providing plate diameter-dependent rheological data of glycerol, and Prof. H. Henning Winter for helping in the preparation of the manuscript.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  1. 1.Department of Polymer Science and Engineering and Department of Chemical EngineeringUniversity of MassachusettsAmherstUSA
  2. 2.Department of Chemical and Metallurgical Engineering, School of Chemical TechnologyAalto UniversityAaltoFinland

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