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Luminescent lanthanide metallogels: situ fabrication, self-healing and rheological properties

  • Min XueEmail author
  • Ming Chen
  • Wenhao Chang
  • Ruiyang Chen
  • Pengna Li
Original Contribution
  • 13 Downloads

Abstract

We have presented a simple method for situ fabrication of photoluminescent lanthanide metallogels. A series of lanthanide metallogels could be rapidly formed through mixing the aqueous solution of Tb3+ or Eu3+ and organic solution of synthesized aromatic carboxylic ligands (DCn, n = 14, 16,18) at room temperature. The gelation tests revealed that the ligand with longer alkyl chain (DC18) showed stronger gelling abilities, indicating that the structure of non-coordinated groups in ligand molecules could affect self-assembly processes and, hence, the microstructures and properties of lanthanide metallogels. FT-IR measurements demonstrated that the driving force of formation of the metallogels was the coordination interaction between DCn and Tb3+ or Eu3+. XRD analysis revealed that DC14 metallogels took a mixture of hexagonal and tetragonal packing modes. All obtained metallogels have shown typical luminescent emissions of the lanthanide complex. In particular, DC18/Tb(NO3)3 metallogel in DMF/H2O (v:v = 1:1) has shown excellent self-supporting, self-healing, film-forming, and rheological properties.

Graphical abstract

The Tb3+/Eu3+ metallogels have been formed with aromatic carboxylic acids as ligands, and they have shown excellent luminescent, self-healing, film-forming, and rheological properties.

Keywords

Metallogel Aromatic carboxylic acids Self-assembly Thixotropic property Self-healing property 

Notes

Funding information

The authors gratefully acknowledge the financial support from the Natural Science Foundation of China (NSFC) (21403166, 21706209), the Natural Science Foundation of Shaanxi Province (2016JQ2005, 2017JQ2028), and the Science and Technology Program of Xi’an (2017CGWL01), College Students’ innovation and entrepreneurship training program (201711080004, S201911080057).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

396_2020_4598_MOESM1_ESM.docx (4 mb)
ESM 1 (DOCX 4083 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2020

Authors and Affiliations

  • Min Xue
    • 1
    Email author
  • Ming Chen
    • 1
  • Wenhao Chang
    • 1
  • Ruiyang Chen
    • 1
  • Pengna Li
    • 1
  1. 1.School of Chemical EngineeringXi’an UniversityXi’anPeople’s Republic of China

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