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Rheologica Acta

, Volume 46, Issue 7, pp 979–987 | Cite as

Experimental observation on the flow-induced assembly of Carbon nanotube suspensions to form helical bands

  • Anson W. K. Ma
  • Malcolm R. Mackley
  • Sameer S. Rahatekar
Original Contribution

Abstract

This paper describes optical observations on the way aggregates of multi-walled carbon nanotubes (CNTs) in an epoxy matrix can form unusual helical bands (HBs) that are aligned perpendicular to the shear flow. By applying specific flow conditions, HBs were formed from isotropic aggregates of CNTs suspended in an essentially Newtonian epoxy matrix. Both optical and matching rheological data are presented together with a schematic model of the way HBs are formed. It was discovered that the steady shear rheology of the CNT suspension did not substantially change during the observed micro-structure change. The HB structure may have relevance in terms of potential applications for CNTs.

Keywords

Fibre suspension Shear-induced structure formation Rheo-optics 

Notes

Acknowledgment

We would like to thank Prof. A.H. Windle and the Department of Materials Science and Metallurgy at the University of Cambridge for providing the base multi-walled carbon nanotubes. Anson Ma would also like to thank the Croucher Foundation Scholarship and the Overseas Research Students Awards Scheme `(ORSAS) for providing financial support.

Supplementary material

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Copyright information

© Springer-Verlag 2007

Authors and Affiliations

  • Anson W. K. Ma
    • 1
  • Malcolm R. Mackley
    • 1
  • Sameer S. Rahatekar
    • 1
  1. 1.Department of Chemical EngineeringUniversity of CambridgeCambridgeUK

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